CAS: 115414-47-6; β-D-Glucopyranoside, Hexadecyl 2-(Acetylamino)-2-Deoxy-, 3,4,6-Triacetate
该化合物是一种甘蓝的化合物,其特点是长期缺水的六丁基环十二烷链和乙基乙酸盐的混合物,其特点是乙酰环十二烷链和乙氧基甲酸盐的混合物,这种结构既具有双栖生物特性,又在各种有机溶剂中溶解,同时又在水生环境中保持某种程度的溶解性;乙酰胺组的存在增强了其稳定性和潜在的生物活动.一般地说,对这种化合物进行研究是为了将其应用于药物运载系统,表面活性剂和作为有机合成的中间体.乙酰胺组可以在特定条件下进行水解,从而释放活性甘胺衍生物,这可能会显示各种生物活动.此外,该化合物的分子结构表明它与生物膜可能发生某种互动,从而使其在制药和生物化学研究中引起兴趣.
- 英文名称β-D-Glucopyranoside, Hexadecyl 2-(Acetylamino)-2-Deoxy-, 3,4,6-Triacetate
- 中文名称β-D-吡喃葡萄糖苷,十六烷基 2-(乙酰氨基)-2-脱氧-, 3,4,6-三乙酸酯
- IUPAC名称(2R,3S,4R,5R,6R)-5-Acetamido-2-(acetoxymethyl)-6-(hexadecyloxy)tetrahydro-2H-pyran-3,4-diyl diacetate
- 其它别名Hexadecyl 2-Acetamido-3,4,6-Tri-O-Acetyl-2-Deoxy-Beta-D-Glucopyranoside; Hexadecyl2-Acetamido-3,4,6-Tri-O-Acetyl-2-Deoxy-B-D-Glucopyranoside; Hexadecyl 2-Acetamido-3,4,6-Tri-O-Acetyl-2-Deoxy-Ss-D-Glucopyranoside; Hexadecyl 2-Acetamido-3,4,6-Tri-O-Acetyl-2-Deoxy-β-D-Glucopyranoside; Hexadecyl 2-(Acetylamino)-2-Deoxy-Beta-D-Glucopyranoside 3,4,6-Triacetate; β-D-Glucopyranoside, Hexadecyl 2-(Acetylamino)-2-Deoxy-, 3,4,6-Triacetate; (2R,3S,4R,5R,6R)-3,4-Bis(Acetyloxy)-5-Acetamido-6-(Hexadecyloxy)Oxan-2-Yl]Methyl Acetate
- CAS编号115414-47-6
- MFCD编号:MFCD08703745
- 分子式:C30H53NO9分子量:571.75
- 产品CID: 190670
- 产品分类有机原料→分子砌块→芳杂环类化合物→吡喃类化合物
相似化合物
115414-49-8 211567-22-5 173725-22-9MSDS等安全信息
上下游产品
1-Hexadecanol 2-methyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranoso)[1,2-d]-2-oxazoline Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl esterhexadecyl 2-acetamido-2-deoxy-β-D-glucopyranoside hexadecyl 2-acetamido-3-O-acetyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside hexadecyl 2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside hexadecyl 2-acetamido-4,6-O-benzylidene-3-O-(D-1-carboxyethyl)-2-deoxy-β-D-glucopyranoside合成工艺路线路线简述
- 合成目标产物 Hexadecyl 2-Acetamido-3,4,6-Tri-O-Acetyl-2-Deoxy-Beta-D-Glucopyranoside 主要起始原料 1-Hexadecanol And 2-Acetamido-2-Deoxy-Alpha-D-Glucopyranosyl Chloride 3,4,6-Triacetate
- (文献来源)合成步骤主要原料 1-Hexadecanol 和 2-Acetamido-2-Deoxy-Alpha-D-Glucopyranosyl Chloride 3,4,6-Triacetate
📜1-十六烷醇,2-乙酰氨基-3,4,6-三-O-乙酰-2-脱氧-α-D-吡喃葡萄糖酰基氯置于3 A Molecular Sieve,Mercury(II) Iodide体系中,用 1,2-二氯乙烷 用作溶剂,以61%的收率获得十六烷基-2,3,4,6-四-氧-乙酰基-β-D-吡喃氨基葡萄糖苷
参考文献:Synthesis Of-Glycosides Of N-Acetylglucosamine In The Presence Of Hgi2
标题:Synthesis Of-Glycosides Of N-Acetylglucosamine In The Presence Of Hgi2
摘要:
Doi:10.1007/bf01372338
海关参考信息
- 2905122000-异丙醇
2905310000-1,2-乙二醇
2905320000-1,2-丙二醇
2905399001-1,3-丙二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Synthesis Of Oligosaccharides Designed To Form Micelles, Corresponding To Structures Found In Ovarian Cyst Fluid作者:Therese Buskas,Peter Konradsson |发布日期:2000.1
摘要:The Syntheses Of Alpha-D-Glcpnac-(1-->4)-Beta-D-Galp-(1-->4)-Beta-D-Glcnac-(1-->O)-(Ch2)(15)Ch3 (1) And Fragments Thereof, Corresponding To Structures Found In Human Ovarian Cyst Fluid, Are Described. Silver Triflate Promoted Coupling Of 3.4,6-Tri-O-Acetyl-2-Azido-2-Deoxy-Beta-D-Glucopyranosyl Bromide (12) And Galactose Acceptor (11) Gave A Disaccharide Donor (13), Which Was Readily Transformed Into The Corresponding Bromo-Derivative 18. For The Synthesis Of Disaccharide Beta-D-Galp-(1-->4)-D-Glcnac, Several Differently Protected Glucosamine Accepters Were Prepared. It Was Found That Cetyl Alcohol Needed To Be Introduced After The Formation Of The P-Galactoside Bond. Glycosylation Of Pent-4-Enyl 3,6-Di-O-Benzyl-2-Deoxy-2-Tetrachlorophthalimido-Beta-D-Glucopyranoside (30) With (3,4,6-Tri-O-Acetyl-2-Azido-2-Deoxy-Alpha-D-Glucopyranosyl)-(1-->4)-2,3,6-Tri-O-Benzoyl-Alpha-D-Galactopyranosyl Bromide (18) By Use Of Silver Triflate As Promoter Gave The Desired Trisaccharide 31. Finally 31 Was Transformed Via Coupling To The Long Alkyl Chain Aglycon And Deprotection Into The Title Compound 1.
合成参考文献
合成方法参考DOI号:10.1016/S0040-4039(00)75823-0
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