CAS: 1074-29-9; Trichloro(Phenyl)Germane

该化合物是一种有机金属化合物,其特点是将原子与一个苯基组和三个氯原子捆绑在一起,其特征是分子重量相对较高,有机和无机成分的存在均有助于其独特的化学特性.三氯苯并呋喃一般是粉黄液体的无色物,在有机溶剂中表现出中等的挥发性和溶解性.由于存在电益菌中心,这种化合物具有反应性,特别是在核生殖器替代反应中.氯原子可以影响化合物的稳定性和再活性,使其在各种化学合成和应用中有用,包括作为其他有机金属化合物的前体.然而,处理这种化合物需要谨慎小心,因为其潜在的毒性和环境影响,需要在实验室环境中采取适当的安全措施.

结构式图片

相似化合物

860585-01-9 1261861-19-1 104013-25-4

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

adamantane Triphenylsilyl chloride diphenylsilyl dichloride chloro(methyl)phenylsilane6H5GeHCl2*(C2H5)3NC6H5GeHCl2*(C2H5)3N allyl(trichloro)germane chlorobenzene 1,1-dichloro-3-methyl-1-germacyclo-3-pentene

合成工艺路线路线简述

    📜反应生成苯基三氯化锗
    参考文献:Piviere P.; Castel A.; Satge J.,J. Organometal. Chem.,1981,212,No 3,351-367
    标题:Piviere P.; Castel A.; Satge J.,J. Organometal. Chem.,1981,212,No 3,351-367

    专利信息


    专利号:US-4565896-A
    优先权日:1984-10-22
    标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas
    发明人:KNIFTON JOHN F; DURANLEAU ROGER G
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.

    专利号:US-4609768-A
    优先权日:1984-10-22
    标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent
    发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.

    专利号:US-4568780-A
    优先权日:1984-10-22
    标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane
    发明人:KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silane or germane-containing promoter dispersed in a hydrocarbon solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi, where the particular solvents used allow the desired product to be separated from the reaction mixture by phase separation.

    专利号:US-4409405-A
    优先权日:1982-05-13
    标题:Production of ethanol from methanol and synthesis gas
    发明人:LIN JIANG-JEN; KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:Ethanol is formed by contacting a mixture of carbon monoxide, hydrogen and methanol with a catalyst comprising a cobalt-containing compound and a germanium-containing compound, such as dicobalt octacarbonyl and triphenylgermanium hydride in the presence of an inert, oxygenated hydrocarbon solvent at a temperature of about 50 DEG to about 350 DEG C. and at a pressure of about 500 psig or greater.

    专利号:FR-2722781-A1
    优先权日:1994-07-20
    标题:Non-catalytic synthesis of organic or organo-metallic prods.

    专利号:EP-0134324-B1
    优先权日:1983-08-15
    标 题 :Production of ethanol from methanol and synthesis gas

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Weinert, C. S., Science of Synthesis Knowledge Updates, (2020) 3, 131.
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