CAS: 1004-66-6; 2,6-Dimethylanisole

相似化合物

4028-66-4 6738-23-4 578-58-5

上下游产品

CAS号576-26-1 2,6-二甲基苯酚 | CAS号74-88-4 碘甲烷 | CAS号77-78-1 硫酸二甲酯 | CAS号876-98-2 2,6-xylyl acetate | CAS号58425-33-5 potassium 2,6-d... | CAS号34949-12-7 Carbonic acid m... | CAS号616-38-6 碳酸二甲酯 | CAS号108-88-3 甲苯 | CAS号26620-08-6 Benzene,2-ethox... | CAS号527-61-7 2,6-二甲基对苯醌 | CAS号60609-65-6 3,5-二甲基-4-甲氧基苯乙酮 | CAS号39785-37-0 4-甲氧基-3,5-二甲基苯胺 | CAS号144316-87-0 2-[3-(cyanometh... | CAS号39250-90-3 3,5-二甲基-4-甲氧基苯甲醛 | CAS号1951-38-8 2-甲氧基间苯二甲酸 | CAS号576-26-1 2,6-二甲基苯酚 | CAS号1687-64-5 2-乙基-6-甲基苯酚 | CAS号3520-52-3 2-甲基-6-丙基苯酚 | CAS号26620-08-6 Benzene,2-ethox...

📜2,6-二甲基苯酚置于4-二甲氨基吡啶 Sodium Hydride体系中,化学反应 5.0H,反应生成2,6-二甲基大茴香醚
参考文献:五烷基胍作为醚化和酯化催化剂
标题:五烷基胍作为醚化和酯化催化剂
摘要:已经制备了几种五烷基胍,并且发现它们是用于由碳酸盐制备芳基和芳烷基醚以及用于苯酚与碳酸二甲酯甲基化的非常好催化剂.它们也可作为有效的催化剂,用于酸与烷基氯甲酸酯的酯化反应,而不是叔醇与乙酸酐的乙酰化反应.
Doi:10.1016/s0040-4020(01)89753-2

专利信息

专利号:US-4985567-A
优先权日:1988-03-07
标题:Chiral phosphinopyrrolidine compounds and their use for asymmetric synthesis of optically active compounds
发明人：ACHIWA KAZUO; TAKEDA HIDEO
权利人:KAZUO ACHIWA; FUJI YAKUHIN KOGYO KK
摘要:New chiral phosphinopyrrolidine compounds of the general formula: ##STR1## wherein R 1 is hydrogen or --COA 1 , --COOA 2 , --CONHA 3 , --SO 2 A 4 or --PO(A 5 ) 2 , A 1 , A 2 , A 3 , A 4 and A 5 each represents independently alkyl or aryl, R 2 is phenyl, di(lower-alkyl)aminophenyl, lower-alkoxyphenyl or 3,5-dimethyl-4-methoxyphenyl, and R 3 is phenyl, lower-alkylphenyl, di(lower-alkyl)aminophenyl, lower-alkoxyphenyl or 3,5-dimethyl-4-methoxyphenyl, with the proviso that R 2 and R 3 may not simultaneously by phenyl, p-di(lower-alkyl)-aminophenyl or p-lower-alkoxyphenyl, as well as the use of these compounds as ligand for a metal complex catalyst for asymmetric synthesis of optically active compounds. The new chiral phosphinopyrrolidine compounds are useful ligands which attain both of high optical yield and high reaction efficiency in catalytic asymmetric reduction.

专利号:US-2009088576-A1
优先权日:2006-01-30
标题:Process for the Stereoselective Preparation of Alcohols From Alpha, Beta-Insaturated Compounds
发明人：HEROLD PETER; STUTZ STEFAN; MAH ROBERT; STOJANOVIC ALEKSANDAR; LYOTHIER ISABELLE; BEHNKE DIRK; SPINDLER FELIX; BAPPERT ERHARD
权利人:HEROLD PETER; STUTZ STEFAN; MAH ROBERT; STOJANOVIC ALEKSANDAR; LYOTHIER ISABELLE; BEHNKE DIRK; SPINDLER FELIX; BAPPERT ERHARD
摘要:A process for the synthesis of an alcohol of formula (I), using as intermediate a compound of formula (V).

专利号:US-5187103-A
优先权日:1991-01-31
标题:Colorimetric method and reagent for the assay of lithium in a test sample
发明人：CZECH BRONISLAW P; CHAPOTEAU EDDY; KUMAR ANAND
权利人:MILES INC
摘要:A chromogenic cryptand found to be especially selective in the determination of lithium in blood of the general formula (I): ##STR1## where: n=1 or 2, n R 1 and R 2 , same or different, are hydrogen, lower alkyl, lower alkenyl, or lower alkylidene; and n Q is a chromogenic moiety capable of providing a detectable response upon complexation of said compound with lithium ion and has the structure: ##STR2## wherein: X is CH, C--OH or N; and Z is p-nitrophenylazo, 2,4-dinitrophenylazo, 2,4,6-trinitrophenylazo, p-nitrostyryl, p-benzoquinonemonoimino, bis-(4-dimethylaminophenyl) hydroxymethyl, 3-phenylisothiazolyl-5-azo, thiazolyl-5-azo; or isothiazolyl-5-azo. n A reagent composition and synthesis of a preferred chromogenic cryptand are also disclosed.

专利号:US-4283574-A
优先权日:1980-01-28
标 题:Process for the synthesis of 2,6-xylenol and 2,3,6-trimethylphenol
发明人：LEACH BRUCE E
权利人:CONOCO INC
摘要:Phenol is methylated over an alumina catalyst using methanol, and the reaction product therefrom is combined with additional methanol over a promoted magnesium oxide catalyst. Major reaction products are ortho-cresol, 2,6-xylenol and 2,3,6-trimethylphenol. The promoted magnesium oxide catalyst contains metal promoters selected from the group consisting of titanium, chromium, and uranium together with sulfate ions.

专利号:US-6828466-B2
优先权日:2002-07-19
标题:Process for the synthesis of phenols from arenes
发明人：MALECZKA JR ROBERT E; SMITH III MILTON R; HOLMES DANIEL; SHI FENG
权利人:UNIV MICHIGAN STATE
摘要:A process to synthesize substituted phenols such as those of the general formula RR'R''Ar(OH) wherein R, R', and R'' are each independently hydrogen or any group which does not interfere in the process for synthesizing the substituted phenol including, but not limited to, halo, alkyl, alkoxy, carboxylic ester, amine, amide; and Ar is any variety of aryl or hetroaryl by means of oxidation of substituted arylboronic esters is described. In particular, a metal-catalyzed C-H activation/borylation reaction is described, which when followed by direct oxidation in a single or separate reaction vessel affords phenols without the need for any intermediate manipulations. More particularly, a process wherein Ir-catalyzed borylation of arenes using pinacolborane (HBPin) followed by oxidation of the intermediate arylboronic ester by OXONE is described.

专利号:US-2006035950-A1
优先权日:2004-08-09
标 题:Novel processes for preparing substantially pure anastrozole
发明人：ALNABARI MOHAMMED; FREGER BORIS; ARAD ODED; ZELIKOVITCH LIOR; SERYI YANA; DANON EDNA; DAVIDI GUY; KASPI JOSEPH
权利人:ALNABARI MOHAMMED; FREGER BORIS; ARAD ODED; ZELIKOVITCH LIOR; SERYI YANA; DANON EDNA; DAVIDI GUY; KASPI JOSEPH
摘要:The present invention provides novel processes for purifying anastrozole, devoid of using liquid chromatography. The purification processes are via the isolated anastrozole salt forms, either by crystallization or by selective acidic extractions, and optionally in both cases, converting the purified anastrozole salt to anastrozole base. Also provided is an improved process for the synthesis of anastrozole, which is obtained by alkylating the isolated and purified starting material 3,5-bis(2-cyanoprop-2-yl)benzylbromide, the process being devoid of using toxic, hazardous and environmental unfriendly solvents and reagents.