CAS: 1459-09-2; Hexadecylbenzene

该化合物是一个有机化合物,其特点是具有长长的疏水烷基链和苯环,属于烷基苯的类别,其中六氯代苯组(一个16碳直链烷基组)附于苯环,具有疏水和亲脂性特性,在各种应用中,包括作为表面活性剂和制成洗涤剂,都具有实用性.六氯代苯通常无色至浅黄色液体或固态,视温度而定,在水中不溶,但有机溶剂中可溶解.其熔点和沸点受烷基链长度的影响,这对其物理特性有帮助.此外,六氯代苯可受到典型的芳香反应,如电子生物替代,因为有苯基环的存在.安全数据表明,应当谨慎处理,因为它可能对环境造成危害,并在接触时可能构成健康风险.

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123-01-3 2189-60-8 4445-07-2

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CAS号6697-12-7 苯正十六酮 | CAS号108-86-1 溴苯 | CAS号544-77-4 1-碘十六烷 | CAS号112-82-3 溴代十六烷 | CAS号71-43-2 苯 | CAS号112-67-4 棕榈酰氯 | CAS号591-50-4 碘苯 | CAS号629-73-2 1-十六烯 | CAS号79098-13-8 4-十六烷基苯胺 | CAS号16722-32-0 PARA-HEXADECYLB... | CAS号6812-38-0 十六烷基环己烷 | CAS号54337-95-0 (4-hexadecylphe...

合成工艺路线路线简述

    📜4-苯基-1-丁基溴置于schwartz'S Reagent,Sodium Iodide体系中,用 四氢呋喃,丙酮 用作溶剂,化学反应 35.0H,反应生成十六烷基苯
    参考文献:可见光诱导的镍催化与未活化烯烃的烷基锆茂新星交叉偶联.
    标题:可见光诱导的镍催化与未活化烯烃的烷基锆茂新星交叉偶联.
    摘要:自然丰富的sp 3-杂化碳中心之间的过渡金属催化交叉偶联反应有助于获得具有复杂三维结构的各种分子.有机金属化合物是最强大的试剂之一,广泛用于碳-碳键的形成.尽管sp 2-杂化的有机金属化合物广泛用于交叉偶联,但是sp 3-杂化的有机金属偶联剂的开发较少.在这里,我们报告可见光诱导的单个镍催化的c(sp 3)-c(sp 3),C(sp 3)-c(sp 2)和c(sp 3)-c(sp)使用烷基锆茂的交叉偶联反应,该反应很容易从末端或内部未活化的烯烃通过加氢锆和链步反应就地生成.该方法温和,适用于多种底物,包括伯,仲,叔烷基,芳基,烯基,炔基卤化物和各种烯烃.机理研究表明,镍催化的自由基交叉偶联是一种新颖的途径,代表了锆锆茂的首次可见光诱导的转变.
    Doi:10.1016/j.Chempr.2019.12.010

    海关参考信息

    专利信息


    专利号:US-10940467-B2
    优先权日:2014-01-27
    标 题 :Synthesis of molecular sieves having MWW framework structure
    发明人：JOHNSON IVY D; HRYCENKO NADYA A
    权利人:EXXONMOBIL CHEMICAL PATENTS INC
    摘要:The present invention provides an improved method for making molecular sieves having MWW framework structure using precipitated aluminosilicates (PAS), and the use of molecular sieves so made in processes for catalytic conversion of hydrocarbon compounds.

    专利号:US-9884763-B1
    优先权日:2004-07-28
    标题 :Process for group III-V semiconductor nanostructure synthesis and compositions made using same
    发明人：SCHER ERIK C; BURETEA MIHAI A; FREEMAN WILLIAM P; GAMORAS JOEL; QIAN BALXIN; WHITEFORD JEFFREY A
    权利人:NANOSYS INC
    摘要:Methods for producing nanostructures, particularly Group III-V semiconductor nanostructures, are provided. The methods include use of novel Group III and/or Group V precursors, novel surfactants, oxide acceptors, high temperature, and/or stable co-products. Related compositions are also described. Methods and compositions for producing Group III inorganic compounds that can be used as precursors for nanostructure synthesis are provided. Methods for increasing the yield of nanostructures from a synthesis reaction by removal of a vaporous by-product are also described.

    专利号:US-10029972-B2
    优先权日:2015-11-13
    标题 :Use of heteroleptic indium hydroxides as precursors for INP nanocrystals
    发明人：CURLEY JOHN J; SLUGOCKI TIM; HOTZ CHARLIE
    权利人:NANOSYS INC
    摘要:The present invention is in the field of nanostructure synthesis. The present invention is directed to methods for producing nanostructures, particularly Group III-V semiconductor nanostructures. The present invention is also directed to preparing Group III inorganic compounds that can be used as precursors for nanostructure synthesis.

    专利号:US-2019151832-A1
    优先权日:2014-01-27
    标题:Synthesis of Molecular Sieves Having MWW Framework Structure

    专利号:EP-3099634-A1
    优先权日:2014-01-27
    标题 :Synthesis of molecular sieves having mww framework structure

    专利号:US-10239052-B2
    优先权日:2014-01-27
    标题 :Synthesis of molecular sieves having MWW framework structure

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    合成参考文献


    参考文献:10.1007/s11743-012-1358-8
    摘要:Luan H, Wu W, Cheng J, Yu T, Qu G, Xu Y, Li G, Gao X, Li A, Yuan D, Tong W, Li Z, Liu K, Liu G, Ding W. Synthesis, Characterization and Surface Activity of Alkyl m‐Xylene Sulfonate Isomers. J Surfact & Detergents. 2012 May 11;15(5):631–6. doi: 10.1007/s11743-012-1358-8.
    参考文献:10.1007/s11743-008-1060-z
    摘要:Bengoechea C, Fernández A. Analysis of Minor Products in Linear Alkylbenzene Sulfonation. Comparison Between the Traditional Gravimetric Method and High Performance Liquid Chromatography (HPLC) Procedures Versus High Temperature Gas Chromatography (HT‐GC). J Surfact & Detergents. 2008 Feb 26;11(2):103–9. doi: 10.1007/s11743-008-1060-z.
    参考文献:10.1007/bf02667278
    摘要:El‐Emary M, Morgan LO. Structural features of linear alkylbenzene sulfonates as observed in13C magnetic resonance spectra. J Americ Oil Chem Soc. 1978 Jul;55(7):593–9. doi: 10.1007/bf02667278.
    参考文献:10.1007/978-981-97-0264-0_59
    摘要:Liu L, Xiong W, Fan W, Wang L. Study on the Synergistic Effects of Changqing Petroleum Sulfonate Complex System. 2024. In: Springer Series in Geomechanics and Geoengineering.
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