CAS: 14220-21-4; Bromorhenium,Carbon Monoxide

该化合物是的协同化合物, 其特点是由五碳基(CO)离心和一溴原子环绕的中正原子, 其特征是独特的协调几何, 典型的特点是由于五碳基组的存在而呈现出三角双相相交安排. 碳基离心对化合物的稳定性和再活性有帮助, 因为它们可以与中心进行欧元反向反应. 溴开碳基氢经常用于有机金属化学和催化, 特别是在涉及碳化过程的反应中. 其特性包括有机溶剂的中溶性和对水的敏感度, 这可能导致水解. 化合物的再活性可能受到溴基离心的存在的影响, 后者可以参与替代反应.

英文名称Bromorhenium,Carbon Monoxide
中文名称五羰基溴铼(I)
IUPAC名称bromorhenium;carbon monoxide
其它别名Rhenium,bromopentacarbonyl- (7CI,8CI); Bromopentacarbonylrhenium; Bromopentacarbonylrhenium(I); Pentacarbonylbromorhenium; Pentacarbonylrheniumbromide; Pentacarbonylrhenium bromide (Re(CO)5Br); Rhenium pentacarbonylbromide; Rhenium(I) pentacarbonyl bromide
CAS编号14220-21-4
EINECS号:238-084-8
分子式:C5BrO5Re分子量:406.163
产品CID: 646594
产品分类有机原料 → 有机金属类化合物 → 有机铋,钴,镨,钆,镓,铱,铼,钇,铽等

相似结构搜索
InChIKey: PUFRYOVJAPCJTJ-UHFFFAOYSA-M
InChI=1S/5C.BrH.Re/h;;;;;1H;/q5*+3;;+1/p-1
计算化学: 氢键受体数5.0氢键供体数*可旋转键数*

MSDS等安全信息

GHS象形图
GHS符号GHS06;
注释: Skull and crossbones
危险类别急性毒性类别3(吸入)
急性毒性类别3(经皮)
急性毒性类别3(经口)
特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
警示词Danger(危险)
危险描述H331 |吸入会中毒.
H311 |皮肤接触会中毒.
H301 |吞咽会中毒.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P261-P280-P301+P310-P305+P351+P338-P311
UN编号UN 3288 6
危险品标志Xn:Harmful;
安全声明S36/37
危险类别码R23/24/25,R20/21/22,R36/37/38
WGK Germany3

欧盟法规

C&L通报REACH预注册

上下游产品

合成工艺路线路线简述

📜五羰基氯铼(I)置于c6H5Ch2Br体系中,用四氢呋喃,甲基环己烷用作溶剂,化学反应生成五羰基溴铼(I)
参考文献:Young,Kent M.; Miller,Timothy M.; Wrighton,Mark S.,Journal Of The American Chemical Society,1990,Vol. 112,# 4,P. 1529-1537
标题:Young,Kent M.; Miller,Timothy M.; Wrighton,Mark S.,Journal Of The American Chemical Society,1990,Vol. 112,# 4,P. 1529-1537

专利信息

专利号:WO-2009077719-A1
优先权日:2007-12-17
标题:Process for the conversion of hydrocarbons to ethanol
发明人：DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
权利人:BP P I C; DANIEL BERIAN JOHN; GRACEY BENJAMIN PATRICK; SUNLEY JOHN GLENN
摘要:The present invention relates to a process for producing ethanol, and optionally methanol, from synthesis gas. In particular the present invention relates to a process for producing ethanol from a carbonaceous feedstock; wherein the carbonaceous feedstock is first converted to synthesis gas which is then converted to methanol which is then converted to dimethyl ether which is then converted to methyl ethanoate, which is then hydrogenated to produce ethanol in the same alcohol synthesis unit used for converting the said synthesis gas to methanol.

专利号:WO-03086476-A1
优先权日:2002-04-08
标题 :Technetium-labeled rotenone derivatives, and methods of use thereof
发明人：BABICH JOHN W; MARESCA KEVIN P
权利人:BIOSTREAM INC; BABICH JOHN W; MARESCA KEVIN P
摘要:One aspect of the present invention relates to Tc-99m-labeled rotenone derivatives. These derivatives are useful, for example, as myocardial blood flow imaging agents. Reported herein are the synthesis, radiolabeling, and testing of Tc-99m-labeled rotenone complexes as single photon emitting probes for improved delineation of myocardial perfusion. The Tc-99m-rotenone derivatives have unique properties. The instant invention also relates to technetium-99m-labeled rotenone derivatives which exhibit high uptake and retention in the myocardium in proportion to flow. Another aspect of the present invention relates to kits compring a Tc-99m-labeled rotenone derivative.

专利号:US-8907140-B2
优先权日:2007-11-14
标题 :Process for the production of alcohol from a carbonaceous feedstock
发明人：DANIEL BERIAN JOHN; DEELEY JON MICHAEL STEWART; GRACEY BENJAMIN PATRICK; LI CONG RONG
权利人:BP PLC
摘要:The present invention relates to an improved process for the production of ethanol from a carbonaceous feedstock; wherein the carbonaceous feedstock is first converted to synthesis gas which is then converted to ethanoic acid, which is then esterified and which is then hydrogenated to produce ethanol.

专利号:US-6455693-B1
优先权日:2000-11-20
标题:Molecular rectangles
发明人：LEE GENE-HSIANG; PENG SHIE-MING; WANG CHONG-MOU; LU KUANG-LIEH; MANIMARAN BALASUBRAMANIAN; LEE FANG-YUAN; RAJANDRAN THANGAMUTHU
权利人:ACADEMIA SINICA
摘要:The invention is based on the discovery that a new class of molecular rectangles can be prepared by using a stepwise synthesis plan under mild temperature conditions. The new rectangles are neutral and exhibit luminescence in solution at room temperature. In general, the invention features a compound having the structure:

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主要参考文献

参考标题:Synthesis Of A Novel Re(I)-Ru(II)-Re(I) Trinuclear Complex As An Effective Photocatalyst For Co2 Reduction
作者:Akinari Umemoto,Yasuomi Yamazaki,Daiki Saito,Yusuke Tamaki,Osamu Ishitani |发布日期:2020.1.15
摘要:Supramolecular Photocatalysts, Which Consist Of Redox Photosensitizer And Catalyst Units, Have Recently Attracted Attention In The Field Of Artificial Photosynthesis. Aiming To Construct A Durable Supramolecular Photocatalyst For Co2 Reduction, A New Re-Ru-Re Trinuclear Complex Was Successfully Developed, Where One Ru Unit, Acting As Photosensitizer, Was Linked To Two Re Units, Acting As Catalysts, Through Ethylene Chains. The Novel Complex Was Synthesized By Creating Two Chelate Moieties On The Ligand Of A Ru Complex Using The Negishi-Coupling Reaction, Which Were Then Coordinated To Re Complexes. This Trinuclear Complex Selectively Photocatalyzed The Reduction Of Co2 To Co Under Visible Light Irradiation, With High Durability Compared With The Corresponding Ru-Re Binuclear Complex And A Mixed System Of Model Mononuclear Complexes. Absorption Spectra And Mass Spectroscopic Data Of The Reaction Solutions Revealed A Rapid Consumption Of The Electrons On The One-Electron Reduced Species Of The Ru Unit, Which Led To Suppression Of The Ru Unit Decomposition, Thereby Maintaining Its Photosensitizing Ability And Product Selectivity.