CAS: 892-20-6; Triphenyltin Hydride

该化合物是一种有机锡化合物,广泛用作有机合成中的减少剂,其主要优势在于能够在温和条件下有效减少有机卤化物,单状物和其他功能组,使其在相应的碳氢化合物中减少其含量.该化合物具有高度选择性,特别是在激进媒介反应中,因此在脱卤和脱氧过程中具有宝贵的价值.三联苯锡氢化物还被用于合成复杂的分子,包括天然产品,因为它具有可预测的再活动性和与各种子体的兼容性.适当的处理至关重要,因为有机锡化合物由于其毒性和环境影响,需要谨慎的储存和处置.

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相似化合物

639-58-7 2273-51-0 1064-10-4

物理性质

MSDS等安全信息

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CAS号16853-85-3 氢化铝锂 | CAS号639-58-7 三苯基氯化锡 | CAS号894-09-7 Stannane,iodotr... | CAS号58-22-0 睾酮 | CAS号16940-66-2 硼氢化钠 | CAS号1262-21-1 双(三苯基锡)氧化物 | CAS号43435-60-5 methyl(oxo)silane | CAS号7732-18-5 水 | CAS号7439-95-4 镁标准溶液 | CAS号1091-26-5 methoxytripheny... | CAS号104849-66-3 triphenyltin,zinc | CAS号93-55-0 苯丙酮 | CAS号2034-10-8 Stannane,triphe... | CAS号77-80-5 Distannathiane,... | CAS号639-58-7 三苯基氯化锡 | CAS号595-90-4 四苯基锡 | CAS号1441-22-1 triphenyl(pheny... | CAS号34557-54-5 methane | CAS号7440-31-5 锡粉

合成工艺路线路线简述

  • 合成目标产物 Triphenyltin Hydride 主要起始原料 Testosterone And Chlorotriphenyltin
  • 61810-54-6 = 892-20-6
    反应条件:1.1 Reagents: Water
    标题:Potassium Trialkyl- And Triarylstannates: Preparation By The Deprotonation Of Stannanes With Potassium Hydride
    作者:Corriu,R.; Guerin,C.; Kolani,B.
    参考文献:Inorganic Syntheses 日期:1989 卷标:25 页码:110-14]

    639-58-7 = 892-20-6
    反应条件:1.1 Reagents: Aluminum Hydride
    标题:Reduction Of Some Aldehydes And Ketones With Organotin Hydrides
    作者:Kuivila,Henry G.; Beumel,O. F. Jr.
    参考文献:Journal Of The American Chemical Society 日期:1961 卷标:83 页码:1246-50]

    639-58-7 = 892-20-6
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether
    标题:Efficient Syntheses Of Four Stable-Isotope Labeled (1R)-Menthyl (1S,2S)-(+)-2-Phenylcyclopropanecarboxylates
    作者:Keliher,Edmund J.; Burrell,Richard C.; Chobanian,Harry R.; Conkrite,Karina L.; Shukla,Rajesh; Et Al
    参考文献:Organic & Biomolecular Chemistry 日期:2006 卷标:4(14) 页码:2777-2784]

    639-58-7 = 892-20-6
    反应条件:1.1 Reagents: Lithium Aluminum Hydride
    标题:Synthesis And Reactivity Of β-Stannylated Phenylalanines
    作者:Doelling,Karin
    参考文献:Zeitschrift Fuer Naturforschung 日期:2018 卷标:73(1) 页码:3-16]

    639-58-7 = 892-20-6
    反应条件:1.1 Reagents: Sodium Borohydride
    标题:A Convenient Preparation Of Tri-N-Butyltin Hydride
    作者:Szammer,J.; Otvos,L.
    参考文献:Chemistry & Industry (London 日期:1988 卷标:(23)]

    1262-21-1 = 892-20-6
    反应条件:1.1 Reagents: Borane Solvents: Tetrahydrofuran
    标题:Organotin Compounds; Iv. Reduction Of Triorganotin Oxides And Hydroxides With Borane: A Simple Route To Organotin Monohydrides
    作者:Chopa,A. B.; Koll,L. C.; Podesta,J. C.; Thorpe,F. G.
    参考文献:Synthesis 日期:1983 卷标:(9)]

    639-58-7 = 892-20-6
    反应条件:1.1 Reagents: Lithium Aluminum Hydride
    标题:Sulfur Substituted Organotin Compounds. X. Preparations And Reactions Of Ph3Sn(Ch2)Nsoc6H4Me-P (N = 3 Or 4) And Ph3Sn(Ch2)Nso2C6H4Me-P (N = 2,3 Or 4)
    作者:Wardell,James L.; Wigzell,John M.
    参考文献:Journal Of Organometallic Chemistry 日期:1983 卷标:244(3) 页码:225-33]

    639-58-7 = 892-20-6
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether; 4 H,0 °C1.2 Reagents: Water
    标题:Organometallic Iridium Complexes Of (Z)-1-Phenyl-2-(4',4'-Dimethyl-2'-Oxazolin-2'-Yl)-Eth-1-En-1-Ate: Structural Aspects,Reactivity And Applications In The Catalytic Dehydrogenation Of Alkanes
    作者:May,Kathleen L.; Clement,Roxanne; Lough,Alan J.; Gossage,Robert A.
    参考文献:Bulletin Of The Chemical Society Of Japan 日期:2021 卷标:94(8) 页码:2043-2047]

    639-58-7 = 892-20-6
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether
    标题:Novel Amino Propyl Substituted Organo Tin Compounds
    作者:Pichler,Johann; Torvisco,Ana; Bottke,Patrick; Wilkening,Martin; Uhlig,Frank
    参考文献:Canadian Journal Of Chemistry 日期:2014 卷标:92(6) 页码:565-573]

    639-58-7 = 892-20-6
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether; 30 Min,0 °C; 3 H,0 °C1.2 Solvents: Water; Cooled
    标题:Linear Oligostannanes: A Synthetic And Td-Dft Study
    作者:Harrypersad,Shane; Liao,Laura; Khan,Aman; Wylie,R. Stephen; Foucher,Daniel A.
    参考文献:Journal Of Inorganic And Organometallic Polymers And Materials 日期:2015 卷标:25(3) 页码:515-528]

    639-58-7 = 892-20-6 [标题:Reaction Conditions
    标题:Chlorotriphenylstannane
    作者:Yamamoto,Yoshinori
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-2]

    639-58-7 = 892-20-6 [标题:Reaction Conditions
    标题:Distannenes And Distannanes
    作者:Podlech,J.
    参考文献:Science Of Synthesis 日期:2003 卷标:5 页码:273-283]

    42451-63-8 = 892-20-6 [标题:Reaction Conditions
    标题:Product Subclass 1: Tin Hydrides
    作者:Clark,A. J.
    参考文献:Science Of Synthesis 日期:2003 卷标:5 页码:205-271]

    639-58-7 = 892-20-6
    反应条件:1.1 Catalysts: Sodium Tetrafluoroborate,Sodium Borohydride
    标题:Simultaneous Determination Of Tributyltin And Triphenyltin Compounds Leached From Antifouling Paint By Gas Chromatography With Flame Photometric Detection
    作者:Takahashi,Kazunobu
    参考文献:Shikizai Kyokaishi 日期:1989 卷标:62(12) 页码:715-19]

    639-58-7 = 892-20-6
    反应条件:1.1 Reagents: Lithium Aluminum Hydride
    标题:Amidoselenation Of Olefins And Its Utilization For Synthesis Of Allylic Amides
    作者:Toshimitsu,Akio; Aoai,Toshiaki; Owada,Hiroto; Uemura,Sakae; Okano,Masaya
    参考文献:Journal Of Organic Chemistry 日期:1981 卷标:46(23) 页码:4727-33
📜三苯基氯化锡置于lialh4体系中,化学反应生成 三苯基氢化锡
参考文献:Cyclic Ketones And Their Use As Perfuming Ingredients
标题:Cyclic Ketones And Their Use As Perfuming Ingredients
摘要:式##str1##的新化合物,其中虚线表示单键或双键的位置,符号r.Sup.1代表氢原子或甲基基团,符号r.Sup.2代表线性或支链,饱和或不饱和的c.Sub.1到c.Sub.4烷基基团,前提是当r.Sup.2代表甲基或正丙基基团时,R.Sup.1不是氢,且环是饱和的.化合物(Ia)可用作香料成分.公开了它们的制备方法.

海关参考信息

专利信息


专利号:US-4940803-A
优先权日:1988-05-23
标题:Process for synthesis of 1R,2R,5R-2-hydroxy-6-oxo-7-oxabicyclo[3.2.1]-octane
发明人：MILLS SANDER G; VOLANTE RALPH P; SHINKAI ICHIRO
权利人:MERCK & CO INC
摘要:A process is described for the synthesis of hydroxy lactone 3, being 1R, 2R, 5R-2-hydroxy-6-oxo-7-oxabicyclo[3.2.1]-octane, in optically pure form, which is useful as an intermediate in the synthesis of the C 20 -C 34 chain of the macrolide structure for the immunosuppressant FK-506. This compound is also useful as a precursor for producing an ultraviolet radiation absorber.

专利号:US-5550267-A
优先权日:1994-06-14
标 题:Process for the synthesis of haloalkylferrocenes
发明人：GRAINDORGE HERVE; MONDET JEAN-CLAUDE; VINCENT CHARLES-HENRY
权利人:POUDRES & EXPLOSIFS STE NALE
摘要:The present invention relates to a process for the synthesis of haloalkylferrocenes, comprising a first stage of reaction, in the presence of AlCl 3 as catalyst and in organic solvent medium, of a carboxylic acid halide or anhydride with ferrocene or an alkylferrocene. n After this stage, without prior isolation of the intermediate compound, a metal hydride is added to the reaction mixture. n The haloalkylferrocenes are particularly useful as intermediates in the synthesis of combustion catalysts for propellants.

专利号:US-2023192731-A1
优先权日:2020-05-29
标 题 :Process for the stepwise synthesis of silahydrocarbons
发明人：AUNER NORBERT; STURM ALEXANDER G; SANTOWSKI TOBIAS; FELDER THORSTEN
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:The invention relates to a process for the stepwise synthesis of silahydrocarbons bearing up to four different organyl substituents at the silicon atom, wherein the process includes at least one step a) of producing a bifunctional hydridochlorosilane by a redistribution reaction, selective chlorination of hydridosilanes with an ether/HCl reagent, or by selective chlorination of hydridosilanes with SiCl 4 , at least one step b) of submitting a bifunctional hydridochloromonosilane to a hydrosilylation reaction, at least one step c) of hydrogenation of a chloromonosilane, and a step d) in which a silahydrocarbon compound is obtained in a hydrosilylation reaction.

专利号:US-4762935-A
优先权日:1986-10-06
标题:Precursors and synthesis of methyl-9-oxo-11α,16-dihydroxy-16-vinyl-5-cis-13-trans-prostadienoates
发明人：WISSNER ALLAN; GREEN KENNETH E; HAMANN PHILIP R; LEVIN JEREMY
权利人:AMERICAN CYANAMID CO
摘要:This disclosure describes novel compounds which are useful as precursors in the synthesis of 9-oxo-11α,16-dihydroxy-16-vinyl-5-cis-13-trans-prostadienoate esters which possess activity as hypotensive agents and/or as vasodilators.

专利号:US-11306157-B2
优先权日:2018-12-21
标 题:Expedient synthesis of core disaccharide building blocks from natural polysaccharides for heparan sulfate oligosaccharide assembly
发明人：HSIEH-WILSON LINDA C; PAWAR NITIN J; WANG LEI
权利人:CALIFORNIA INST OF TECHN
摘要:Methods for the preparation of oligosaccharide products from polysaccharide starting materials are disclosed. The methods include: hydrolyzing a glucosamine-containing polysaccharide starting material, such as heparin or heparosan, under conditions sufficient to form an oligosaccharide intermediate (e.g., a GlcN-IdoA disaccharide intermediate or a GlcA-GlcN disaccharide intermediate), and converting the oligosaccharide intermediate to the oligosaccharide product. Conversion of the oligosaccharide intermediates to the oligosaccharide products may include one or more esterification, acylation, epimerization, protection, and deprotection steps. Preparation of higher-order oligomers is described, as well as methods for selective oligosaccharide sulfation.

专利号:US-2005130221-A1
优先权日:2001-02-01
标 题:Synthesis for the preparation of compounds for screening as potential tubulin binding agents
发明人：FLYNN BERNARD L; HAMEL ERNEST
权利人:US GOV HEALTH & HUMAN SERV
摘要:The present invention relates to methods for the synthesis of chemical compounds for screening as potential tubulin polymerization inhibitors. The invention also provides chemical compounds with tubulin polymerization inhibitor activity.

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主要参考文献

[参考文献]: Carolin Hobler, Et Al. Sex-Dependent Aromatase Activity In Rat Offspring After Pre- And Postnatal Exposure To Triphenyltin Chloride. Toxicology. 2010 Oct 29;276(3):198-205.
[参考文献]: Fernando Cesar Perina, Et Al. Comparative Toxicity Of Antifouling Compounds On The Development Of Sea Urchin. Ecotoxicology. 2011 Nov;20(8):1870-80.
[参考文献]: Hajime Takeuchi, Et Al. Retinoid X Receptor Agonists Modulate Foxp3 Regulatory T Cell And Th17 Cell Differentiation With Differential Dependence On Retinoic Acid Receptor Activation. J Immunol. 2013 Oct 1;191(7):3725-33.
[参考文献]: Huahong Shi, Et Al. Divergent Teratogenicity Of Agonists Of Retinoid X Receptors In Embryos Of Zebrafish (Danio Rerio). Ecotoxicology. 2012 Jul;21(5):1465-75.
[参考文献]: Jing Yuan, Et Al. Stage-Specific Malformations And Phenotypic Changes Induced In Embryos Of Amphibian (Xenopus Tropicalis) By Triphenyltin. Ecotoxicol Environ Saf. 2011 Oct;74(7):1960-6.

合成参考文献


参考文献:10.3724/sp.j.1123.2011.00353
摘要:Li Y, Hu Y, Liu J, Guo Y, Wang G. [Determination of organotin compounds in textile auxiliaries by gas chromatography-mass spectrometry]. Se Pu. 2011 Apr;29(4):353–7. doi: 10.3724/sp.j.1123.2011.00353.
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