专利号:US-2024075466-A1 优先权日:2021-04-09 标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites 发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE 权利人:UMICORE AG & CO KG 摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.
专利号:US-11884855-B2 优先权日:2019-07-08 标 题 :Synthesis of europium halide perovskites in solution phase 发明人:YANG PEIDONG; HUANG JIANMEI; LEI TENG 权利人:UNIV CALIFORNIA 摘要:A solution phase synthesis process for preparing a rare earth perovskite, the process includes reacting an alkali metal material with a first surfactant ligand in the presence of a first solvent to obtain a first precursor complex solution; reacting a rare earth metal halide with a second surfactant ligand in the presence of a second solvent to obtain a second precursor complex solution; and reacting the first precursor complex solution with the second precursor complex solution in the presence of a third surfactant ligand and a third solvent to obtain the rare earth perovskite; wherein: the rare earth perovskite is in the form of nanocrystals; and the first solvent and third solvent comprise a non-coordinating solvent.
专利号:US-11505471-B2 优先权日:2017-12-18 标 题:Mechanochemical synthesis of rare earth sulfides 发明人:D'ALENCON LAURIANE; LE MERCIER THIERRY; BRAIDA MARC-DAVID; GAMON JACINTHE; BARBOUX PHILIPPE 权利人:RHODIA OPERATIONS 摘要:The present invention pertains to a process for preparing particles of rare earth sulfide comprising the steps of:—preparing a reaction mixture comprising at least one compound comprising at least one rare earth element (A) and at least one alkali metal sulfide (B),—submitting said reaction mixture to a mechanical stress so as to cause a chemical reaction that produces the particles of rare earth sulfide.
专利号:US-2022259497-A1 优先权日:2019-07-08 标 题 :Synthesis of europium halide perovskites in solution phase
参考文献:10.1007/s11172-024-4444-y 摘要:Abdrakhmanov AM, Yakshembetova LR, Vasilyuk KS, Gareev BM, Sharipov GL. Chemiluminescence of Eu3+ in aqueous solutions upon electron transfer from Eu2+ to Ce4+. Russ Chem Bull. 2024 Nov;73(11):3285–90. doi: 10.1007/s11172-024-4444-y.