CAS: 2929-52-4; Trihexylsilane

该化合物是一种多用途的减少剂,特别是在水合反应方面,它有助于有选择地减少碳基和卤化物等功能群体,它的不育成量增强了合成应用的稳定性和选择性,Trihexylsilane还被用于制作以硅为基础的材料,并用作有机硅化学的前体.该化合物的疏水性和低挥发性使其适合用于湿度敏感反应,它与各种催化剂和溶剂的兼容性进一步扩大了其在有机合成和材料科学中的用途.

结构式图片

相似化合物

18765-09-8 998-41-4 32395-58-7

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

(1-hexyl)(hexyl)silane 1-bromo-hexaneTrihexyl-pentafluorophenyloxy-silane Cyclohexyloxy-trihexyl-silane trihexylsilyl chloride Trihexyl-(4-brom-phenoxy)-silan

合成工艺路线路线简述

    Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于三氯硅烷体系中,化学反应生成三正己硅烷
    参考文献:Woronkow; Chudobin,Izvestiya Akademii Nauk Sssr,Seriya Khimicheskaya,1956,P. 805,807;Engl.Ausg.S.823,824,825
    标题:Woronkow; Chudobin,Izvestiya Akademii Nauk Sssr,Seriya Khimicheskaya,1956,P. 805,807;Engl.Ausg.S.823,824,825

    海关参考信息

    专利信息


    专利号:US-7956011-B2
    优先权日:2005-05-04
    标题:Materials and methods for the photodirected synthesis of oligonucleotide arrays
    发明人:SERAFINOWSKI PAWEL JERZY; GARLAND PETER BRYAN
    权利人:CANCER RES INST ROYAL
    摘要:Materials and methods for photodirected synthesis of oligonucleotide arrays on a solid substrate by photodirected synthesis are disclosed which employ a film formed from (i) a photoacid generator that on photolysis generates acid that is capable of directly removing the protecting group of the linker molecules or oligonucleotides and (ii) a polymer substantially lacking electronegative heteroatoms that are capable of hydrogen bonding with photogenerated acid. Methods of synthesizing an oligomer arrays are also described that use a film that restricts diffusion of reactants and products on the substrate during synthesis of the array and which includes a precursor of a deprotecting reagent. The method involves removing one or more of the non-required products of the deprotection reaction from the reactive array elements at which they are produced during the reaction, in order to displace the deprotection reaction towards completion.

    专利号:US-6262251-B1
    优先权日:1995-10-19
    标题 :Method for solution phase synthesis of oligonucleotides
    发明人:PIEKEN WOLFGANG; MCGEE DANNY; SETTLE ALECIA; ZHAI YANSHENG; HUANG JIANPING
    权利人:PROLIGO LLC
    摘要:This invention discloses an improved method for the sequential solution phase synthesis of oligonucleotides. The method lends itself to automation and is ideally suited for large scale manufacture of oligonucleotides with high efficiency.

    专利号:WO-9847910-A1
    优先权日:1997-04-21
    标题:Method for solution phase synthesis of oligonucleotides
    发明人:PIEKEN WOLFGANG; MCGEE DANNY; SETTLE ALECIA; ZHAI YANSHENG; HUANG JIANPING; HILL KEN; SMITH RANDALL S
    权利人:NEXSTAR PHARMACEUTICALS INC; PIEKEN WOLFGANG; MCGEE DANNY; SETTLE ALECIA; ZHAI YANSHENG; HUANG JIANPING; HILL KEN; SMITH RANDALL S
    摘要:This invention discloses an improved method for the sequential solution phase synthesis of oligonucleotides. The method lends itself to automation and is ideally suited for large scale manufacture oligonucleotides with high efficiency.

    专利号:US-5874532-A
    优先权日:1997-01-08
    标 题 :Method for solution phase synthesis of oligonucleotides and peptides
    发明人:PIEKEN WOLFGANG; GOLD LARRY
    权利人:NEXSTAR PHARMACEUTICALS INC
    摘要:This invention discloses an improved method for the sequential solution phase synthesis of oligonucleotides and peptides. The method lends itself to automation and is ideally suited for large scale manufacture oligonucleotides with high efficiency.

    专利号:US-6001966-A
    优先权日:1995-10-19
    标题 :Method for solution phase synthesis of oligonucleotides and peptides
    发明人:PIEKEN WOLFGANG; GOLD LARRY
    权利人:PROLIGO LLC
    摘要:This invention discloses an improved method for the sequential solution phase synthesis of oligonucleotides and peptides. The method lends itself to automation and is ideally suited for large scale manufacture oligonucleotides with high efficiency.

    专利号:US-4616097-A
    优先权日:1984-10-22
    标 题:Process for low pressure synthesis of ethylene glycol from synthesis gas plus formaldehyde
    发明人:KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention relates to the manufacture of ethylene glycol and more particularly to a low pressure process for making ethylene glycol comprising reacting synthesis gas, i.e. a mixture of carbon monoxide and hydrogen, plus formaldehyde in the presence of a homogenous liquid catalyst containing an effective amount of cobalt-containing compound and a silicon-containing promoter at a temperature of at least 50 DEG C. and a pressure of at least 500 psi.
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    合成参考文献


    摘要:Müller, T., Science of Synthesis Knowledge Updates, (2013) 3, 27.
    摘要:Bertrand, X.; Paquin, J.-F., Science of Synthesis: Modern Strategies in Organofluorine Chemistry, (2025) 2.
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