CAS: 629-45-8; Dibutyldisulfide

上下游产品

1-bromo-butane tetrachloromethane sodium 1-buthanethiolate vinyl acetate1,2-bis-butylsulfanyl-1-phenyl-ethane butyl methyl disulfide 4-butyldisulfanyl-3-nitro-benzoic acid n-butyl methyl sulfide

丙烷-1-硫醇置于magnetic Ion Exchanged Montmorillonite-K10体系中,用 四氢呋喃 作为反应溶剂,化学反应 1.0H,以91%的收率获得产物二丁基二硫
参考文献:使用可回收的磁性纳米粒子将硫醇氧化二聚为二硫键
标题:使用可回收的磁性纳米粒子将硫醇氧化二聚为二硫键
摘要:摘要 巯基二聚为二硫键是化学过程中的重要转变.在这项研究中,合成了磁性离子交换的蒙脱石-K10,并使用ftir,X射线衍射和扫描电子显微镜技术对其进行了表征.然后,在最佳反应条件下,在不同硫醇氧化二聚为相应的二硫化物的过程中,评估了合成催化剂作为有效氧化剂的应用.用芳族,脂族和杂环硫醇容易地进行反应.通过施加外磁体可以容易地回收磁性催化剂,并且进一步将其再用于后续反应中. 图形概要
DOI:10.1007/s11164-016-2718-1

专利信息

专利号:US-2012184653-A1
优先权日:2011-01-18
标 题:Synthesis of linear phosphorus-containing functional fluorocopolymer
发明人：WANG LIANG; WANG VIKTORIA
权利人:WANG LIANG; WANG VIKTORIA
摘要:This invention relates to a synthesis of a linear fluorocopolymer having a plurality of pendant phosphorus-containing functional groups. The synthesized phosphorus-containing fluorocopolymer has chain linearity and narrow molecular weight distributions. It has applications as a lubricant additive that provides friction-reduction, anti-wear, and corrosion protection properties.

专利号:US-2015018579-A1
优先权日:2012-02-22
标题:Synthesis of high purity dmt-c3-disulfide phosphoramidite
发明人：SRIVASTAVA SURESH C; THATIKONDA SANTHOSH K; SHUKLA PRAVEEN; SRIVASTAV SANT KUMAR
权利人:SRIVASTAVA SURESH C; THATIKONDA SANTHOSH K; SHUKLA PRAVEEN; SRIVASTAV SANT KUMAR
摘要:The 5′ and 3′-thiol modified oligonucleotides are attractive tools with a vast number of potential applications in the field of nucleic acid chemistry. There is a strong interest in developing new disulfide compounds or to optimize synthesis of existing disulfide modifiers, which are efficient in generating the 3′- or 5′-end reactive thiol group. Various synthetic protocols have been employed to synthesize pure 3-((3-(bis(4-dimethoxytrityl)propyl)di-sulfanyl)propyl 2-cyanoethyl diisopropylphosphoramidite (compound 2) starting from 3-(dimethoxytrityl)propyl)disulfanyl)pro-pan-1-ol, (compound 1). Herein, we describe an efficient, reproducible synthetic and purification protocol for target compound 2 from the compound 1. It is noteworthy that our reaction conditions were reproducible even at multi-gram scale (27 g) with a purity level as achieved in a small scale.

专利号:US-5239052-A
优先权日:1990-08-30
标 题 :Process for synthesis of aromatic sulfides
发明人：HAY ALLAN S; WANG ZHI Y
权利人:HAY ALLAN S; WANG ZHI Y
摘要:Aromatic sulfides including diarylsulfides and poly(arylene sulfides) are produced in a novel synthesis in high yield under moderate conditions by heating an aromatic disulfide in the presence of aromatic halide, in which the halide is chloride, bromide or iodide; the diaryl sulfides are useful precursors and starting materials for a range of compounds and the poly(arylene sulfides) are important high temperature engineering thermoplastics.

专利号:US-5177183-A
优先权日:1990-08-30
标 题:Process for synthesis of aromatic sulfides
发明人：HAY ALLAN S; WANG ZHI Y
权利人:HAY ALLAN S; WANG ZHI Y
摘要:Aromatic sulfides including diarylsulfides and poly(arylene sulfides) are produced in a novel synthesis in high yield under moderate conditions by heating an aromatic disulfide in the presence of aromatic halide, in which the halide is chloride, bromide or iodide; the diaryl sulfides are useful precursors and starting materials for a range of compounds and the poly(arylene sulfides) are important high temperature engineering thermoplastics.

专利号:US-6432294-B1
优先权日:2000-12-14
标题 :Electrochemical activation of organic disulfides for electrophilic substitution
发明人：GLASS RICHARD S; JOUIKOV VIATCHESLAV V; BOJKOVA NINA V
权利人:UNIV ARIZONA
摘要:Electrochemical oxidation of organic disulfides is conducted in an electrolytic solution containing an arene (e.g., anthracene, acenaphthylene, phenanthrene), and depending on the arene used and/or the product desired, an organic base (e.g., pyridine) to effect the synthesis of organothiated products in good yields.

专利号:US-5113019-A
优先权日:1987-11-27
标 题:Process for phenol alkylthiolation and its application to the synthesis of 4-acyl-2-alkylthiophenols
发明人：VOTTERO CATHERINE; LABAT YVES; POIRIER JEAN-MARIE
权利人:ELF AQUITAINE
摘要:The invention relates to the preparation of alkylthiophenols by reaction of a dialkyl disulphide with a phenol. n In the process according to the invention, the reaction is carried out in the presence of aluminum chloride or of ferric chloride in a solvent of the alkylbenzene type or, soley in the case of methylthiolation, in an excess of dimethyl disulphide. n This process makes it possible, in particular to obtain, with a selectivity and in a yield which are excellent, 2-alkylthiophenols which may then be converted into 4-acyl-2-alkylthiophenols by means of a reaction at a temperature ranging from 40° to 100° C. with a complex BF 3 :2RCOOH where R denotes an alkyl or propenyl radical, in a proportion of 10 to 15 moles of complex per mole of 2-alkylthiophenol.