CAS: 120-51-4; Benzyl Benzoate

相似化合物

100-51-6 65-85-0 1079-02-3

上下游产品

CAS号93-58-3 苯甲酸甲酯 | CAS号100-51-6 苯甲醇 | CAS号93-97-0 苯甲酸酐 | CAS号65-85-0 苯甲酸 | CAS号2902-69-4 2,2,2-三氯苯乙酮 | CAS号100-52-7 苯甲醛 | CAS号591-50-4 碘苯 | CAS号201230-82-2 carbon monoxide | CAS号532-32-1 苯甲酸钠 | CAS号620-05-3 苄基碘 | CAS号10578-34-4 硬脂醇苯甲酸酯 | CAS号583-04-0 苯甲酸烯丙酯 | CAS号76-84-6 三苯基甲醇 | CAS号5333-62-0 (diphenyl-pheny... | CAS号65-85-0 苯甲酸 | CAS号93-89-0 苯甲酸乙酯 | CAS号100-39-0 溴化苄 | CAS号451-40-1 二苯乙酮 | CAS号103-29-7 1, 2-二苯乙烷 | CAS号1753-62-4 1-苄基1,2-二氢吡啶-2-酮

苯基乙炔基三甲基硅烷置于oxone,Potassium Chloride,三乙胺体系中,用 水,乙腈 用作溶剂,化学反应 0.5H,反应生成苯甲酸苄酯
参考文献:炔基硅烷与 Oxone-Kx (X = Cl,Br,I) 的反应及其一锅法转化为酰胺/酯的研究
标题:炔基硅烷与 Oxone-Kx (X = Cl,Br,I) 的反应及其一锅法转化为酰胺/酯的研究
摘要:使用 Oxone 作为温和氧化剂和 Kcl,Kbr 和 Ki 作为卤素源研究了各种炔基硅烷的氧卤化反应.在这项研究中,炔基硅烷与 Oxone-Kx(x = Cl 或 Br)的反应以高产率产生了三氯甲基/三溴甲基酮.然而,在类似条件下,发现炔基硅烷与 Oxone-Ki 的反应以高产率仅产生 1,2,2-三碘乙烯基衍生物.在这项研究中,开发了通过三卤甲基酮分别与胺和醇反应,将炔基硅烷有效地一锅法转化为酰胺和酯的新方法.
Doi:10.1246/cl.161171

专利信息

专利号:US-6770436-B1
优先权日:1996-11-14
标题:Chemical amplification for the synthesis of patterned arrays
发明人：BEECHER JODY E; GOLDBERG MARTIN J; MCGALL GLENN H
权利人:AFFYMETRIX INC
摘要:Radiation-activated catalysts (RACs), autocatalytic reactions, and protective groups are employed to achieve a highly sensitive, high resolution, radiation directed combinatorial synthesis of pattern arrays of diverse polymers. When irradiated, RACs produce catalysts that can react with enhancers, such as those involved in autocatalytic reactions. The autocatalytic reactions produce at least one product that removes protecting groups from synthesis intermediates. This invention has a wide variety of applications and is particularly useful for the solid phase combinatorial synthesis of polymers.

专利号:US-2006287520-A1
优先权日:2005-05-16
标 题 :Synthesis of salinosporamide A and analogues thereof
发明人：DANISHEFSKY SAMUEL J; ENDO ATSUSHI
权利人:DANISHEFSKY SAMUEL J; ENDO ATSUSHI
摘要:A novel synthesis of salinosporamide A is provided. Salinospoamide A as well as structurally related natural products, omuralide and lactacystin, have been shown to be proteasome inhibitors. Therefore, these compounds as well as analogues of these natural products may be useful in the treatment of proliferative diseases such as cancer, autoimmune diseases, diabetic retinopathy, etc. The invention provides for the synthesis of salinosporamide A as well as analogs thereof using a convenient point for derivatization of the bicyclic core. Pharmaceutical compositions and method of using the inventive compounds are also provided.

专利号:US-7288661-B2
优先权日:2003-12-10
标 题 :Process for the synthesis of (2S,3aS,7aS)-1-[(S)-alanyl]-octahydro-1H-indole-2-carboxylic acid compounds and application in the synthesis of perindopril
发明人：DUBUFFET THIERRY; LECOUVE JEAN-PIERRE
权利人:SERVIER LAB
摘要:Process for the synthesis of compounds of formula (I): n nwherein R represents a hydrogen atom or a protecting group for the amino function.n n Application in the synthesis of perindopril and pharmaceutically acceptable salts thereof.

专利号:US-6818777-B2
优先权日:2000-12-07
标 题:Intermediates for synthesis of vinblastine compound and method for synthesizing the intermediate
发明人：FUKUYAMA TOHRU; TOKUYAMA HIDETOSHI
权利人:JAPAN SCIENCE & TECH AGENCY
摘要:Intermediates A, which are important in the whole synthesis of vindoline; and a method of synthesizing intermediates respectively represented by the general formulae B and C. By the method, the target intermediates are effectively synthesized with satisfactory reproducibility. This synthesis method is especially suitable for mass production. General formula A General formula B General formula C.

专利号:US-4242256-A
优先权日:1977-03-15
标 题 :Synthesis of peptide analogues
发明人：SHARPE ROBERT; SZELKE MICHAEL
权利人:SHARPE ROBERT; SZELKE MICHAEL
摘要:Compounds being analogues of a dipeptide in which the nitrogen atom of the linking amide group of the dipeptide is replaced by trivalent group ##STR1## and in which, optionally, the carbonyl function of this linking group is replaced by the divalent group --CH 2 -- are of value in the synthesis of isosterically modified peptides.

专利号:EP-1724260-B1
优先权日:2005-05-06
标题:Process for the synthesis of (2S, 3aR, 7aS)octahydroindole-2-carboxylic acid and its conversion to trandolapril
发明人：AKHTAR HAIDER; RAMESH BABU POTLURI; VENKATA SUBHRAMANIAN HARIHARAK; HARI PRASSAD KODALI
权利人:SOCHINAZ SA
摘要:The present invention describes a novel method for the synthesis of (2S,3aR,7aS)-octahydroindole-2-carboxylic acid of formula III nusing a new intermediate of formula II nand conversion of the product of formula-III to trandolapril of formula I