CAS: 1080-32-6; Diethyl Benzylphosphonate

相似化合物

3762-25-2 4546-04-7 63909-50-2

上下游产品

CAS号100-51-6 苯甲醇 | CAS号122-52-1 亚磷酸三乙酯 | CAS号1666-17-7 苯甲醛对甲苯磺酰腙 | CAS号762-04-9 亚磷酸二乙酯 | CAS号100-39-0 溴化苄 | CAS号2768-31-2 苯甲基亚磷酸二乙酯 | CAS号100-44-7 氯化苄 | CAS号591-50-4 碘苯 | CAS号10419-77-9 碘甲基膦酸二乙酯 | CAS号1137728-03-0 ((diethoxyphosp... | CAS号35302-70-6 银松素单甲醚 | CAS号14990-01-3 benzylphosphane | CAS号4714-21-0 4-甲基二苯乙烯 | CAS号833-81-8 (E)-丙-1-烯-1,2-二基二苯 | CAS号779-51-1 Alpha－甲基均二苯乙烯 | CAS号102-08-9 二苯基硫脲 | CAS号58-72-0 三苯乙烯 | CAS号948-65-2 2-苯基吲哚

📜氘代甲苯 反应 114.0H,反应生成苯基膦酸二乙酯
参考文献:通过ddq苄基c-H键的氧化性官能†
标题:通过ddq苄基c-H键的氧化性官能†
摘要:C-h活化甲基 甲苯和相关的拱3个由2,3-二氯-4,5-二氰基-1,4-苯醌衍生物(ddq)使插入产品,Arch 2 O [c 6氯2(cn)2 ] Oh经由速率决定氢化ddq进行抽象.生成的苄基醚可与膦反应生成苄基phospho盐(wittig试剂),与亚磷酸酯生成膦酸酯(horner-wadsworth-emmons试剂).
Doi:10.1039/c2Nj40021A

专利信息

专利号:US-10927135-B2
优先权日:2017-08-03
标 题:Metal-free direct arylation of dialkyl phosphonates for the synthesis of mixed alkyl aryl phosphonates
发明人：KANG JUN YONG; HUANG HAI
权利人:THE BOARD OF REGENTS OF THE NEVADA SYSTEM OF HIGHER EDUCATION ON BEHALF OF THE UNIV OF NEVADA LAS VE
摘要:Provided herein are phosphates, thiophosphates, phosphonates, and phosphinates, methods of making same, and methods of using these compounds and methods for the generation of pharmaceutically relevant phosphate, phosphonate, and phosphinate analogs. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

专利号:US-5420328-A
优先权日:1992-09-11
标题:Methods for the synthesis of phosphonate esters
发明人：CAMPBELL DAVID A
权利人:AFFYMAX TECH NV
摘要:Phsophonate esters can be synthesized in high yields by condensations of alcohols with methyl phosphonates followed by selective demethylation. The reaction is general, relativly insensitive to steric constraints of hindered phosphonic acids, and can also be carried out on a solid support to synthesize large collections of compounds to screen for pharmacological activity.

专利号:US-5359115-A
优先权日:1992-03-26
标题 :Methods for the synthesis of phosphonate esters
发明人：CAMPBELL DAVID A; JACOBS JEFFREY W
权利人:AFFYMAX TECH NV
摘要:Phosphonate esters can be synthesized in high yields by condensations of alcohols with methyl phosphonates followed by selective demethylation. The reaction is general, relatively insensitive to steric constraints of hindered phosphonic acids, and can also be carried out on a solid support to synthesize large collections of compounds to screen for pharmacological activity.

专利号:WO-2025133100-A1
优先权日:2023-12-22
标 题:Process for the preparation of intermediates useful for the preparation of tapinarof
发明人：MARQUILLAS OLONDRIZ FRANCISCO DE ASÃ?S; LEÓN SERRANO THIERRY
权利人:INTERQUIM SA
摘要:The present invention relates to a new process for the preparation of synthesis intermediate products useful for the preparation of tapinarof and to new intermediates thus obtained.

专利号:WO-2019028391-A1
优先权日:2017-08-03
标 题 :DIALKYL PHOSPHONATE DIRECT METAL-FREE ARYLATION FOR THE SYNTHESIS OF MIXED ALKYL ARYLATED PHOSPHONATES

专利号:EP-0659188-A1
优先权日:1992-09-11
标 题:Methods for the synthesis of phosphonate esters