2-(2-{[(Dimethoxytrityl)Oxy]Ethoxy}Ethoxy)Ethanol置于sodium Periodate体系中,用 丙酮 用作溶剂,化学反应 16.0H,反应生成三乙二醇 参考文献:Selective Cleavage Of O-(Dimethoxytrityl) Protecting Group With Sodium Periodate 标题:Selective Cleavage Of O-(Dimethoxytrityl) Protecting Group With Sodium Periodate 摘要:在水有机溶剂中,过碘酸钠在温和的反应条件下选择性地去除了o-(二甲氧基三苯甲基)保护基团.利用核苷衍生物进行了裂解的选择性研究,这些核苷衍生物受到核苷和核苷酸化学中常用的各种基团的保护. Doi:10.1135/cccc20020502
专利号:WO-2009018504-A1 优先权日:2007-08-01 标题 :Process for the synthesis of diaminopyridine and related compounds 发明人:RITTER JOACHIM C 权利人:DU PONT; RITTER JOACHIM C 摘要:A process is provided for the synthesis of a diaminopyridine, such as 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a chlorine-ammonia displacement in the presence of a copper source.
专利号:US-8735317-B2 优先权日:2009-06-16 标 题 :Catalyst for synthesis of hydrocarbons from CO and H2 and preparation method thereof 发明人:MORDKOVICH VLADIMIR ZALMANOVICH; SINEVA LILIA VADIMOVA; SOLOMONIK IGOR GRIGORIEVICH; ERMOLAEV VADIM SERGEEVICH; MITBERG EDUARD BORISOVICH 权利人:MORDKOVICH VLADIMIR ZALMANOVICH; SINEVA LILIA VADIMOVA; SOLOMONIK IGOR GRIGORIEVICH; ERMOLAEV VADIM SERGEEVICH; MITBERG EDUARD BORISOVICH; INFRA XTL TECHNOLOGY LTD 摘要:The present invention relates to petrochemistry, gas chemistry, coal chemistry, particularly the invention relates to a catalyst for synthesis of hydrocarbons from CO and H 2 and a preparation method thereof. The catalyst is pelletized and comprises at least Raney cobalt as active component in an amount of 1-40% by weight based on the total weight of the catalyst, metallic aluminium in an amount of 25-94% by weight based on the total weight of the catalyst and a binder in an amount of 5-30% by weight based on the total weight of the catalyst. The present invention provides the catalyst stability to overheating and high productivity of hydrocarbons C 5 -C 100 for synthesis of hydrocarbons from CO and H 2 .
专利号:US-9196482-B2 优先权日:2011-06-01 标题:Solution-based synthesis of CsSnI3 发明人:SHUM KAI; CHEN ZHUO; REN YUHANG 权利人:SHUM KAI; CHEN ZHUO; REN YUHANG 摘要:This invention discloses a solution-based synthesis of cesium tin tri-iodide (CsSnI 3 ) film. More specifically, the invention is directed to a solution-based drop-coating synthesis of cesium tin tri-iodide (CsSnI 3 ) films. CsSnI 3 films are ideally suited for a wide range of applications such as light emitting and photovoltaic devices.
专利号:US-8840809-B2 优先权日:2011-06-01 标 题 :Solution-based synthesis of CsSnI3 thin films 发明人:SHUM KAI; CHEN ZHUO; REN YUHANG 权利人:SHUM KAI; CHEN ZHUO; REN YUHANG 摘要:This invention discloses a solution-based synthesis of cesium tin tri-iodide (CsSnI 3 ) film. More specifically, the invention is directed to a solution-based spray-coating synthesis of cesium tin tri-iodide (CsSnI 3 ) thin films. This invention is also directed to effective and inexpensive methods to synthesize the thin CsSnI 3 films on large-area substrates such as glass, ceramics, glass, ceramic, silicon, and metal foils. CsSnI 3 films are ideally suited for a wide range of applications such as light emitting and photovoltaic devices.
专利号:WO-9900440-A1 优先权日:1997-06-26 标 题:Synthesis of a dendritic polyalcohol 发明人:IHRE HENRIK; HULT ANDERS 权利人:PERSTORP AB; IHRE HENRIK; HULT ANDERS 摘要:A process for a double stage convergent synthesis of a polymeric polyalcohol substantially and preferably built up from polyester units and composed of a monomeric or polymeric core to which at least one hyperbranched dendritic branch (dendron) consisting of a number of branching generations is added. The branching generations comprise a polymeric or monomeric branching chain extender having three reactive functions of which two are hydroxyl groups and one is a carboxyl group. The two hydroxyl groups of the branching chain extender is in a first step ketal protected by reacting said two hydroxyl groups with a ketal. A second step includes protection of the carboxyl group of said branching chain extender. The ketal protected branching chain extender and the carboxyl protected chain extender are then employed for repeated addition in a number of step yielding a predetermined number of branching generations. The thus synthesized dendron is finally added to a core having reactive hydroxyl or epoxide groups and the ketal protected hydroxyl groups are optionally deprotected.
专利号:EP-1431274-B1 优先权日:2002-12-18 标题 :Synthesis of mono-N-substituted functionalized anilines 发明人:SELVA MAURIZIO; TUNDO PIETRO 权利人:CONSORZIO INTERUNIVERSITARIO N 摘要:The present invention relates to a process for direct and selective synthesis of mono-N-substituted functionalized anilines by using alkylating agents selected from the class of organic carbonates, preferably of the dialkyl, dibenzyl and diallyl types, in the presence of suitable catalysts that are chemically related to the class of aluminosilicates.
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合成参考文献
参考文献:10.1016/j.jmb.2010.02.011 摘要:Hirano Y, Higuchi M, Azai C, Oh-Oka H, Miki K, Wang ZY. Crystal structure of the electron carrier domain of the reaction center cytochrome c(z) subunit from green photosynthetic bacterium Chlorobium tepidum. J Mol Biol. 2010 Apr 16;397(5):1175–87. doi: 10.1016/j.jmb.2010.02.011. 参考文献:10.1007/978-1-61779-188-8_19 摘要:Di Primo C, Dausse E, Toulmé JJ. Surface plasmon resonance investigation of RNA aptamer-RNA ligand interactions. Methods Mol Biol. 2011;764():279–300. doi: 10.1007/978-1-61779-188-8_19.