CAS: 13455-36-2; Cobalt(Ii) Phosphate

该化合物是一种无机化合物,一般是蓝色或绿色固体,由钴离子和磷酸盐组组成,呈现晶状结构,以其稳定性和水中的溶性相对较低闻名,因而在各种应用中,包括在陶瓷和玻璃中作为色素有用.磷酸钴也可以作为合成其他含钴材料的前体.就其化学特性而言,它可以经受典型的磷酸盐反应,例如降水和复合.特别是由于钴具有独特的特性,钴磷酸盐在材料科学和催化领域很受关注.然而,由于钴具有潜在的毒性和与钴有关的环境关切,处理钴化合物需要谨慎.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    📜Ammonium Cobalt(II) Phosphate 反应生成磷酸钴
    参考文献:Ulyanova,T. M.;Zemtsova,Z. N.;Ermolenko,I. N.,Oksid Tsirkoniya: Tez. Dokl. Bcec. Konf.,Zvenigorod,23-25 Ceht.,1991,+
    标题:Ulyanova,T. M.;Zemtsova,Z. N.;Ermolenko,I. N.,Oksid Tsirkoniya: Tez. Dokl. Bcec. Konf.,Zvenigorod,23-25 Ceht.,1991,+

    专利信息


    专利号:US-4794199-A
    优先权日:1984-07-05
    标题:Process for synthesis of primary amines from olefins, syngas and ammonia
    发明人：LIN JIANG-JEN; KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention concerns the synthesis of primary amines from olefins, synthesis gas and ammonia via an amination process in the presence of a cobalt catalyst, an ether solvent and a tertiary group VB donor ligand.

    专利号:US-10944106-B2
    优先权日:2018-06-25
    标题 :Metal oxide and synthesis of lithium ion battery
    发明人：CHEN PENGWEI; WANG MENG; XU LEIMIN; WANG LIANG
    权利人:NINGDE AMPEREX TECHNOLOGY LTD
    摘要:The present application relates to a metal oxide and synthesis of a lithium ion battery. Specifically, the present application selects a cobalt oxide compound, which uses Co3O4 as a main body, as a precursor of lithium cobalt oxide, and anion doping is performed in particles of Co3O4 to obtain a doped precursor for lithium cobalt oxide. The general formula of the precursor can be expressed as Co3(O1-yMy)4, where about 0
    专利号:US-4666945-A
    优先权日:1983-11-14
    标 题:Catalyst composition suitable for synthesis of methanol
    发明人：OSUGI MINORU; TAKAGAWA MAKOTO; NAKAMURA TADASI; KOJIMA TAKASHI; TSUJI KINYA
    权利人:MITSUBISHI GAS CHEMICAL CO
    摘要:A catalyst composition comprising copper oxide, zinc oxide and zirconium oxide, the content of zirconium oxide being 30 to 70% by weight. This catalyst composition is useful for synthesis of methanol from carbon monoxide and/or carbon dioxide and hydrogen by a gas-liquid-solid phase fluidized bed method or a gas-solid phase fluidized bed method.

    专利号:US-4616097-A
    优先权日:1984-10-22
    标 题:Process for low pressure synthesis of ethylene glycol from synthesis gas plus formaldehyde
    发明人：KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon-containing promoter at a temperature of at least 50 DEG C. and a pressure of at least 500 psi.

    专利号:US-4565896-A
    优先权日:1984-10-22
    标 题 :Process for low pressure synthesis of ethylene glycol from synthesis gas
    发明人：KNIFTON JOHN F; DURANLEAU ROGER G
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glcyol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogeneous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon or germanium-containing promoter and a solvent at a temperature of at least 50 DEG C. and a pressure of at least 500 psi wherein said ethylene glycol product separates as a separate liquid phase from the solvent.

    专利号:US-4609768-A
    优先权日:1984-10-22
    标题 :Process for synthesis of ethylene glycol from synthesis gas plus 1,3-dioxolane using 1,3-dioxolane as a solvent
    发明人：KNIFTON JOHN F; LIN JIANG-JEN; GRICE NEAL J
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus 1,3-dioxolane in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound, a silane or germane-containing promoter dispersed in a dioxolane solvent at a temperature of at least 50° C. and a pressure of at least 500 psi.

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    合成参考文献


    摘要:Food and Chemical Toxicology., 20(311), 1982 []
    参考文献:10.1038/ncomms4949
    摘要:Maiyalagan T, Jarvis KA, Therese S, Ferreira PJ, Manthiram A. Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions. Nat Commun. 2014 May 27;5():3949. doi: 10.1038/ncomms4949.
    参考文献:10.1007/bf00305288
    摘要:Yokota S. Electron microscopic demonstration of carbonic anhydrase activity in mouse liver cells. Histochemistry and Cell Biology. 1969 Sep;19(3):255–61. doi: 10.1007/bf00305288.
    参考文献:10.1038/ncomms9625
    摘要:Bergmann A, Martinez-Moreno E, Teschner D, Chernev P, Gliech M, de Araújo JF, Reier T, Dau H, Strasser P. Reversible amorphization and the catalytically active state of crystalline Co3O4 during oxygen evolution. Nature Communications. 2015 Oct 12;6(1):8625. doi: 10.1038/ncomms9625.
    参考文献:10.1007/s00253-018-9026-1
    摘要:Chakravarty J, Brigham CJ. Solvent production by engineered Ralstonia eutropha: channeling carbon to biofuel. Applied Microbiology and Biotechnology. 2018 Apr 29;102(12):5021–31. doi: 10.1007/s00253-018-9026-1.
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