专利号:US-5962364-A 优先权日:1997-07-30 标 题:Process for synthesis of molybdenum sulfide dimers 发明人:WILSON JR ROBERT B; DU YUHUA; BOMBERGER DAVID 权利人:BP AMOCO CORP 摘要:A method for converting MoCp(CO) 3 ! 2 , in which at least one of the Cp groups has a substitutent having a carbonyl or carboxyl group and the compound has a Mo--Mo single bond, into a resinous supported material having repeating units of the formula (MoCp) 2 S 4 . The repeating units have four bridging sulfido ligands between the two molybdenum atoms, and the repeating units are joined to each other by bridging-sulfide ligands. The method comprises reacting the molybdenum carbonyl dimer with elemental sulfur in a solvent for the starting material at a temperature between 110-120° C. in the presence of a solid adsorbent support. The resinous material may be further hydrogenated, the hydrogenated material may be further reacted to form a material having a carboxyl-containing methanedithiolate ligand, and this latter material may be further hydrolyzed. The molybdenum sulfide dimers are useful for separation, purification, and recovery of unsaturated hydrocarbons.
专利号:WO-2023089578-A1 优先权日:2021-11-22 标题:A synthesis process of iron-bearing compositions and possible additional essential elements 发明人:MORMILE SILVIA; GUSMEROLI MARILENA; ZANARDI GIAMPAOLO; BIANCHI DANIELE; COTROMINO MICHELE; SARGIOTTO CHIARA; LIGUORI RICCARDO 权利人:GOWAN CROP PROT LIMITED 摘要:A synthesis process of iron-bearing compositions and possible additional essential elements is described for treating nutritional deficiencies in plants, in particular for the prevention and treatment of physiological alterations or nutritional unbalances in plants due to the deficiency of iron and other essential elements, and the iron-bearing compositions and possibly further essential elements obtained with said process.
专利号:US-5629394-A 优先权日:1992-12-17 标 题 :Direct synthesis by living cationic polymerization of nitrogen-containing polymers 发明人:CHERADAME HERVE M; CHEN FRANK J; STANAT JON E R; NGUYEN HUNG A; TABAR BEHROOZ R 权利人:EXXON CHEMICAL PATENTS INC 摘要:A method is provided for the direct synthesis by living cationic polymerization of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino, cyanato, thiocyanato or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.
专利号:US-6515091-B2 优先权日:2000-05-01 标 题 :Anionic vinyl/dicarboxylic acid polymers and uses thereof 发明人:SANDERS JOHN LARRY; KIMMERLY JAMES MICHAEL; MAZO GRIGORY 摘要:Biodegradable anionic polymers are disclosed which include recurring polymeric subunits preferably made up of vinylic and dicarboxylic monomers such as vinyl acetate or vinyl alcohol and maleic anhydride, itaconic anhydride or citraconic anhydride, or combinations thereof. Free radical polymerization is used in the synthesis of the polymers, which are then hydrolyzed to replace ester groups with alcohol groups. The polymers may be complexed with ions and/or mixed with fertilizers or seed to yield agriculturally useful compositions. The preferred products of the invention may be applied foliarly, to seeds, to fertilizer, or to the earth adjacent growing plants in order to enhance nutrient uptake by the plants.
专利号:AU-2023208727-A1 优先权日:2022-01-18 标题:Synthesis of boron-containing amidoxime reagents and their application to synthesize functionalized oxadiazole and quinazolinone derivatives
专利号:US-11820834-B2 优先权日:2018-07-10 标题 :Polymorphic forms of Cyclo (-His-Pro) and methods of use to treat kidney disease 发明人:OLMSTEAD KAY; PEARSON DAVID; MCPHERSON ELAINE 权利人:NOVMETAPHARMA CO LTD 摘要:The present disclosure relates to synthesis and characterization of novel polymorphic forms of Cyclo (-His-Pro) (“CHPâ€?).