专利号:US-9289755-B2 优先权日:2012-12-07 标题 :Synthesis of ZSM-5 crystals with improved morphology 发明人:LAI WENYIH FRANK; ROLLMAN NICHOLAS S 权利人:LAI WENYIH FRANK; ROLLMAN NICHOLAS S; EXXONMOBIL RES & ENG CO 摘要:Methods are provided for synthesizing crystals having a ZSM-5 framework structure from synthesis mixtures suitable for synthesis of ZSM-12 framework structure crystals in the absence of seed crystals with a ZSM-5 framework structure, such as in the absence of any seed crystals. For synthesis mixtures with a sufficiently high XO 2 :Y 2 O 3 ratio, seeding a synthesis mixture with ZSM-5 seed crystals can result in production of pure phase ZSM-5 crystals with a new morphology. The morphology can include rod-like primary crystallites with a length of about 0.5 μm or less that are organized/aggregated into larger secondary crystal structures. The aggregation of the primary crystallites into a secondary crystal structure can allow for an unexpectedly large mesoporous surface area for the ZSM-5 crystals.
专利号:US-5192521-A 优先权日:1991-11-19 标题 :Synthesis of crystalline silicate ZSM-12 发明人:MOINI AHMAD; VALYOCSIK ERNEST W 权利人:MOBIL OIL CORP 摘要:This invention relates to a new form of crystalline material identified as zeolite ZSM-12, to a new and useful improvement in synthesizing said crystalline material and to use of said crystalline material prepared in accordance herewith as a catalyst for organic compound, e.g. hydrocarbon compound, conversion.
专利号:CN-104812703-A 优先权日:2012-12-07 标 题:Synthesis of ZSM-5 crystals with improved morphology
专利号:US-2014162867-A1 优先权日:2012-12-07 标 题:Synthesis of zsm-5 crystals with improved morphology
专利号:US-6977141-B2 优先权日:1998-02-10 标 题 :Direct adsorption scintillation assay for measuring enzyme activity and assaying biochemical processes 发明人:YUAN ZHENGYU; CHEN ZHONG-XIAO 权利人:VICURON PHARM INC 摘要:Methods and materials for scintillation assays are disclosed. The scintillation assays rely on differences in general molecular property-based binding interactions, such as charge or hydrophobicity, to localize a radioactive substance near a scintillating material, stimulating scintillation. They are thus described as a direct adsorption scintillation assay (DASA) to distinguish them from the scintillation proximity assay (SPA). The assays are more convenient and inexpensive to implement than SPAs, which rely on specific binding of ligand-receptor pairs, antibody-antigen pairs, or other binding partners which rely on the precise and specific structural complementarity of the partners. The assays can be employed for studying enzymatic reactions, such as those involved in the synthesis of Mur-pentapeptide. The assays are readily adaptable to high throughput screening for use in conjunction with combinatorial libraries of compounds.
专利号:CA-2891025-C 优先权日:2012-12-07 标 题 :Synthesis of zsm-5 crystals with improved morphology
1: Brown TC. Aspects of depolarizing neuromuscular blockers: decamethonium and suxamethonium. Paediatr Anaesth. 2013 Sep;23(9):868-70. doi: 10.1111/pan.12122. Epub 2013 Feb 11. Epub 2004 Mar 3.
合成参考文献
摘要:Journal of the American Pharmaceutical Association, Scientific Edition., 45(792), 1956