CAS: 23526-45-6; (S)-4-Hydroxy-4-((R,E)-3-Hydroxybut-1-En-1-yl)-3,5,5-Trimethylcyclohex-2-En-1-One
- 英文名称(S)-4-Hydroxy-4-((R,E)-3-Hydroxybut-1-En-1-yl)-3,5,5-Trimethylcyclohex-2-En-1-One
- 中文名称吐叶醇
- IUPAC名称Vomifoliol
- 其它别名(+-)-6-Hydroxy-3-Oxo-Alpha-Ionol; (4S)-4-Hydroxy-4-[(E,3R)-3-Hydroxybut-1-Enyl]-3,5,5-Trimethylcyclohex-2-En-1-One; 2-Cyclohexen-1-One, 4-Hydroxy-4-((1E,3R)-3-Hydroxy-1-Butenyl)-3,5,5-Trimethyl-, (4S)-; (6S,9R)
- CAS编号23526-45-6
- MFCD编号:MFCD20260591
- FDA UNII编号:B7QV234K84
- 分子式:C13H20O3分子量:224.3
- 产品CID: 1177362
- 产品分类天然产物 → 倍半萜
物理性质
- 熔点115 °C
- 沸点362.3±42.0 °C(预测)
- 闪点187.1 °C
- 密度1.130±0.06 g/cm3(预测)
- pKa:12.72±0.60(预测)
- PSA:57.53
- LogP:1.479 (est)
- 折射率1.567
- 蒸汽压1.03E-06 mmHg at 25 °C
- 溶解性Soluble In Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,Etc.
- 外观形态白色至类白色粉末
- 储存条件存放温度应控制在2-8°C,需保持干燥并密闭保存.
- 产品应用该化合物是一种与腹痛酸有关的化合物,配有经修改的2,4-苯丁二烯基副链,其生物活动与ABA相似.
上下游产品
(6S,9R)-roseoside zizyvoside I (+)-(S)-dehydrovomifoliol vomifoliol acetate(+)-(S)-dehydrovomifoliol 2,2-Dimethyl-propionic acid (2R,3R,4S,5R,6R)-4,5-bis-(2,2-dimethyl-propionyloxy)-6-(2,2-dimethyl-propionyloxymethyl)-2-[(E)-(R)-3-((S)-1-hydroxy-2,6,6-trimethyl-4-oxo-cyclohex-2-enyl)-1-methyl-allyloxy]-tetrahydro-pyran-3-yl ester (6S,9R)-roseoside (6S,7E,9S)-6,9-dihydroxy-4,7-megastigmadien-3-one合成工艺路线路线简述
📜长寿花糖甙置于β-Glucosidase体系中,化学反应 48.0H,以11 Mg的收率获得吐叶醇
参考文献:Megastigmane Glycosides From Seeds Of Trifoliumalexandrinum
标题:Megastigmane Glycosides From Seeds Of Trifoliumalexandrinum
摘要:Five Megastigmane Glycosides Have Been Isolated From The Seeds Of Trifolium Alexandrinum L.,Of Which Two Are Known Compounds,While Three Are New Compounds Showing The Presence Of Apiofuranosyl-(1--> 2)-Glucopyranosyl Residue As A Sugar Moiety. The Structures Of The Isolated Compounds Were Established On The Basis Of NMR And Mass Spectral Data. (C) 1999 Elsevier Science Ltd. All Rights Reserved.
Doi:10.1016/s0031-9422(98)00603-7
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905143000-叔丁醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1016/0031-9422(96)00258-0
摘要:Luyengi L, Suh N, Fong HH, Pezzuto JM, Kinghorn AD. A lignan and four terpenoids from Brucea javanica that induce differentiation with cultured HL-60 promyelocytic leukemia cells. Phytochemistry. 1996 Sep;43(2):409–12. doi: 10.1016/0031-9422(96)00258-0.
参考文献:10.1248/cpb.56.843
摘要:Wang Y, Li Z, Zhang H, Sha Y, Pei Y, Hua H. New germacrane sesquiterpenes from Salvia chinensis. Chem Pharm Bull (Tokyo). 2008 Jun;56(6):843–6. doi: 10.1248/cpb.56.843.
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