CAS: 21964-51-2; Hexadeca-1,15-Diene

上下游产品

1,10-dibromodecane allyl bromide 1,6-bis(p-toluenesulfonyloxy)hexane 4-penten-1-ylmagnesium bromide 1,16-hexadecanediol

📜1,10-二溴癸烷置于乙醚,Magnesium体系中,化学反应生成16碳二烯酸
参考文献:Polymerization Of Higher α-Diolefins With Metal Alkyl Coordination Catalysts1
标题:Polymerization Of Higher α-Diolefins With Metal Alkyl Coordination Catalysts1
摘要:
Doi:10.1021/ja01526A072

专利信息

专利号:US-8258362-B2
优先权日:2009-05-04
标 题:Method for the production of α, ω-olefins by using the copper catalyzed coupling reaction of a Grignard reagent with an allylic substrate
发明人：NACHARAJU KRISHNAMURTHY; TAYLOR PAUL D; COONEY MARK J; CRABTREE LARRY A
权利人:NACHARAJU KRISHNAMURTHY; TAYLOR PAUL D; COONEY MARK J; CRABTREE LARRY A; ISP INVESTMENTS INC
摘要:A process for the synthesis of linear α,ω-diolefins from an allylic substrate comprises the steps of a) forming the bis-Grignard reagent XMgCH2(CH2)nCH2MgX from an α,ω-acyclic dihalide with X being a halogen; b) preparing a solution comprising an allylic substrate and a copper catalyst; c) catalyzing a coupling reaction by adding to the solution of step (b) the bis-Grignard reagent of step (a); and d) isolating and purifying the α,ω-olefin coupling reaction product.

专利号:US-9388345-B2
优先权日:2012-07-03
标题:Hydrocarbon synthesis methods, apparatus, and systems
发明人：MCNEFF CLAYTON V; MCNEFF LARRY C; NOWLAN DANIEL THOMAS; YAN BINGWEN; GREUEL PETER G
权利人:SARTEC CORP
摘要:Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a process for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.