📜硫酸单辛酯铵盐,氯化(1-丁基-3-甲基咪唑) 反应 0.17H,以83%的收率获得产物1-丁基-3-甲基咪唑正辛基硫酸 参考文献:Further Investigation Of The Biodegradability Of Imidazolium Ionic Liquids 标题:Further Investigation Of The Biodegradability Of Imidazolium Ionic Liquids 摘要:本报告延续了我们之前的研究,介绍了一系列咪唑离子液体的设计原理,以及使用二氧化碳顶空试验(iso 14593 方法,Oecd 310)对其进行生物降解的情况.通过加入各种官能团和增加烷基链长度,进一步研究了咪唑离子 N 取代侧链的变化对这些盐类生物降解性的影响.一系列含有已知可生物降解分子的阴离子也被加入到一些咪唑盐中,并以类似的方式进行了研究. DOI:10.1039/b900787C
专利号:US-2010191010-A1 优先权日:2007-07-02 标题 :Process for the synthesis of carbamates using co2 发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY 权利人:HUNTSMAN INT LLC 摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.
专利号:US-9267213-B1 优先权日:2005-03-25 标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array 发明人:MAURER KARL; COOPER JOHN J 权利人:CUSTOMARRAY INC 摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.
专利号:US-10407676-B2 优先权日:2014-12-09 标题 :High efficiency, small volume nucleic acid synthesis 发明人:POEHMERER THOMAS; KUHN PHILLIP; NOTKA FRANK; ZEIDLER ANDREAS; HEIL KORBINIAN; TREFZER AXEL; FONNUM GEIR; KATZEN FEDERICO; ANDERSSON KRISTIAN 权利人:LIFE TECHNOLOGIES CORP; THERMO FISHER SCIENT GENEART GMBH; LIFE TECH AS 摘要:The disclosure generally relates to compositions and methods for the production of nucleic acid molecules. In some aspects, the invention allows for the microscale generation of nucleic acid molecules, optionally followed by assembly of these nucleic acid molecules into larger molecules. In some aspects, the invention allows for efficient production of nucleic acid molecules (e.g., large nucleic acid molecules such as genomes).
专利号:EP-2173705-A1 优先权日:2007-07-02 标 题:Process for the synthesis of carbamates using co2
专利号:EP-2011782-A1 优先权日:2007-07-02 标题:Process for the synthesis of carbamates using co2
专利号:WO-2009013062-A1 优先权日:2007-07-02 标 题:Process for the synthesis of carbamates using co2
参考文献:10.1007/s11743-016-1895-7 摘要:Joondan N, Caumul P, Jhaumeer‐Laulloo S. Investigation of the physicochemical and biological properties of proline‐based surfactants in single and mixed surfactant systems. J Surfact & Detergents. 2016 Nov 07;20(1):103–15. doi: 10.1007/s11743-016-1895-7. 参考文献:10.1007/s11743-014-1666-2 摘要:Xu W, Zhang Q, Wei H, Qin J, Yu L. Self‐Aggregation of Catanionic Surface Active Ionic Liquids in Aqueous Solutions. J Surfact & Detergents. 2015 Jan 07;18(3):421–8. doi: 10.1007/s11743-014-1666-2. 参考文献:10.1007/s10953-023-01246-7 摘要:Altun A, Şara ON, Pekdemir T. Volumetric Properties and Viscosities for 1-Ethyl-3-methylimidazolium Ethyl Sulfate and Ethylene Glycol Binary Mixture from 293.15 K to 343.15 K at Atmospheric Pressure. J Solution Chem. 2023 Feb 18;52(5):530–50. doi: 10.1007/s10953-023-01246-7. 参考文献:10.1007/s11164-023-05007-5 摘要:Nguyen VC, Do VH, Truong DD, Pham TT, Dinh PK, Vu TL, Garcia-Suarez EJ, Riisager A, Fehrmann R, Le MT. The influence of triphenylphosphine trisulfonate (TPPTS) ligands on the catalytic activity of the supported ionic liquid-phase catalysts for the hydroformylation of ethylene. Res Chem Intermed. 2023 Apr 19;49(6):2383–98. doi: 10.1007/s11164-023-05007-5. 参考文献:10.1007/s00217-024-04484-1 摘要:Fuster MG, Moulefera I, Montalbán MG, Víllora G. Biocatalytic transesterification of salmon oil in ionic liquid media to obtain concentrates of omega-3 polyunsaturated fatty acids. Eur Food Res Technol. 2024 Mar 25;250(6):1707–19. doi: 10.1007/s00217-024-04484-1.