CAS: 12025-32-0; Germanium(Ii) Sulfide

该化合物是一种二元无机化合物,由1:1个蒸气度比例的和硫组成,它呈现出一种类似于黑磷的分层晶体结构,它使其具有独特的厌食性能. GeS 以其半导体行为为显著特征,其带宽大约1.6 eV, 使其适合光检测器和薄膜晶体化器等光电子应用.它的高度化学稳定性和低毒性进一步增强了其在研究和工业环境中的效用.此外, GeS 由于其有利的电子和电传导特性,在能源储存和转换技术方面表现出很有潜力.

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上下游产品

digermyl sulfide hydrogen sulfide monogermylarsine germane

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    专利信息


    专利号:US-2007074541-A1
    优先权日:2003-10-10
    标 题:Synthesis of germanium sulphide and related compounds
    发明人:BADDING JOHN V; HEWAK DANIEL W; HUANG CHUNG-CHE
    权利人:UNIV SOUTHAMPTON
    摘要:The invention relates to synthesis of germanium sulphide glasses and optical devices formed therefrom. In a chemical vapour deposition process, germanium tetrachloride is reacted with hydrogen sulphide at temperatures in the range 450-700° C. to form germanium sulphide. Lower temperatures within this range of 450-550° C. directly produce a glass, whereas higher temperatures within the range of 600-700° C. produce a crystalline powder which can then be reduced to a glass by subsequent melting and annealing. The reaction is preferably carried out at atmospheric pressure or slightly higher. Thin films and bulk glasses suitable for optical waveguides can be formed directly in one processing step as can powders and microspheres. The materials synthesised are of a high purity with low oxide impurities and only trace levels of transition metal ions.

    专利号:US-2011171816-A1
    优先权日:2007-10-18
    标题:Synthesis of germanium sulfide and related compounds for solid electrolytic memory elements and other applications
    发明人:TOMPA GARY S; COLEMAN ELANE; PROVOST LLOYD G
    权利人:STRUCTURED MATERIALS INC
    摘要:A method for making high purity GeS and related compounds such as Germanium Silicon Sulfide (GeSiS); Copper Sulfide (CuS); Silicon Sulfide (SiS); Zinc Sulfide (ZnS) and Iron Sulfide (FeS) at low temperatures and pressures in a Chemical Vapor Deposition (CVD) process for solid electrolyte memory elements and other applications. Disclosed is a method of generating a proper chemical and energy environment for the formation of GeS and related compounds on a specific surface. The produced films have utility in memory and other devices. The technology offers cost savings and the advantage of low temperature film creation through the use of plasma assisted deposition—increasing its compatibility for use not only on silicon (or ceramic or glass) non metal substrates as well as polymer or thin metal foil substrates which would be damaged by higher temperature processes.

    专利号:WO-2005035455-A1
    优先权日:2003-10-10
    标题:Synthesis of germanium sulphide and related compounds

    专利号:GB-0323805-D0
    优先权日:2003-10-10
    标题:Synthesis of germanium sulphide and related compounds

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    主要参考文献

    [参考文献]: Sankaran Murugesan, Et Al. Electrochemical Deposition Of Germanium Sulfide From Room-Temperature Ionic Liquids And Subsequent Ag Doping In An Aqueous Solution. Langmuir. 2012 Apr 3;28(13):5513-7.
    [参考文献]: Yong Jae Cho, Et Al. Germanium Sulfide(Ii And Iv) Nanoparticles For Enhanced Performance Of Lithium Ion Batteries. Chem Commun (Camb). 2013 May 21;49(41):4661-3.

    合成参考文献


    参考文献:10.1007/978-3-031-86006-5_9
    摘要:Sutter P. Recombination. 2025. In: Introduction to Semiconductors.
    参考文献:10.1007/978-3-031-86006-5_5
    摘要:Sutter P. The Density of Band States. 2025. In: Introduction to Semiconductors.
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