CAS: 963-16-6; (E)-1,2-Bis(Phenylsulfonyl)Ethene

该化合物是一种多用途有机硫化合物,其特点是硬性转成的乙烯脊柱,由两个苯硫酰基组成,由两个苯硫酰基组成.这种结构具有高的电益性,使其成为有机合成中有价值的中间体,特别是循环合成,迈克尔添加和核生殖替代反应.电离子磺酰基组在稳定相邻的厌离性中间体的同时增强反应力.其晶体固态保证了处理和净化的便利性.该化合物被广泛用于准备乙型循环,功能化烷基体和作为Diels-Alder反应中的致命剂.在标准条件下和可预测的再活动特征下,其稳定性使它成为合成应用的可靠试剂.

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CAS号963-15-5 顺-1,2-二(苯砜)乙烯 | CAS号3123-10-2 2,2-dichloroeth... | CAS号873-55-2 苯亚磺酸钠 | CAS号39082-53-6 1,1-双(苯基磺酰基)乙烯 | CAS号98-09-9 苯磺酰氯 | CAS号105-53-3 丙二酸二乙酯 | CAS号6262-45-9 1,2-dichloro-3,... | CAS号32501-95-4 Benzene, [(2,2-... | CAS号72078-39-8 methyl 5-(furan... | CAS号52179-72-3 5-苯基-1H-吡咯-2-羧酸甲酯

合成工艺路线路线简述

  • 963-15-5 = 963-16-6
    反应条件:1.1 Reagents: Oxygen Solvents: Carbon Dioxide; 60 Min,10 Mpa,473 K
    标题:The Selective Thermal Cis-Trans Isomerization Of 1,2-Diphenylsulfonyl Ethylene In The Presence Of Carbon Dioxide
    作者:Sato,Takafumi; Ito,Satoshi; Yajima,Yumiko; Itoh,Naotsugu
    参考文献:Journal Of Supercritical Fluids 日期:2009 卷标:51(2) 页码:217-220]

    38238-75-4 + 873-55-2 = 963-16-6
    反应条件:1.1 Solvents: Toluene,Water; Rt -> 70 °C; 70 °C; 70 °C -> 85 °C; 3 H,85 °C
    标题:Reactions For Improved Preparation Of Trans-1,2-Bis(Phenylsulfonyl)Ethylene And Its Intermediates
    参考文献:Japan]

    39082-53-6 = 963-16-6 [标题:Reaction Conditions
    标题:Product Subclass 10: 1,2-Bis(Sulfur-Functionalized) Alkenes
    作者:Chandler,C.; Torres,R. R.; Erkkila,A.; List,B.
    参考文献:Science Of Synthesis 日期:2008 卷标:32 页码:365-380]

    156-60-5 = 963-16-6 + 963-15-5
    反应条件:1.1 Solvents: Dimethylformamide; 70 - 90 °C
    标题:1,2-Bis(Phenylsulfonyl)Ethylene
    作者:De Lucchi,Ottorino; Pasquato,Lucia; Rollin,Patrick; Tatibouet,Arnaud
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2005 卷标:1 页码:1-5]

    873-55-2 + 3123-10-2 = 963-16-6
    反应条件:1.1 Solvents: Methanol,Water
    标题:A Novel Route For The Synthesis Of Unsaturated Oxo Sulfones And Bissulfones
    作者:Reddy,D. Bhaskar; Babu,N. Chandrasekhar; Padmavathi,V.; Sumathi,R. P.
    参考文献:Synthesis 日期:1999 卷标:(3) 页码:491-494]

    963-15-5 = 963-16-6
    反应条件:1.1 Catalysts: Iodine
    标题:1,2-Bis(Phenylsulfonyl)Ethylene
    作者:De Lucchi,Ottorino; Pasquato,Lucia
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2016 卷标:1 页码:1-10]

    39082-53-6 = 963-16-6 [标题:Reaction Conditions
    标题:Introduction To Synthesis Of Allenes And Alkenes
    作者:Mulzer,J.
    参考文献:Science Of Synthesis 日期:2008 卷标:32 页码:1-11
📜Trans-β-Bromovinyl Phenyl Sulfone置于三苯基膦体系中,化学反应生成 反-1,2-双(苯基磺酰基)乙烯
参考文献:Kataev,E.G. Et Al.,Journal Of Organic Chemistry Ussr (English Translation),1974,Vol. 10,P. 1059-1062
标题:Kataev,E.G. Et Al.,Journal Of Organic Chemistry Ussr (English Translation),1974,Vol. 10,P. 1059-1062

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主要参考文献

参考标题:A Novel And Simple Route For The Synthesis Of 3,4-Disubstituted Pyrroles
作者:Venkatapuram Padmavathi,Boggu Jagan Mohan Reddy,Adivireddy Padmaja |发布日期:2005.3
摘要:A New Class Of 3,4-Disubstituted Pyrroles Has Been Prepared By The Reaction Of 1-Aroyl-2-Arylsul-Fonylethenes And 1,2-Diarylsulfonylethenes With Tosyl Methyl Isocyanide.

合成参考文献


摘要:Lubell, W. D.; St-Cyr, D. J.; Dufour-Gallant, J.; Hopewell, R.; Boutard, N.; Kassem, T.; Dörr, A.; Zelli, R., Science of Synthesis Knowledge Updates, (2013) 1, 242.
摘要:Kawęcki, R., Science of Synthesis Knowledge Updates, (2018) 4, 320.
摘要:Grimmer, J.; Krieg, S.-C.; Manolikakes, G., Science of Synthesis Knowledge Updates, (2021) 1, 221.
摘要:Grimmer, J.; Krieg, S.-C.; Manolikakes, G., Science of Synthesis Knowledge Updates, (2021) 1, 220.
摘要:Kawęcki, R., Science of Synthesis Knowledge Updates, (2018) 4, 319.
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