CAS: 13462-88-9; Nickel(Ii) Bromide

该化合物是一种无机化合物,其特点是绿色或黄色晶体外观,通常以水分形式存在二氢酸盐(NiBr22H2O),更常见地遇到这种物质;镍溴在水中溶解,并表现出血压特征,这意味着它可以吸收空气中的湿度;这种化合物经常用于各种用途,包括作为有机合成和镍基材料制作的催化剂;镍溴还可用于电镀和其他镍化合物的前体;在安全方面,镍化合物一般被认为是有毒的,可能具有致癌性,在使用过程中需要小心处理和采取适当的安全措施;镍溴应储存在冷,干的地方,远离不相容的物质,并用保护设备处理,以尽量减少接触风险.

结构式图片

相似化合物

18721-96-5 313223-18-6 13601-55-3

欧盟法规

统一分类与标签ECHA物质食品接触材料-禁用CMR物质ECHA物质化妆品禁用物质清单C&L通报工作场所安全标识要求REACH预注册废弃物危险特性清单

上下游产品

(0)bis(1,5-cyclo°Ctadiene)nickel (0) 1-bromo-1-propene bromine nickel(2R)-3-bromo-1,2-propanediol 2,2'-dimethyl-1,1'-biphenyl 2(Tri-p-tolyl-phosphin)2NiBr2(Tri-p-tolyl-phosphin)2 {NiBr2γ-(CH3C5H4N)2}

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    专利信息


    专利号:US-11548898-B2
    优先权日:2017-07-06
    标题 :Synthesis of halichondrins
    发明人:KISHI YOSHITO; AI YANRAN; YE NING; WANG QIAOYI; YAHATA KENZO; ISO Kentaro; NAINI SANTHOSH REDDY; YAMASHITA SHUJI; LEE JIHOON; OHASHI ISAO; FUKUYAMA TAKASHI
    权利人:HARVARD COLLEGE; EISAI R&D MAN CO LTD
    摘要:The present invention provides methods for the synthesis of ketones involving a Ni/Zr-mediated coupling reaction. The Ni/Zr-mediated ketolization reactions can be used in the synthesis of halichondrins (e.g., halichondrin A, B, C; homohalichondrin A, B, C; norhalichondrin A, B, C), and analogs thereof. Therefore, the present invention also provides synthetic methods useful for the synthesis of halichondrins, and analogs thereof. Also provided herein are compounds (i.e., intermediates) useful in the synthesis of halichondrins, and analogs thereof. In particular, the present invention provides methods and compounds useful in the synthesis of compound of Formula (H3-A).

    专利号:WO-2025053792-A1
    优先权日:2023-09-06
    标题:Collective synthesis of phantomolin family through total synthesis of the sesquiterpene lactone molephantin
    发明人:CHIBA SHUNSUKE; PATOURET REMI HENRI LOUIS; LI HOI YEUNG; LAI SOAK KUAN
    权利人:UNIV NANYANG TECH
    摘要:Disclosed herein are processes to generate an intermediate in the total synthesis of (+)- molephantin or a derivative thereof, and a total synthesis of (+)-molephantin or a derivative thereof. Also disclosed herein are methods of forming a compound of formula XIV and of forming a compound of formula XV, wherein compound of formula XIV and compound of formula XV are as defined in the description.

    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-2025023061-A1
    优先权日:2021-11-17
    标题 :Method for the synthesis of a metal catalyst surrounded with a carbon matrix
    发明人:CHATENET MARIAN; DOAN HUONG; SGARBI RICARDO
    权利人:INST POLYTECHNIQUE GRENOBLE; UNIV GRENOBLE ALPES; CENTRE NAT RECH SCIENT; UNIV SAVOIE MONT BLANC
    摘要:A method for a synthesis of a metal catalyst, including providing at least one metal complex including a metal ion and a non-chelating complexing agent having carbon, the complex having a decomposition temperature, and performing a pyrolysis of the complex at a temperature greater than or equal to a decomposition temperature of the complex, whereby inducing a formation of nanoparticles surrounded by a carbon matrix to form the catalyst. Thanks to the carbon matrix, the catalysts provided herein can be corrosion resistant, self-healing, more cost-effective, and can have higher catalytic activity. The synthesis of the catalyst and its properties can furthermore be improved compared to catalysts formed from a complex including a chelating.

    专利号:US-11247977-B2
    优先权日:2018-06-22
    标题 :Compound and use thereof in synthesis of brivaracetam intermediate and crude drug
    发明人:FENG YAN; WANG RUYONG; YE YIZHANG; ZHANG FENGSEN; GONG XUAN; WANG ZHONGHONG; KANG XINSHAN
    权利人:FUJIAN HAIXI PHARMACEUTICALS CO LTD
    摘要:The present application provides a compound in formula III, and further provides a use of the compound in the synthesis of a Brivaracetam intermediate and a crude drug, and a synthesis method. A raw material involved in the method of the present application is low in costs and easily available; (R)-4-propyl-dihydrofuran-2-ketone having high optical purity can be prepared; complicated separation and purification steps are avoided; costs are reduced, and the method is more applicable to industrial production.
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    合成参考文献


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    摘要:Drabowicz, J.; Krasowska, D.; Wicha, J., Science of Synthesis, (2009) 48, 248.
    摘要:Nishinaga, T., Science of Synthesis, (2010) 45, 388.
    摘要:Vrána, J.; Růžička, A., Science of Synthesis Knowledge Updates, (2021) 2, 36.
    摘要:Vrána, J.; Růžička, A., Science of Synthesis Knowledge Updates, (2021) 2, 33.
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