2,4-二硝基苯胺置于氯仿,Bf3-N2O3体系中,化学反应生成 颜料橙 5 参考文献:Bachman; Hokama,Journal Of The American Chemical Society,1957,Vol. 79,P. 4370,4372 标题:Bachman; Hokama,Journal Of The American Chemical Society,1957,Vol. 79,P. 4370,4372
专利号:US-4255578-A 优先权日:1978-11-02 标题 :Synthesis of perhalomethylcarbinol-substituted phenol and naphthol sulfamphthalein dyes from the corresponding triacylated derivatives 发明人:CINCOTTA LOUIS; FOLEY JAMES W 权利人:POLAROID CORP 摘要:The present invention is concerned with a method of synthesizing certain ##STR1## 3-disubstituted sulfam(na)phthalein compounds useful as pH-sensitive indicator dyes and with intermediates useful in the preparation of said compounds. The subject method comprises (1) reacting (a) a 3,3-disubstituted sulfam(na)phthalein wherein one of the 3-substituents is a 4'-hydroxy-1'-phenyl moiety or a 4'-hydroxy-1'-naphthyl moiety substituted in the 3'-position with a perhalomethylcarbinol group and (b) an acid halide, ##STR2## wherein R is alkyl or aryl to give (c) an acylated intermediate wherein the N atom of the sulfam(na)phthalein ring and the 4'-hydroxy and carbinol hydroxy groups are acylated with ##STR3## and (2) treating said compound (c) with alkali to selectively remove said ##STR4## from said hydroxy groups and yield the ##STR5## product. The intermediates of the present invention are the acylated compounds (c).
专利号:US-4210752-A 优先权日:1978-11-02 标题 :Synthesis of substituted sulfam(na)phthaleins 发明人:CINCOTTA LOUIS; FOLEY JAMES W 权利人:POLAROID CORP 摘要:The present invention is concerned with synthesizing certain ##STR1## by reacting (a) a 3,3-disubstituted sulfam(na)phthalein wherein one of the 3-substituents is a 4'-hydroxy-1'-phenyl moiety or a 4'-hydroxy-1'-naphthyl moiety substituted in the 3'-position with a perhalomethylcarbinol group and (b) an acid halide, ##STR2## wherein W is chloro or bromo and Y is hydrogen or an electron-withdrawing group, preferably, in the presence of a zeolite molecular sieve or acid alumina to give (c) the corresponding ##STR3## The compounds produced are useful, for example, as pH-sensitive indicator dyes or as photographic light-screening dyes.
专利号:US-7432031-B2 优先权日:2005-03-22 标 题:Toner for electrostatic charge developing, production method thereof, developer for electrostatic charge developing using the same, and image forming method 发明人:MIZUTANI NORIYUKI; MAEHATA HIDEO; HAMANO HIROKAZU; TANAKA HIROYUKI; KITAGAWA SOICHIRO; IGUCHI MOEGI 权利人:FUJI XEROX CO LTD 摘要:A toner for electrostatic charge developing prepared by a production method including aggregating one or more kind of particles in a raw material dispersion including the particles to form aggregated particles, and coalescing the aggregated particles by heating. At least one kind of the particles is resin particles including an amorphous polyester resin synthesized by copolymerizing one or more polyvalent carboxylic acids and two or more polyhydric alcohols; at least one of the polyvalent carboxylic acids is polyvalent carboxylic acid having a sulfonic acid group; two of the polyhydric alcohols are an ethylene oxide adduct of bisphenol A and a propylene oxide adduct of bisphenol A; and the following equation is satisfied:n n10/90≦ BPA ( EO )/ BPA ( PO )≦90/10.n n In the equation, BPA(EO) represents a total mole amount of the ethylene oxide adduct of bisphenol A used in synthesis of the amorphous polyester resin, and BPA(PO) represents a total mole amount of the propylene oxide adduct of bisphenol A used in synthesis of the amorphous polyester resin.
专利号:CN-116355231-B 优先权日:2023-04-10 标题 :Synthesis and preparation method of EB (electron beam) curing coating for metal coiled material
专利号:CN-116355231-A 优先权日:2023-04-10 标 题:Synthesis and preparation method of EB cured coating for metal coil
专利号:CN-119775531-A 优先权日:2024-12-26 标题:Synthesis method and application of intrinsic conductive epoxy resin
[参考文献]: P Mller, Et Al. Dna Damage In Isolated Rat Hepatocytes Exposed To C.I. Pigment Orange 5 And C.I. Pigment Yellow 12 By The Alkaline Comet Assay. Teratog Carcinog Mutagen. 1998;18(1):9-16.
合成参考文献
摘要:Lyman WJ et al; Handbook of Chemical Property Estimation Methods. Washington, DC: Amer Chem Soc pp. 7-4, 7-5, 8-12 (1990) 摘要: 摘要:Moller P et al; Teratog Carcinog Mutagen 18 (1): 9-16 (1998); Erratum in: Teratog Carcinog Mutagen 21 (1): 107 (2001) 摘要:Lewis, R.J. Sr.; Hawley's Condensed Chemical Dictionary 15th Edition. John Wiley & Sons, Inc. New York, NY 2007., p. 456 摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)