CAS: 7546-30-7; Mercurous Chloride

上下游产品

clorine Iodine mon°Chloride dichloromethane sulfur dichloride

📜氯化亚砜,汞 以 Neat (No Solvent,Gas Phase) 作为反应溶剂,化学反应生成 氯化亚汞
参考文献:流动的余辉研究汞(3P2)和汞(3P0)原子被卤素,卤素间原子和多原子卤化物分子淬灭的反应
标题:流动的余辉研究汞(3P2)和汞(3P0)原子被卤素,卤素间原子和多原子卤化物分子淬灭的反应
摘要:
DOI:10.1021/j100289A019

专利信息

专利号:US-2008125587-A1
优先权日:2006-05-25
标 题 :Synthesis of triazole compounds that modulate HSP90 activity
发明人：CHIMMANAMADA DINESH U; LEE CHI-WAN; JAMES DAVID; ZHANG SHIJIE; YING WEIWEN; CHAE JUNGHYUN; PRZEWLOKA TERESA
权利人:CHIMMANAMADA DINESH U; LEE CHI-WAN; JAMES DAVID; ZHANG SHIJIE; YING WEIWEN; CHAE JUNGHYUN; PRZEWLOKA TERESA
摘要:The present invention provides novel methods of preparing triazole compounds which inhibit the activity of Hsp90. One embodiment of the invention is directed to methods for preparing a triazole compound represented by the following Structural Formula: n n n n n n n n n n or a tautomer, a pharmaceutically acceptable salt, solvate, or clathrate, or a prodrug thereof, comprising the steps of: a) reacting an amide represented by the following Structural Formula: n n n n n n n n n n with a thionation reagent to form a thioamide; b) reacting the thioamide of step a) with hydrazine to form a hydrazonamide; c) reacting the hydrazonamide of step b) with a carbonylation or a thiocarbonylation reagent. n In one embodiment, the present invention is a method of synthesis of a compound of formula (IA) n n n n n n n n n n or a tautomer, a pharmaceutically acceptable salt, solvate, or clathrate, or a prodrug thereof, comprising reacting a compound of formula (IIA) n n n n n n n n n n with an oxidizing agent, thereby producing a compound of formula (IA). n The present invention is also directed to a method of preparing a compound or a tautomer thereof represented by the following Structural Formula: n n n n n n n n n n or a tautomer, a pharmaceutically acceptable salt, solvate, or clathrate, or a prodrug thereof. The method comprises the step of reacting a first starting compound represented by the following Structural Formula: n n n n n n n n n n in the presence of a mercuric salt, with a second starting compound represented by the following Structural Formula:

专利号:WO-2024243127-A1
优先权日:2023-05-19
标题:Transformative synthesis of semiconductor nanoclusters with atomic precision via metal-ligand coordination exchange
发明人：ZENG CHENJIE; MA FUYAN
权利人:UNIV FLORIDA
摘要:Precision nanosynthesis is crucial for atomic engineering in nanostructures and mechanistic understanding of nanoscale reactions. But it is a daunting task due to emerging complexities in nanostructures and nanosynthesis. Here, we report the precision synthesis of semiconductor nanocluster via synergizing coordination, cluster, and colloidal chemistry at the nanoscale. In particular, by employing Cu26Se13(PEt2Ph)14 cluster and Cdl2(PPr3)2 coordination complex as precise precursors in colloidal cation exchange reaction, an atomically precise Cd26Se17I18(PPr3)10 cluster is produced at near- unity yield. X-ray crystallography reveals that the child CdSe cluster inherits its icosahedral-packed anion lattice and halide-phosphine-rich surface from parent cluster and complex respectively and further evolves into an enlarged structure. The hybridization of achiral precursors leads to chiral CdSe clusters co-crystallized as a 1:1 mixture of enantiomers. In-situ optical spectroscopy unveils that the reaction proceeds with well-defined pathways. Based on charge and coordination conservations, the structure of child cluster can be atomically linked to precursors via a series of transformations including surface coordination exchange, intra-cluster reorganization, and inter-cluster digestive ripening. The precision nanosynthesis with atomically defined precursors, pathways, and products is expected to further rationalize and diversify nanochemistry.

专利号:US-2023312596-A1
优先权日:2020-07-20
标题:Method for large-scale synthesis of tetrodotoxin
发明人：WANG GUANGYIN; LI XIAOMING; WANG CHENGXI; HUANG PING; BAI HUA; LAI LIANG; GUO PENG; JIANG BIAO; ZHU WENFENG
权利人:SHANGHAI SHENGPING MEDICAL EQUIPMENT CO LTD; SHANGHAI VASTPRO TECH DEVELOPMENT CO LTD; ZHEJIANG BOXIAO BIOPARMACEUTICAL CO LTD
摘要:The present invention provides a method for biological and chemical synthesis of tetrodotoxin, specifically comprising the following steps: using cheap and easily available benzyl acetate as a raw material, and performing biological fermentation to obtain an optically pure intermediate ((5S, 6R)-5, 6-dihydroxycyclohexa-1, 3-dienyl) methyl acetate (formula I); and performing a series of chemical conversions on the intermediate to finally obtain tetrodotoxin at a purity of 95% or more without purifying the product. The present invention has the potential of large-scale production, and is an excellent alternative to the existing extraction method from a pufferfish.

专利号:US-2025296849-A1
优先权日:2021-04-16
标 题:Method of making silver-iron titanate nanoparticles and uses thereof
发明人：SENEVIRATNE KASUN LAKNATH; MUNAWEERA IMALKA; PEIRIS SRIYANI EDUSSURIYA; PEIRIS COLIN NISANTHA; KOTTEGODA NILWALA
权利人:SRI LANKA INSTITUTE OF INFORMATION TECH
摘要:High quality silver-iron titanate nanoparticles are synthesized using an ilmenite source. The silver-iron titanate nanoparticles were characterized using various analytical techniques. As compared to prior art methods, the disclosed methods provide for the simple, cost-effective synthesis of relatively high-quality silver-iron titanate nanoparticles. The silver-iron titanate nanoparticles can be used in a variety of important agricultural, industrial, and hygienic uses, including in the important area of plant tissue culture explant sterilization.

专利号:US-5574148-A
优先权日:1995-02-02
标 题 :Rapid synthesis of radiolabeled pyrimidine nucleosides or nucleotides
发明人：KASSIS AMIN I; FOULON CATHERINE F; ADELSTEIN S JAMES
权利人:PRESIDENT U FELLOWS OF HARVARD
摘要:A method of making a radiolabeled pyrimidine nucleoside or nucleotide is described. In the method an aqueous solution (i) a radioactive iodide, bromide, chlorine or astatide ion and (ii) a water soluble halomercuri pyrimidine nucleoside or nucleotide is contacted with an oxidizing agent, whereby a water soluble pyrimidine nucleoside or nucleotide labeled with radioactive iodine, bromine, chlorine or astatine is formed. Kits suitable for practicing the method are also disclosed.

专利号:WO-9013513-A1
优先权日:1989-05-12
标 题:Combustion synthesis of materials using microwave energy
发明人：CLARK DAVID E; IFTIKHAR AHMAD; DALTON ROBERT C
权利人:UNIV FLORIDA
摘要:Combustion synthesis process using microwave energy. The process uses microwave energy to ignite at least two reactants which are capable of reacting exothermically to produce a reaction product. In accordance with one embodiment of the invention, combustion of the reactants is also controlled using microwave energy.