专利号:US-6566292-B2 优先权日:2001-03-27 标 题 :Process for the enhancement of the cycle life of a zinc-chromium based catalyst in the synthesis of 2-methylpyrazine 发明人:POTHARAJU SEETHARAMANJANEYA SA; RAGHAVAN KONDAPURAM VIJAYA; RAO PANJA KANTA; KULKARNI SHIVANAND JANARDAN; RAO KATABATHINI NARASIMHA; GOPINATH RAJESH; FARSINAVIS SURESH; MESHRAM HARSHADAS MITARAM 权利人:COUNCIL SCIENT IND RES 摘要:The present invention relates to enhancement of the cycle life of a zinc chromium based catalyst used in the synthesis of 2-methylpyrazine by increasing the reaction temperature step-wise, starting from a low temperature, while monitoring the levels of total conversion and selectivity towards pyrazine. The catalyst can be regenerated after each cycle of use without substantial loss of activity.
专利号:EP-1373226-B1 优先权日:2001-03-30 标题 :Process for the enhancement of cycle life of a zinc-chromium based catalyst in the synthesis of 2-methylpyrazine 发明人:POTHARAJU SEETHARAMANJANEYA SA; RAGHAVAN KONDAPURAM VIJAYA; RAO PANJA KANTA; KULKARNI SHIVANAND JANARDAN; RAO KATABATHINI NARASIMHA; GAPINATH RAJESH; FARSINAVIS SURESH; MESHRAM HARSHADAS MITARAM 权利人:COUNCIL SCIENT IND RES 摘要:The present invention relates to enhancement of the cycle life of a zinc chromium based catalyst used in the synthesis of 2-methylpyrazine by increasing the reaction temperature step-wise, starting from a low temperature, while monitoring the levels of total conversion and selectivity towards pyrazine. The catalyst can be regenrated after each cycle of use without substantial loss of activity.
专利号:US-2011201702-A1 优先权日:2009-08-14 标题:Ultra small synthetic doped ferrihydrite with nanoflake morphology for synthesis of alternative fuels 发明人:BALI SUMIT; BALI GARIMA; EYRING EDWARD M; ERNST RICHARD D; PUGMIRE RONALD J 权利人:BALI SUMIT; BALI GARIMA; EYRING EDWARD M; ERNST RICHARD D; PUGMIRE RONALD J 摘要:A ferrihydrite catalyst composition can comprise a ferrihydrite of a structural promoter metal, a chemical promoter metal and potassium to form an amorphous nanoparticulate. The ferrihydrite catalyst can be formed by dissolving an iron salt, a structural promoter metal salt and a chemical promoter metal salt in water to form an aqueous iron solution. A ferrihydrite solid can be precipitated from the aqueous iron solution by addition of a precipitating agent under conditions such that the ferrihydrite solid is a nanoparticulate. A potassium can be incorporated into the ferrihydrite solid to form a ferrihydrite catalyst precursor. The ferrihydrite catalyst precursor can be calcined to form the ferrihydrite catalyst. A synthesis gas can be readily converted to a fuel product by contacting the ferrihydrite catalyst with the synthesis gas under reaction conditions sufficient to form a fuel product mixture.
专利号:US-9822053-B2 优先权日:2016-01-28 标题:Single step conversion of N-butyraldehyde to 2-ethylhexanal 发明人:BOPPANA Venkata Bharat; HAMPTON JR KENNETH WAYNE; LIU ZHUFANG; SUMNER JR CHARLES EDWAN; TUSTIN GERALD C; STEINMETZ GUY RALPH; STEFFEY MELISSA PAGE 权利人:EASTMAN CHEM CO 摘要:Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.
专利号:US-9932685-B2 优先权日:2012-02-09 标题:Synthesis of palladium nanoparticles 发明人:HALADA GARY P; JHA PRASHANT KUMAR; CUIFFO MICHAEL A 权利人:UNIV NEW YORK STATE RES FOUND 摘要:A method of synthesizing metal nanoparticles is provided. The method includes submerging an electrically conductive substrate in a polysaccharide solution containing a predetermined concentration of a metal salt; applying an electric potential between the electrically conductive substrate and the polysaccharide solution for a predetermined period of time to form a polysaccharide layer containing metal nanoparticles on the electrically conductive substrate; re-dissolving the polysaccharide layer in a solvent to form a solution including the polysaccharide and the metal nanoparticles; and separating the metal nanoparticles from the polysaccharide.
专利号:US-11691135-B2 优先权日:2020-10-15 标 题:Synthesis of alkynones via carbonylative Sonogashira coupling reactions catalyzed by Pd(II)-N-Heterocyclic carbene-pyridine complexes 发明人:EL ALI BASSAM; MANSOUR WASEEM; FETTOUHI MOHAMMED 权利人:UNIV KING FAHD PET & MINERALS; SAUDI ARABIAN OIL CO 摘要:This disclosure relates to N-substituted Pd(II)-N-heterocyclic carbene-pyridine complexes, methods of preparing the complexes, and methods of using the complexes in Sonogashira coupling reactions.