N-苯基-1-萘胺,三(4-碘苯)胺置于铜,Potassium Carbonate体系中,用 萘烷 用作溶剂,化学反应 24.0H,以60%的收率获得4,4',4"-三(N-(1-萘基)-N-苯基氨基)三苯胺 参考文献:Organic El Devices And Production Process Thereof 标题:Organic El Devices And Production Process Thereof 摘要:一种有机电致发光器件,包括位于一对电极之间的发光层,该发光层包括由三级胺化合物组成的传输空穴材料,电子传输材料和发光添加剂材料的混合物,其中三级胺化合物具有由循环伏安法确定的两个或更多氧化电位,氧化电位中第一个氧化电位和第二个氧化电位之间的电位差为0.22V或更大,且具有至少100oc的玻璃转变温度,电子传输材料具有至少100oc的玻璃转变温度.
专利号:US-8987451-B2 优先权日:2012-01-03 标题 :Synthesis of cyclometallated platinum(II) complexes 发明人:TSAI JUI-YI; KOTTAS GREGG; YEAGER WALTER 权利人:UNIVERSAL DISPLAY CORP 摘要:A single-step method of making tetradentate platinum complexes is disclosed. The method advantageously allows the formation of a platinum complex in a single step, even with sterically hindered ligands, without the use of highly reactive intermediates. The compounds made by the disclosed method are useful in OLED applications.
专利号:US-2013172561-A1 优先权日:2012-01-03 标 题:Synthesis of cyclometallated platinum(ii) complexes
专利号:US-2025042877-A1 优先权日:2021-11-30 标题:Organic compound, organic device, light-emitting apparatus, and electronic appliance 发明人:HAYASHI YUKI; KAWAKAMI SACHIKO; HASHIMOTO NAOAKI 权利人:SEMICONDUCTOR ENERGY LAB 摘要:A novel compound, a synthesis method thereof, and an organic device including the novel compound are provided. A compound represented by General Formula (G1) is provided. In General Formula (G1), each of R1, R2, and R5 to R7 independently represents any of hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 1 to 60 carbon atoms, and a substituted or unsubstituted heteroaryl group having 1 to 60 carbon atoms. R3 represents a condensed ring composed of 4 to 10 rings containing nitrogen as an element forming the ring, and R4 represents any of a substituted or unsubstituted condensed ring having 1 to 60 carbon atoms, a substituted or unsubstituted aryl group with a molecular weight of 78 or more, and a substituted or unsubstituted heteroaryl group with a molecular weight of 80 or more. At least one of A1 to A3 represents nitrogen, and each of the others represents substituted carbon. Each of substituents of A1 to A3 independently represents any of hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 1 to 60 carbon atoms, and a substituted or unsubstituted heteroaryl group having 1 to 60 carbon atoms.
专利号:US-7455792-B2 优先权日:2002-02-20 标 题 :Organic conductive material and conductive varnish 发明人:YOSHIMOTO TAKUJI; FUKURO HIROYOSHI; FURUSHO HITOSHI; YANAGIMOTO AKIRA 权利人:NISSAN CHEMICAL IND LTD 摘要:Disclosed herein are an organic conductive material and a conductive varnish containing it in an amount of 1 to 80 wt %. The organic conductive material comprises an oligoaniline derivative represented by the formula (1) in which quinoimine as an oxidant formed at the time of synthesis is reduced by a reducing agent and a salt is formed with an electron accepting dopant. n n(where R 1 to R 3 independently denote a hydrogen atom, unsubstituted or substituted monovalent hydrocarbon group, organoxy group, or acyl group; A and B independently denote a divalent group represented by the formula (2) or (3) below;n n nwhere, R 4 to R 11 independently denote a hydrogen atom, hydroxyl group, unsubstituted or substituted monovalent hydrocarbon group, organoxy group, acyl group, or sulfonic group; and m and n independently denote a positive number equal to or larger than 1 such that m+n≦20.)
专利号:US-9260463-B2 优先权日:2011-11-30 标题 :Substituted pyrimidinato iridium complexes and substituted pyrazinato iridium complexes having an alicyclic diketone ligand 发明人:INOUE HIDEKO; SEO HIROMI; SEO SATOSHI 权利人:SEMICONDUCTOR ENERGY LAB 摘要:As a novel substance having a novel skeleton, a novel organometallic complex that can emit phosphorescence in the green to red wavelength region and has high emission efficiency and a high yield of synthesis is provided. One embodiment of the present invention is an organometallic complex in which a diketone having a five-membered or six-membered alicyclic structure composed of carbon and hydrogen is a ligand. n nIn the formula, L represents a bidentate aromatic ligand and has at least a bond between carbon of an aromatic ring in the aromatic ligand and Ir. X represents a five-membered or six-membered alicycle composed of carbon and hydrogen. Further, R 1 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms.
专利号:US-9309458-B2 优先权日:2012-02-24 标 题:Phosphorescent organometallic iridium complex, light-emitting element, light-emitting device, electronic device, and lighting device 发明人:INOUE HIDEKO; ISHISONE TAKAHIRO; OHSAWA NOBUHARU; SEO SATOSHI; HAMADA TAKAO 权利人:SEMICONDUCTOR ENERGY LAB 摘要:A novel phosphorescent organometallic iridium complex is provided in which a coordination position of a ligand with respect to a metal can be controlled in synthesis. A novel phosphorescent organometallic iridium complex is provided which can keep high quantum efficiency and can emit phosphorescence in the blue to green wavelength region. A phosphorescent organometallic iridium complex which includes a structure represented by General Formula (G1) and whose ligand is a 4H-1,2,4-triazole compound which has an unsubstituted phenyl group at the 3-position, a substituted or unsubstituted phenyl group at the 4-position, and a phenyl group at the 5-position. In the phenyl group at the 5-position, an alkyl group is bonded to at least one of the ortho-positions, and the other of the ortho-positions, the meta-positions, and the para-position are substituted or unsubstituted.
参考文献:10.1557/proc-0965-s14-03 摘要:Fleissner A, Schmid H, Melzer C, Schmechel R, von Seggern H. Transition from Non-Dispersive to Dispersive Hole Transport in a Small Molecule Organic Semiconductor Controlled by Molecular Doping. MRS Advances. 2006;965():0965–s14-03. doi: 10.1557/proc-0965-s14-03.