CAS: 593-33-9; 1-Fluorotetradecane

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CAS号88303-25-7 Bromotetradecyl... | CAS号19218-94-1 TETRADECYL IODIDE | CAS号72422-53-8 1-(4-methylphen... | CAS号112-72-1 十四醇 | CAS号6221-89-2 methyl 2-[(4-ox... | CAS号77774-34-6 tert-butyldimet... | CAS号112-71-0 溴代十四烷

📜十四醇置于三甲基氯硅烷,4-二氟化碘甲苯,Triethylamine Tris(Hydrogen Fluoride),Sodium Iodide体系中,用 二氯甲烷 作为反应溶剂,化学反应生成 十四烷基氟
参考文献:烷基碘的氟化deiodinative与p-Iodotoluene二氟
标题:烷基碘的氟化deiodinative与p-Iodotoluene二氟
摘要:用对碘代甲苯二氟化物(4)对烷基碘进行氧化氟化.在et 3 N-4Hf的存在下,伯烷基碘化物的氟化反应在温和条件下在碘位置上选择性发生,从而以高收率得到相应的烷基氟化物.
DOI:10.1016/s0040-4020(01)00201-0

专利信息

专利号:US-9790377-B2
优先权日:2011-09-21
标题:Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane (“F-POSSâ€?)
发明人：HADDAD TIMOTHY S; MABRY JOSEPH M; RAMIREZ SEAN
权利人:US AIR FORCE
摘要:A method of manufacturing a fluorinated polyhedral oligomeric silsesquioxane. The method for manufacture includes opening a single edge of a closed-cage F-POSS and bridging the opened, single edge with a sulfate group. The sulfate group is converted to a disilanol, which is then reacted with a functional dichlorosilane having an organic functional group comprising at least three carbon atoms.

专利号:US-2020179977-A1
优先权日:2011-09-21
标 题:Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane ('f-poss')

专利号:US-10550271-B2
优先权日:2011-09-21
标题 :Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane (“F-POSSâ€?)

专利号:US-7307177-B2
优先权日:2004-12-17
标题:Metallocene complexes, their synthesis and use in catalyst systems for olefin polymerization
发明人：HUANG LEGAL REPRESENTATIVE JIL; CANICH JO ANN M; COKER CATALINA L
权利人:EXXONMOBIL CHEM PATENTS INC
摘要:A metallocene complex is represented by the the formulan n(C p R 5 ) n MX k n nwhere C p (each occurrence) is a cyclopentadienyl group; each of the five R substituents on the or each cyclopentadienyl group is independently selected from hydrogen, C 1 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and SiR′ 2 NR″ 2 where each of the two R′ substituents is independently selected from hydrogen, C 1 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R′ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and each of the two R″ substituents is independently selected from C 2 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R″ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure; n is 1 or 2; M is a metal of valence m from Groups 4 to 11 of the Periodic Table of Elements, k is equal to m minus n and the or each X substituent is a univalent anionic ligand, or two X substituents are joined and bound to the metal atom to form a metallocycle ring, or two X substituents are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand, provided that at least one R substituent on the or one cyclopentadienyl group is SiR′ 2 NR″ 2 , provided that at least one R substituent on at least one C p is SiR′ 2 NR″ 2 and provided that one or the C p may be bridged by a bridging group to another C p group, or a heteroatom containing group, where the bridging group replaces one R group on the C p group(s) or a hydrogen on a heteratom containing group.

专利号:US-2016122558-A1
优先权日:2011-09-21
标题 :Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane ('f-poss')

专利号:US-9249313-B2
优先权日:2011-09-21
标 题:Synthesis of functional fluorinated polyhedral oligomeric silsesquioxane (F-POSS)