CAS: 3234-28-4; 2-Dodecyloxirane

该化合物是一种长链氧化物,分子式为C14H28O,其特点是在终点位置上有一个活性氧环,该化合物主要用作有机合成的中间体,特别是在生产表面活性剂,润滑剂和特殊聚合物方面,其过氧化功能允许环状反应,允许引入氢氧基或进一步衍生.长烷基链具有疏水性,适合需要量身定制的表面活动或与非极地基兼容性的应用.该化合物一般在对水分和酸性敏感度的不热条件下处理,其稳定性和再活性平衡使其成为工业和研究环境中的多功能建筑块.

结构式图片

相似化合物

2855-19-8 2984-50-1 7320-37-8

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号1120-36-1 1-十四烯 | CAS号21129-09-9 1,2-十四碳二醇 | CAS号638-59-5 肉豆蔻醇乙酸酯 | CAS号79-21-0 过氧乙酸 | CAS号112-71-0 溴代十四烷 | CAS号2345-27-9 2-十四酮 | CAS号124-25-4 十四烷醛 | CAS号3234-28-4 1,2-环氧十四烷 | CAS号153062-87-4 (S)-1,2-十四烷二醇 | CAS号153062-86-3 (R)-1,2-4-TRIAC... | CAS号130404-10-3 (R)-tetradec-1-... | CAS号123650-80-6 2-fluorotetrade... | CAS号135987-18-7 1-fluorotetrade... | CAS号74649-89-1 2-dodecyl-1,4,7...

合成工艺路线路线简述

    1-十四烯置于过氧乙酸,C26H30F6Mnn8O8S2体系中,用 二氯甲烷,乙腈 用作溶剂,化学反应 0.55H,反应生成1,2-环氧十四烷
    参考文献:"click" Tetradentate Ligands
    标题:"click" Tetradentate Ligands
    摘要:使用cui催化的叠氮-炔烃"点击"策略,高效合成了系列三唑基n4四面体配体1A-d,并可方便地与多种金属离子(如mnii,Niii,Znii和feii)配位.所得金属配合物的x射线结构(4A-d,5A,6A和7A)显示为具有两个共配体的八面体单核结构,且两个三唑作为氮供体与金属中心处于cis位.Mnii配合物(4A-d)在过乙酸引发的多种脂肪族末端烯烃环氧化反应中表现出高效的催化活性,具有低催化剂负载量,快速转化和高产率的特征.
    Doi:10.1039/b922043G

    海关参考信息

    专利信息


    专利号:US-5073643-A
    优先权日:1990-08-30
    标 题 :High yield synthesis of hydroxyl-containing cationic photoinitiators
    发明人:CRIVELLO JAMES V
    权利人:POLYSET CORP
    摘要:Synthesis use of a new class of diaryliodonium salt photo and thermal polymerization initiators in which the aryl groups are substituted with alkoxy group bearing hydroxy groups. Good to excellent yields are obtained of diaryliodonium salts in which the aryl groups are substituted with long chain alkoxy groups, which alkoxy groups also possess at least one hydroxyl moiety attached at the 2-position of an alkoxy group. The resultant salts have enhanced solubility when compared with their lower molecular weight counterparts. The hydroxyl groups serve as chain transfer agents; and, in cross linking UV-induced cationic polymerizations, the hydroxyl groups effect marked accelertion on polymerization rates. The salts also have excellent compatability with nonpolar monomers such as epoxidized oil and poly(1,2-butadience oxide) and provide further benefits when they are used along with copper cocatalysts in thermally curable polymer systems. In the latter form of cases, the secondary hydroxyl group serves as a reducing agent for the copper (II) complex.

    专利号:WO-9967219-A1
    优先权日:1998-06-22
    标 题:Compounds for inhibiting beta-amyloid peptide release and/or its synthesis
    发明人:AUDIA JAMES E; PORTER WARREN J; THOMPSON RICHARD C; WILKIE STEPHEN C; STACK DOUGLAS R; SHI QING
    权利人:ELAN PHARM INC; LILLY CO ELI; AUDIA JAMES E; PORTER WARREN J; THOMPSON RICHARD C; WILKIE STEPHEN C; STACK DOUGLAS R; SHI QING
    摘要:Compounds of formula (I), wherein W is a cyclic group of the type (2); (3); Y is represented by the formula (II); these compounds inhibit β-amyloid peptide release and/or its synthesis, and, accordingly, have utility in treating Alzheimer's disease. Also disclosed are pharmaceutical compositions comprising a compound which inhibits β-amyloid peptide release and/or its synthesis as well as methods for treating Alzheimer's disease both prophylactically and therapeutically with such pharmaceutical compositions.

    专利号:US-6838455-B2
    优先权日:1998-06-22
    标题 :Deoxyamino acid compounds, pharmaceutical compositions comprising same, and methods for inhibiting beta-amyloid peptide release and/or its synthesis by use of such compounds
    发明人:AUDIA JAMES E; PORTER WARREN J; THOMPSON RICHARD C; WILKIE STEPHEN C; STACK DOUGLAS R; SHI QING
    权利人:ATHENA NEUROSCIENCES INC; LILLY CO ELI
    摘要:Disclosed are compounds which inhibit β-amyloid peptide release and/or its synthesis, and, accordingly, have utility in treating Alzheimer's disease. Also disclosed are pharmaceutical compositions comprising a compound which inhibits β-amyloid peptide release and/or its synthesis as well as methods for treating Alzheimer's disease both prophylactically and therapeutically with such pharmaceutical compositions.

    专利号:US-9228147-B2
    优先权日:2010-12-14
    标题 :Glycol ether-based cyclohexanoate esters, their synthesis and methods of use
    发明人:PATIL ABHIMANYU ONKAR; BODIGE SATISH
    权利人:PATIL ABHIMANYU ONKAR; BODIGE SATISH; EXXONMOBIL RES & ENG CO
    摘要:Glycol ether-based cyclohexanoate esters, their synthesis and methods of use as lubricant basestocks or co-basestocks.

    专利号:US-2023118672-A1
    优先权日:2017-06-21
    标 题:Substituted poly(alkylene oxide) and surfactant composition
    发明人:XU FENG; AL-ANAZI FLAIYH FARHAN N
    权利人:SABIC GLOBAL TECHNOLOGIES BV
    摘要:A method for the synthesis of a substituted poly(alkylene oxide) comprises reacting a substituted alcohol of formula (1) with an alkylene oxide of formula (2) in the presence of a catalyst and under conditions effective to provide the substituted poly(alkylene oxide) of formula (3) wherein in the foregoing formulas, each R is independently hydrogen, C 1-60 alkyl, or C 3-12 cycloalkyl, ring A is cyclohexane or phenyl, each R 1 is independently hydrogen, methyl, ethyl, propyl, butyl, hexyl, decyl, dodecyl, tetradecyl, or hexadecyl, preferably hydrogen or methyl, and n is 2 to 60.

    专利号:WO-9202479-A1
    优先权日:1990-07-27
    标 题 :(2-hydroxyalkyl)-substituted beta-dicarbonyl compounds
    发明人:STOLL GERHARD; KLAMANN JOERG-DIETER; RENGA JAMES M
    权利人:HENKEL KGAA
    摘要:(2-hydroxyalkyl)-substituted beta-dicarbonyl compounds are produced by reacting beta-dicarbonyl compounds having the formula R?1-CO-CH2?-CO-R?2, in which R?1 and R?2 represent independently from each other alkyl, cycloalkyl, aryl or alkoxy residues with 1 to 6 carbon atoms, with 1,2-epoxyalkanes having formula (II), in which R?3 represents an alkyl residue with 6 to 24 carbon atoms, in the presence of polyalkylene glycolethers and/or anorganic or organic bases. The beta-dicarbonyl compounds thus produced are useful as starting materials for the production of heterocyclic compounds for the synthesis of dyes, pharmaceuticals and plant protective products.
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    合成参考文献


    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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