CAS: 23389-75-5; 4-(1-Hydroxyethyl)Pyridine

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CAS号1122-54-9 4-乙酰基吡啶 | CAS号75-29-6 2-氯丙烷 | CAS号872-85-5 4-吡啶甲醛 | CAS号75-16-1 甲基溴化镁 | CAS号54401-85-3 4-吡啶乙酸乙酯 | CAS号536-75-4 4-乙基吡啶 | CAS号925-90-6 乙基溴化镁 | CAS号18006-13-8 三异丙醇甲基钛 | CAS号917-64-6 甲基碘化镁 | CAS号2555-02-4 1-(4-Pyridyl)et... | CAS号50392-78-4 1-(4-吡啶基)乙胺 | CAS号54656-96-1 (S)-(-)-4-吡啶-1-乙醇 | CAS号27854-88-2 (R)-1-(吡啶-4-基)乙醇 | CAS号6457-48-3 1-(4-哌啶基)乙醇 | CAS号32064-89-4 Ethanone,1-(4-p... | CAS号1122-54-9 4-乙酰基吡啶

📜4-乙酰吡啶置于c26H33Cln5Ru(1+)*bf4(1-),Potassium Tert-Butylate体系中,用 异丙醇 用作溶剂,化学反应 0.5H,以98%的收率获得1-(4-吡啶基)乙醇
参考文献:1,2,3-三唑/三唑亚烷基侧基的异位ru(II)-和ir(III)-Nhc配合物:对不饱和化合物转移加氢的立体电子影响
标题:1,2,3-三唑/三唑亚烷基侧基的异位ru(II)-和ir(III)-Nhc配合物:对不饱和化合物转移加氢的立体电子影响
摘要:咪唑-2-亚烷基(imnhc)和1,2,3-三唑-5-亚烷基(tznhc)已被确定为均相催化中卡宾配体的重要类别.考虑到氢化物转移反应的电子和空间分布,基于这些配体系统开发ru(II)/ Ir(III)配合物,我们采用了以imnhc和三唑-N或由ch桥接的中型tznhc供体为特征的螯合配体2个在三唑主链上可能经过修饰的间隔子 通常,发现合成的ru(II)配合物在还原酮和醛亚胺方面的性能明显优于类似的ir(III)配合物.在ru(II)配合物中,通式[(p-Cymene)(imnhc-ch)的富电子配合物8/92-Tznhc)的ru Ii(cl)] Bf 4具有两个不同的卡宾供体(imnhc和tznhc)被发现显着地在酮还原更好执行比imnhc和三唑的组合类似络合物ñ端供体([(p-Cymene)(imnhc-ch 2-tz-n)ru Ii(cl)] Bf 4;4)解释了催化系统的
Doi:10.1021/acs.Organomet.9B00156

专利信息

专利号:US-7579294-B2
优先权日:2004-12-29
标题:Synthesis of supported transition metal catalysts
发明人：PARK JAIWOOK; KIM NAMDU; KWON MIN SERK; PARK CHEON MIN
权利人:POSTECH FOUNDATION
摘要:A highly active and recyclable supported transition metal catalyst can be prepared by a simple process comprising mixing with heating a transition metal complex, a metal-chelating agent and an alkoxide of Ti, Al or Si, followed by treatment with water to induce a sol-gel reaction among the reactants.

专利号:US-4546198-A
优先权日:1983-01-18
标 题 :Asymmetric synthesis of esters and acids
发明人：STOUTAMIRE DONALD W
权利人:SHELL OIL CO
摘要:Stereoisomerically-enriched esters are prepared by treating a non-symmetrical ketene with a racemic or chiral tertiary-base-substituted alkylcarbinol. Optional hydrolysis of the esters gives the corresponding optically-active carboxylic acids corresponding to the non-symmetrical ketene.

专利号:US-2009137385-A1
优先权日:2004-12-29
标 题 :Synthesis of supported transition metal catalysts

专利号:WO-9725992-A1
优先权日:1996-01-16
标 题 :Tocolytic oxytocin receptor antagonists
发明人：SPARKS MICHELLE A; FRIEDINGER ROGER M; PERLOW DEBRA S; WILLIAMS PETER D
权利人:MERCK & CO INC; SPARKS MICHELLE A; FRIEDINGER ROGER M; PERLOW DEBRA S; WILLIAMS PETER D
摘要:This invention relates to certain novel benzoxazinone compounds and derivatives thereof, their synthesis, and their use as oxytocin receptor antagonists. One application of these compounds is in the treatment of preterm labor. The ability of the compounds to relax uterine contractions in mammals also makes them useful for treating dysmenorrhea and stopping labor prior to cesarean delivery.

专利号:US-5726172-A
优先权日:1996-01-16
标题 :Tocolytic oxytocin receptor antagonists
发明人：SPARKS MICHELLE A; FREIDINGER ROGER M; PERLOW DEBRA S; WILLIAMS PETER D
权利人:MERCK & CO INC
摘要:This invention relates to certain novel benzoxazinone compounds and derivatives thereof, their synthesis, and their use as oxytocin receptor antagonists. One application of these compounds is in the treatment of preterm labor. The ability of the compounds to relax uterine contractions in mammals also makes them useful for treating dysmenorrhea and stopping labor prior to cesarean delivery. A typical compound is as follows:

专利号:KR-100224153-B1
优先权日:1994-03-28
标 题 :Method of synthesis for 6,9-bis((2-aminoethyl)amino)benzo(g)isoquinoline-5, 10-dione and its dimaleate salt