CAS: 103361-09-7; Flumioxazin

该化合物是一种化学化合物,主要用于农业用途中的除草剂,属于二苯醚类化合物,其特点是能够抑制多种杂草的生长,特别是在大豆和棉花等作物中.作用方式包括干扰光合作用和抑制对叶绿素合成至关重要的杀菌素氧化酶.氟甲辛通常用于抗生素前或抗生素,以控制大叶素和草杂草.众所周知,它具有低挥发性和环境相对较高的稳定性,有助于其有效性.此外,氟甲氧辛在使用标签指示时对人类和非目标生物的毒性较低.其配方往往包括各种抗生素,以提高其功效和对植物表面的耐药性.同所有除草剂一样,适当处理和应用对于最大限度地减少潜在的环境影响和杂草本种群的耐药性至关重要.

结构式图片

欧盟法规

[欧盟农药活性物质

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    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-9750259-B2
    优先权日:2014-11-24
    标题:Pyroxasulfone and glutamine synthesis inhibitor compositions for weed control
    发明人:REFSELL DAWN
    权利人:VALENT U S A; VALENT USA CORP
    摘要:The present invention is directed to compositions containing herbicidal mixtures of pyroxasulfone and glutamine synthesis inhibitors. The present invention is further directed to methods of increasing the activity of a glutamine synthesis inhibitor with the compositions of the present invention.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.
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    主要参考文献


    1: Takaku T, Nagahori H, Sogame Y. Metabolism and physiologically based pharmacokinetic modeling of flumioxazin in pregnant animals. Toxicol Appl Pharmacol. 2014 Jun 15;277(3):242-9. doi: 10.1016/j.taap.2014.03.022. Epub 2014 Apr 6. doi: 10.1016/j.foodchem.2014.04.061. Epub 2014 Apr 24. doi: 10.1107/S2056989015017223. eCollection 2015 Oct 1.
    4: Shibata A, Kodaka R, Fujisawa T, Katagi T. Degradation of flumioxazin in illuminated water-sediment systems. J Agric Food Chem. 2011 Oct 26;59(20):11186-95. doi: 10.1021/jf202542v. Epub 2011 Sep 29. doi: 10.1039/c2an36023c. Chinese. Epub 2003 Jun 18. doi: 10.1002/ps.1533. Epub 2006 Dec 20. doi: 10.1111/j.1399-3054.2008.01151.x. Epub 2008 Jul 31. Epub 2003 Mar 6. Chinese. doi: 10.1002/bdrb.21133. Epub 2014 Dec 4.

    合成参考文献


    参考文献:10.1107/s1600536811006933
    摘要:He Q, Li J, Huang BJ. 4-(3-Fluoro-phen-yl)-6-hy-droxy-5-(thio-phen-2-ylcarbon-yl)-6-trifluoro-methyl-1,3-diazinan-2-one. Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 01;67(Pt 4):o759.
    参考文献:10.1107/s1600536811015376
    摘要:Yang FL, Fa WJ. Ethyl 4-hy-droxy-6-(4-hy-droxy-phen-yl)-4-trifluoro-methyl-2-sulfanyl-idene-1,3-diazinane-5-carboxyl-ate ethanol monosolvate. Acta Crystallogr Sect E Struct Rep Online. 2011 May 01;67(Pt 5):o1280–1.
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