CAS: 70591-20-7; 2-((Diphenylmethylene)Amino)Acetonitrile

上下游产品

Benzophenone imine 2-aminoacetonitrile hydr°Chloride sodium cyanide trimethylammoniumiodid(Diphenylmethylen)aminomethyltrimethylammoniumiodid-1-cyclopentanecarbonitrile1-(Diphenylmethylene)-amino-1-cyclopentanecarbonitrile 2-(N-diphenylmethylene)amino-3-(1H-indol-3-yl)propionitrile 3-cyano-1,1,4-triphenyl-2-aza-1,3-butadiene

二苯甲酮肟置于吡啶,[ir(Df(Cf3)Ppy)2(Dtbbpy)](Pf6)体系中,用 二氯甲烷 作为反应溶剂,化学反应 2.0H,反应生成 二苯亚甲基氨基乙腈
参考文献:直接c(sp3)-N自由基偶联:通过非常规分子间氢原子转移到芳基自由基的光催化ch官能化.
标题:直接c(sp3)-N自由基偶联:通过非常规分子间氢原子转移到芳基自由基的光催化ch官能化.
摘要:通过使用o-苯甲酰肟对简单烷基底物进行光催化c(sp 3)-H活化,已经开发出一种非常规的分子间直接c(sp 3)-N自由基偶联方法.选择性光催化能量转移驱动的均质反应,然后进行脱羧,反应生成持久的亚氨基和芳基,它们会经历从烷基底物空前的分子间氢原子提取,从而提供关键的c(sp 3)自由基.选择性自由基-自由基c-N交叉偶联提供了亚胺,它们是有价值的胺结构单元.
DOI:10.1021/acs.Orglett.0C02179

专利信息

专利号:US-6207858-B1
优先权日:1999-03-03
标 题 :Regioselective synthesis of DTPA derivatives
发明人：CHINN PAUL; GYORKOS ALBERT; LABARRE MICHAEL J; RUHL STEVE; RYSKAMP THOMAS
权利人:IDEC PHARMA CORP
摘要:The present invention provides a process for high yield regioselective synthesis of DTPA derivatives that eliminates the need for ion exchange chromotographic separation of intermediates. Moreover, as this process yields a single regioisomer of the chelate, it provides for the regiospecific synthesis of desired chelates useful as radiolabeling agents.

专利号:US-7737284-B2
优先权日:2001-01-18
标题 :Synthesis of temozolomide and analogs
发明人：KUO SHEN-CHUN; MAS JANET L; HOU DONALD CHEN-TUNG
权利人:SCHERING PLOUGH CORP
摘要:This invention relates to a novel process for the synthesis of Temozolomide, an antitumor compound, and analogs, and to intermediates useful in this novel process.

专利号:US-2013012706-A1
优先权日:2010-03-01
标 题 :Methods and Intermediates for the Synthesis of 4-oxo-3,4-dihydro-imidazo[5,1-d][1,2,3,5]tetrazines
发明人：HUMMERSONE MARC GEOFFERY; COUSIN DAVID
权利人:PHARMINOX LTD; HUMMERSONE MARC GEOFFERY; COUSIN DAVID
摘要:The present invention provides a compound of general formula (II), or a salt or solvate thereof: n n n n n n n n n n n n wherein n A is independently -A 1 , -A 2 , -A 3 , -A 4 , -A 5 , -A 6 , or -A 7 , wherein:n -A 1 is independently C 5-12 heteroaryl, and is optionally substituted; -A 2 is independently thioamido or substituted thioamido; -A 3 is independently imidamido, substituted imidamido, N-hydroxyimidamido, or substituted N-hydroxyimidamido; -A 4 is independently hydroxamic acid or hydroxamate; -A 5 is independently carboxamide or substituted carboxamide; -A 6 is independently aliphatic C 2-6 alkenyl, and is optionally substituted; and -A 7 is independently carboxy or C 1-4 alkyl-carboxylate;n nand its use in the synthesis of temozolomide and analogues thereof.

专利号:US-2005131227-A1
优先权日:2001-01-18
标 题:Synthesis of temozolomide and analogs

专利号:US-2006229456-A1
优先权日:2001-01-18
标 题:Synthesis of Temozolomide and analogs

专利号:WO-02057269-A1
优先权日:2001-01-18
标题:Synthesis of temozolomide and analogs