CAS: 670-98-4; Methyl Benzenesulfinate

该化合物是一种有机化合物,其特征是附于苯硫化物混合物的甲基组分,其典型特征是无色的黄色液体,其芳香气味不同,是黄色的黄色液体;该化合物以其作为全氟辛烷磺酸酯的作用而著称,可参与各种化学反应,包括核生殖替代物和嗜血性芳香替代物;甲基苯硫化物在乙醇和乙醇等有机溶剂中可溶解,但由于其水分芳香结构,在水中溶解性有限;该化合物经常用于有机合成,并用作制作磺酰胺和其他磺酸衍生物的试剂;在处理该化合物时,应注意安全防范措施,因为这可能会对皮肤和眼睛产生刺激;建议在远离不相容物质的冷干的地方适当储存,以保持其稳定性和再活性.

结构式图片

欧盟法规

C&L通报

上下游产品

methanol benzenesulphinyl chloride methoxy-phenyl-sulfane diphenyldisulfanemethanol 1,1'-sulfinylbisbenzene thiophenol ethyl benzenesulfinate

合成工艺路线路线简述

  • 合成目标产物 Methyl Benzenesulfinate 主要起始原料 Methanol And Diphenyl Disulfide
  • (文献来源)合成步骤主要原料 Methanol 和 Diphenyl Disulfide
Methyl (1,2-Benzisoxazol-3-yl)-Phenylsulphinyl-Acetate置于sodium Hydride体系中,用 四氢呋喃 作为反应溶剂,化学反应 3.5H,反应生成 苯亚硫酸甲酯
参考文献:Ueda,Shozo; Naruto,Shunsuke; Yoshida,Toyokichi,Journal Of The Chemical Society. Perkin Transactions I,1988,P. 1013-1022
标题:Ueda,Shozo; Naruto,Shunsuke; Yoshida,Toyokichi,Journal Of The Chemical Society. Perkin Transactions I,1988,P. 1013-1022

海关参考信息

专利信息


专利号:US-9908846-B2
优先权日:2014-02-21
标题:Composition, synthesis, and use of new arylsulfonyl isonitriles
发明人:FLEMING FRASER FERGUSSON; LUJAN MONTELONGO JESUS ARMANDO
权利人:DUQUESNE UNIV OF THE HOLY GHOST; UNIV HOLY GHOST DUQUESNE
摘要:This invention relates to novel isonitriles, including arylsulfonyl isonitriles, and methods for their synthesis. The isonitriles include a conjugated ring system. The structure is designed with the flexibility to have multiple substitution patterns. The isonitriles may be used in applications including, but not limited to, pharmaceutical compositions.

专利号:EP-1586579-B1
优先权日:2004-03-08
标 题:Process for the preparation of delta(15-16)-17-ketosteroids and use thereof in the synthesis of pharmacologically active compounds
发明人:GRISENTI PARIDE; REZA HELAI SHARZAD; PENGO DANIELE
权利人:EUTICALS SPA

专利号:US-5218109-A
优先权日:1988-07-05
标 题:Steroid compounds
发明人:TSUJI JIRO; TAKAHASHI TAKASHI; TSUJI MASAO; NAKAGAWA NAOSHI; TAKIGAWA TETSUO
权利人:KURARAY CO
摘要:Steroid compounds of the following general formulas (I), (II) and (III) are provided: ##STR1## In the above formulas, R 1 and R 2 each is a hydrogen atom or a hydroxyl-protecting group, R is a group of the formula --CH 2 --X (in which X is a substituent such as a hydroxyl group), a carboxyl group or a protected carboxyl group, A 1 is an aryl group, a lower alkyl group or an aralkyl group, and Z 1 , Z 2 , Z 3 and Z 4 each is a hydrogen atom, a hydroxyl group or a protected hydroxyl group. n The above steroid compounds are useful as intermediates for the synthesis of vitamin D 3 derivatives having a hydroxyl group at the 1α-position.

专利号:EP-1586579-A1
优先权日:2004-03-08
标题:Process for the preparation of delta(15-16)-17-ketosteroids and use thereof in the synthesis of pharmacologically active compounds

专利号:US-2015239833-A1
优先权日:2014-02-21
标题:Composition, synthesis, and use of new arylsulfonyl isonitriles

专利号:CN-110373681-A
优先权日:2019-08-13
标题:A kind of electrochemical synthesis method of sulfinate
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合成参考文献


摘要:Lattanzi, A., Science of Synthesis: Stereoselective Synthesis, (2011) 3, 976.
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