CAS: 626-20-0; 1-Methoxy-3-Vinylbenzene

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CAS号2065-66-9 甲基三苯基碘化 | CAS号591-31-1 3-甲氧基苯甲醛 | CAS号1779-49-3 甲基三苯基溴化膦 | CAS号766-85-8 3-碘苯甲醚 | CAS号1826-67-1 乙烯基溴化镁 | CAS号28539-02-8 1H-苯并三唑-1-甲醇 | CAS号18880-05-2 (3-甲氧基苄基)三苯基氯化鏻 | CAS号54509-73-8 ethene | CAS号2845-89-8 3-氯苯甲醚 | CAS号7486-35-3 三丁基乙烯基锡 | CAS号40101-17-5 3,3'-二甲氧基苯偶酰 | CAS号40138-66-7 3-(3-甲氧基苯基)丙醛 | CAS号14064-58-5 1-methoxy-3-[2-... | CAS号5020-41-7 2-(3-甲氧基苯基)乙醇 | CAS号23308-82-9 1-(3-甲氧基苯基)乙醇 | CAS号10002-44-5 2-(2-Methoxy-ph... | CAS号1017395-60-6 2-(3-甲氧基苯基)吗啉 | CAS号10568-38-4 Benzene,1-ethyl... | CAS号32017-77-9 2-(间甲氧基苯基)环氧乙烷

📜3-乙炔基苯甲醚置于c31H33B2Np2体系中,用 甲苯 作为反应溶剂,以85 %的收率获得产物3-甲氧基苯乙烯
参考文献:氨基膦硼烷作为腈,炔烃和羧酸的硼氢化试剂
标题:氨基膦硼烷作为腈,炔烃和羧酸的硼氢化试剂
摘要:我们在此报道了使用氨基膦硼烷 {(Bh 3)(Pph 2)-Nc(Ch 3) 3 },{(Bh 3) 2 (Pph) 2 N(Ch 2)C进行腈类,炔烃和羧酸的硼氢化反应6 H 5 }和{(Bh 3) 2 (Pph 2) 2 N-(Bh 3)Ch 2 C 6 H 4 N}作为还原剂.合成这些化合物是为了替代更常用的硼烷试剂.固体酰胺膦硼烷易于合成,对多种腈,炔和羧酸表现出优异的反应活性和官能团耐受性,以非常好的产率提供相应的铵盐,烯烃和醇.
DOI:10.1021/acs.Orglett.3C03194

专利信息

专利号:WO-2022155981-A1
优先权日:2021-01-25
标题 :USE OF N-HETEROCYCLIC CARBENE-BASED COMPOUNDED NICKEL (II) COMPLEX IN SYNTHESIS OF α-BENZYL BENZOFURAN COMPOUND
发明人：SUN HONGMEI; SHUI YU; JIN WENHUI
权利人:UNIV SOOCHOW
摘要:Disclosed is the use of an N-heterocyclic carbene-based compounded nickel (II) complex in the synthesis of an α-benzyl benzofuran compound. In the present invention, an air-stable compounded nickel (II) complex Ni[P(OEt) 3 ]{[R`NC(CH 3 )C(CH 3 )NR`]C}Br 2 is used as a catalyst, wherein R` is 2,4,6-trimethylphenyl, and the α-benzyl benzofuran compound is synthesized by means of a hydrogen heteroarylation reaction of an aryl ethylene compound and a benzofuran compound in the presence of an organic base. The operability and substrate applicability of the catalyst are obviously better than those of the prior art, and meanwhile, the nickel catalyst has a higher practical application value due to the air stability and easiness of synthesis thereof.

专利号:US-5998627-A
优先权日:1997-08-04
标题 :Preparation and uses of hydrocarbylnitrones
发明人：THERIOT KEVIN J
权利人:ALBEMARLE CORP
摘要:Nitrones are produced by reaction of primary amine with aldehyde or ketone, in the presence of a transition metal-containing oxidation catalyst, and a peroxidic compound. The nitrone can then be reacted with a vinylaromatic compound to produce a 2-hydrocarbyl-5-arylisoxazolidine. Both such reactions can be conducted concurrently by including the vinylaromatic compound in the initial reaction mixture. Hydrogenation of the 2-hydrocarbyl-5-arylisoxazolidine, e.g., using hydrogen and a palladium-carbon catalyst, forms an N-hydrocarbyl-3-aryl-3-hydroxypropylamine. Such reactions enable, inter alia, synthesis of the racemic hydrochloride salt of N-methyl-3-phenyl-3-[4-trifluoromethyl)phenoxy]-propylamine, known generically as fluoxetine hydrochloride, a widely used antidepressant.

专利号:US-8716532-B2
优先权日:2009-03-27
标 题:One pot multicomponent synthesis of some novel hydroxy stilbene derivatives with alpha, beta-carbonyl conjugation under microwave irradiation
发明人：SHARMA ABHISHEK; SINHA ARUN KUMAR; KUMAR RAKESH; SHARMA NAINA
权利人:SHARMA ABHISHEK; SINHA ARUN KUMAR; KUMAR RAKESH; SHARMA NAINA; COUNCIL SCIENT IND RES
摘要:The present invention provides a method for the preparation of some novel multiconjugated 2- or 4-hydroxy substituted stilbenes. The method provides one pot multicomponent approach wherein 3-4 step reaction sequences viz. condensation, decarboxylation and Heck coupling occur simultaneously which results in an enhanced yield of desired products and reduced reaction times.

专利号:US-8742045-B2
优先权日:2009-06-03
标题:Polymerization initiator for living radical polymerization
发明人：GOTO ATSUSHI; KIM JEONG SIK; TSUJII YOSHINOBU; FUKUDA TAKESHI
权利人:GOTO ATSUSHI; KIM JEONG SIK; TSUJII YOSHINOBU; FUKUDA TAKESHI; UNIV KYOTO
摘要:Provided is a method of living radical polymerization which does not necessitate complicated and intricate synthesis of a dormant species and which is highly efficient. A halogenated derivative compound is used as a dormant species for initiating living radical polymerization. The derivative compound is obtained by halogenating an alcohol compound having a non-conjugated structure or an amine compound having a non-conjugated structure with a halogenating agent capable of halogenating an alcohol or amine. A radical produced by elimination of halogen from the halogenated derivative compound is allowed to react with the unsaturated bond of the monomer. Thus, the monomer, which has a radical-reactive unsaturated bond, is polymerized by living radical polymerization. Preferably, the halogenating agent is a compound (NIS or the like) which also has a function as a catalyst.

专利号:US-5187288-A
优先权日:1991-05-22
标 题 :Ethenyl-substituted dipyrrometheneboron difluoride dyes and their synthesis
发明人：KANG HEE C; HAUGLAND RICHARD P
权利人:MOLECULAR PROBES INC
摘要:This invention relates to ethenyl-substituted derivatives of dipyrrometheneboron difluoride dyes that have an absorption maximum at wavelengths longer than about 525 nm, and are electrically neutral, highly photostable and, in most cases, highly fluorescent with relatively narrow absorption and emission spectra. The ethenyl-substituted dyes generally have the structure: wherein at least one of the fluorophore substituents R1-R7, is an ethenyl group of the formula -CXm=CYm-Zm, where m is any combination of locations 1, 2, 3, 4, 5, 6, and 7 corresponding to the location of parent fluorophore substituents R1-7. The initial ethenyl substituents Xm, Ym, and Zm, which may be the same or different, are halogen, alkyl (containing 1-10 carbon atoms), cyano, ester, amide, ethenyl or polyethenyl, aryl or heteroaryl. The non-ethenyl substituents, which may be the same or different, are hydrogen, halogen, alkyl (containing 1-18 carbon atoms), aryl, arylalkyl, heteroaryl, acyl or sulfo.

专利号:US-4734495-A
优先权日:1985-07-17
标 题 :Process and intermediates for beta-lactam antibiotics
发明人：EVANS DAVID A; SJOGREN ERIC B
权利人:HARVARD COLLEGE
摘要:1-Benzyl(or substituted benzyl)-3β-[4(S)-aryloxazolidin-2-one-3-yl]-4β-(2-arylvinyl)azetidin-2-ones are provided via cycloaddition of a 4(S)-aryloxazolidin-2-one-3-ylacetyl halide and an imine formed with a benzylamine and a 3-arylacrolein, e.g. cinnamaldehyde. The azetidinones are useful chiral intermediates in an asymmetric synthesis of 1-carba(1-dethia)-3-hydroxy-3-cephem-4-carboxylic acids and esters and to monocyclic β-lactam antibiotics.