CAS: 33404-34-1; (2R,3R,4R,5R)-4-(((2S,3R,4R,5S,6R)-3,4-Dihydroxy-6-(Hydroxymethyl)-5-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Pyran-2-yl)Oxy)-2,3,5,6-Tetrahydroxyhexanal

该化合物是一种三色细胞,由三色糖组成,由1-1,4-甘醇结层连接,成为纤维素家族的成员;它是在水中溶解的白色晶状固体,反映其碳水化合物的性质;其性质不常见于自由形式,而通常是在纤维素酶酶酶对纤维素进行酶解过程中生产的.其分子结构有助于其特性,包括形成氢结层的能力,从而影响其溶性以及与其他分子的互动.Cellotriose是各种微生物的子体,可以将之用于能源,在碳循环中发挥作用.在应用方面,它对与碳水酸盐化学,食品科学以及生物燃料和生物加工的潜在用途有关的研究感兴趣.CAS编号33404-34-1在化学数据库中独特地确认了这种化合物,便利其在各个科学领域的研究和应用.

结构式图片

相似化合物

32860-62-1 69-79-4 528-50-7

上下游产品

cellotetraose cellopentaose Sucrose D-maltoseD-glucose 48H82O41C48H82O41 54H92O46C54H92O46 60H102O51C60H102O51

合成工艺路线路线简述

    📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid 反应生成 D-(+)-纤维三糖
    参考文献:The Polymer-Homologous Series Of Oligosaccharides From Cellulose1
    标题:The Polymer-Homologous Series Of Oligosaccharides From Cellulose1
    摘要:
    DOI:10.1021/ja01141A032

    专利信息


    专利号:US-2021246476-A1
    优先权日:2020-01-31
    标 题:Biosynthesis of preparing nicotinamide mononucleotide and derivatives thereof
    发明人:ZHANG YI HENG PERCIVAL
    权利人:ZHANG YI HENG PERCIVAL
    摘要:A method of making nicotinamide mononucleotide (NMN), nicotinamide mononucleotide derivatives, or mixtures thereof is disclosed. The method involves the in vitro artificial enzymatic pathways comprised: the generation of alpha-D-ribose-1-phosphate from numerous substrates followed by the synthesis of nicotinamide mononucleotide catalyzed by nicotinamide riboside phosphorylase and nicotinamide riboside kinase or the generation of 5-phospho-alpha-D-ribose-1-diphosphate from nucleotides followed by the synthesis of nicotinamide mononucleotide catalyzed by nicotinamide phosphoribosyltransferase. The multiple enzymes were reconstituted in one pot, wherein in-situ removal of byproducts that can be converted to other non-inhibitory chemicals with supplementary enzymes push the overall biotransformation toward the synthesis of nicotinamide mononucleotide. Furthermore, nicotinamide mononucleotide can be converted to its derivatives—nicotinamide adenine dinucleotide and nicotinamide adenine dinucleotide phosphate.

    专利号:US-2023278976-A1
    优先权日:2021-07-05
    标题:Synthesis Of Beta-Glycolipid Compounds
    发明人:BOXLEY CHETT; STOLLEY RYAN; BRUGGEMAN ROBERT
    权利人:GLYCOSURF INC
    摘要:Methods of forming a glycolipid are disclosed. A method may include glycosylating a sugar with a beta-hydroxyester using BF3-L as a glycosylation promoter. L may include one or more of Diethylether, Tetrahydrofurn, Dimethyle Sulfide, or combinations thereof. The beta-hydroxyester may include a carbon length ranging from C2 to C24. The sugar may be a protected sugar that includes peracetylated-rhamnose, peracetylated-xylose, peracetylated-glucose, peracetylated-galactose or combinations thereof. The beta-hydroxyester and sugar may be combined in a reaction vessel to form a mixture. A solvent may be added to the mixture to substantially dissolve the mixture. The glycosylation promoter may be added to the solution such that the solution is maintained withing a desired temperature range.

    专利号:WO-9102739-A1
    优先权日:1989-08-11
    标题:Synthesis of glycosides having predetermined stereochemistry
    发明人:DANISHEFSKY SAMUEL J
    权利人:UNIV YALE
    摘要:Methods of stereoselectively preparing a substituted 1,2-anhydrosugar wherein a substituted glycal is converted into a 1,2-anhydrosugar that is utilized to glycosylate a hydroxyl group containing glycal, are disclosed. Methods of preparing a saccharide multimer wherein a nucleophile is reacted with a substituted 1,2-anhydrosugar having a plurality of non-participating substituents, are disclosed. In addition, methods of preparing stereospecific halo-substituted saccharide multimers by haloglycosylation of a glycosyl donor substituted glycal and a glycosyl acceptor glycal derivative in the absence of water and in the presence of a halonium ion, are disclosed. Methods of preparing stereospecific particle-linked halo-substituted saccharide multimers, by haloglycosylation of a particle-linked nucleophilic hydroxyl group with a substituted glycal and a halonium ion, are also disclosed.

    专利号:US-4614718-A
    优先权日:1983-08-23
    标 题 :Synthesis of sugar or sugar-alcohol fatty acid esters
    发明人:SEINO HAJIME; UCHIBORI TSUYOSHI; INAMASU SACHIKO; NISHITANI TOSHIYUKI
    权利人:DAI ICHIO KOGYO SEIYAKU CO LTD
    摘要:Sugar or sugar-alcohol fatty acid esters such as sucrose fatty acid esters are synthesized by incubating an aqueous mixture of a sugar or sugar-alcohol, a fatty acid and a catalytically active amount of a lipolytic enzyme, and recovering the resulting ester from the mixture.

    专利号:US-6573076-B1
    优先权日:1997-03-04
    标 题:Gene, group of genes, and novel β-glucosidase
    发明人:TONOUCHI NAOTO; TSUCHIDA TAKAYASU; YOSHINAGA FUMIHIRO; TAHARA NAOKI; YANO HISATO; HAYASHI TAKAHISA
    权利人:AJINOMOTO KK
    摘要:An object of the present invention is to provide novel genes and gene group involved in cellulose synthesis of microorganisms.The present invention relates to a gene group encoding cellulase, cellulose synthase complex, beta-glucosidase and the like, and to novel beta-glucosidase.

    专利号:US-11180740-B2
    优先权日:2018-04-23
    标 题 :Synthesis of glucan comprising beta-1,3 glycosidic linkages with beta-1,3-glucan phosphorylase enzymes
    发明人:YU ZHEYONG; KRALJ SLAVKO; BEHABTU NATNAEL; ZHANG ZHENGHONG; HOWE LAURIE A
    权利人:DANISCO US INC
    摘要:Reaction compositions are disclosed herein comprising at least water, alpha-glucose-1-phosphate (alpha-G1P), an acceptor molecule, and a beta-1,3-glucan phosphorylase enzyme. These reactions can synthesize oligosaccharides and polysaccharides with beta-1,3 glycosidic linkages. Further disclosed are methods of isolating beta-1,3-glucan.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Reese Et, Et Al. Enzymic Production Of Cellotriose From Cellulose. Arch Biochem Biophys. 1959 Nov;85:171-5.
    [参考文献]: Camila R Santos, Et Al. Dissecting Structure-Function-Stability Relationships Of A Thermostable Gh5-Cbm3 Cellulase From Bacillus Subtilis 168. Biochem J. 2012 Jan 1;441(1):95-104.
    [参考文献]: Christopher D Warner, Et Al. Kinetic Characterization Of A Glycoside Hydrolase Family 44 Xyloglucanase/endoglucanase From Ruminococcus Flavefaciens Fd-1. Enzyme Microb Technol. 2011 Jan 5;48(1):27-32.
    [参考文献]: Elodie Alinat, Et Al. Capillary Electrophoresis Fingerprinting Of 8-Aminopyrene-1,3,6-Trisulfonate Derivatized Nitrocellulose After Partial Acid Depolymerization. J Chromatogr A. 2015 Mar 27:1387:134-43.
    [参考文献]: Julie Ravachol, Et Al. Combining Free And Aggregated Cellulolytic Systems In The Cellulosome-Producing Bacterium Ruminiclostridium Cellulolyticum. Biotechnol Biofuels. 2015 Aug 13:8:114.

    合成参考文献


    参考文献:10.1007/s12010-007-8058-2
    摘要:Apiraksakorn J, Nitisinprasert S, Levin RE. Grass degrading beta-1,3-1,4-D-glucanases from Bacillus subtilis GN156: purification and characterization of glucanase J1 and pJ2 possessing extremely acidic pI. Appl Biochem Biotechnol. 2008 Apr;149(1):53–66. doi: 10.1007/s12010-007-8058-2.
    参考文献:10.1007/s00284-008-9149-1
    摘要:Pérez-Avalos O, Sánchez-Herrera LM, Salgado LM, Ponce-Noyola T. A bifunctional endoglucanase/endoxylanase from Cellulomonas flavigena with potential use in industrial processes at different pH. Curr Microbiol. 2008 Jul;57(1):39–44. doi: 10.1007/s00284-008-9149-1.
    参考文献:10.1007/s11103-011-9791-z
    摘要:Sooriyaarachchi S, Jaber E, Covarrubias AS, Ubhayasekera W, Asiegbu FO, Mowbray SL. Expression and β-glucan binding properties of Scots pine (Pinus sylvestris L.) antimicrobial protein (Sp-AMP). Plant Mol Biol. 2011 Sep;77(1-2):33–45. doi: 10.1007/s11103-011-9791-z.
    参考文献:10.1016/j.bmc.2011.04.048
    摘要:Noguchi S, Takemoto S, Kidokoro S, Yamamoto K, Hashimoto M. Syntheses of cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases. Bioorg Med Chem. 2011 Jun 15;19(12):3812–30. doi: 10.1016/j.bmc.2011.04.048.
    参考文献:10.1007/s00894-018-3654-3
    摘要:Shao C, Shi K, Hua Q, Zhang L, Dai Y, You W, Liu Y, Li C, Zhang C. Mechanism for the depolymerization of cellulose under alkaline conditions. Journal of Molecular Modeling. 2018 May 02;24(6):124. doi: 10.1007/s00894-018-3654-3.
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