CAS: 64421-27-8; (1S,4As,7S,7As)-Methyl 7-Hydroxy-7-Methyl-1-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)-1,4A,5,6,7,7A-Hexahydrocyclopenta[c]Pyran-4-Carboxylate
该化合物是一个复杂的有机化合物,其特点是独特的双环结构以及多种功能组的存在.该化合物具有一种晶体基质,表明它是一种晶质,有助于其溶性及潜在的生物活动.氢氧基化合物的存在表明它可能表现出氢联结能力,影响其再活性和与其他分子的相互作用.该物质可进行水解,以释放相应的碳箱酸.其立体结构在几个乳房中心中标明,其立体化学成型对生物活动及其与酶或受体的相互作用至关重要.
- 英文名称(1S,4As,7S,7As)-Methyl 7-Hydroxy-7-Methyl-1-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)-1,4A,5,6,7,7A-Hexahydrocyclopenta[c]Pyran-4-Carboxylate
- 中文名称玉叶金花甙酸甲酯
- IUPAC名称methyl (1S,4aS,7S,7aS)-7-hydroxy-7-methyl-1-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylate
- 其它别名(1S,7S)-1-(β-D-Glucopyranosyloxy)-1,4Aα,5,6,7,7Aα-Hexahydro-7-Hydroxy-7-Methylcyclopenta[c]Pyran-4-Carboxylic Acid Methyl Ester; Mussaenoside; Mussaeside; Cyclopenta[c]Pyran-4-Carboxylicacid, 1-(B-D-Glucopyranosyloxy)-1,4A,5,6,7,7A-Hexahydro-7-Hydroxy-7-Methyl-,Methyl Ester, (1S,4As,7S,7As)-; Cyclopenta[c]Pyran-4-Carboxylic Acid, 1-(β-D-Glucopyranosyloxy)-1,4A,5,6,7,7A-Hexahydro-7-Hydroxy-7-Methyl-, Methyl Ester, (1S,4As,7S,7As)-; Methyl(1S,4As,7S,7As)-1-(β-D-Glucopyranosyloxy)-7-Hydroxy-7-Methyl-1,4A,5,6,7,7A-Hexahydrocyclopenta[c]Pyran-4-Carboxylate; (1S,4As,7S,7As)-Methyl 7-Hydroxy-7-Methyl-1-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)-1,4A,5,6,7,7A-Hexahydrocyclopenta[c]Pyran-4-Carboxylate
- CAS编号64421-27-8
- MFCD编号:MFCD20260824
- FDA UNII编号:G74LVE833Z
- 分子式:C17H26O10分子量:390.39
- 产品CID: 1628364
- 产品分类天然产物 → 环烯醚萜衍生物
物理性质
MSDS等安全信息
上下游产品
ladroside ipolamiide lamiide合成工艺路线路线简述
📜Ladroside置于sodium Hydroxide体系中,用 甲醇 作为反应溶剂,化学反应生成 Trans-咖啡酸,玉叶金花甙酸甲酯
参考文献:Ladroside(= 6'-Caffeoyl-Mussaenoside),一种来自veronica Officinalis L.(scrophulariaceae)的新的鸢尾糖苷,并阐明了mussaenoside的c(8)处的绝对构型†
标题:Ladroside(= 6'-Caffeoyl-Mussaenoside),一种来自veronica Officinalis L.(scrophulariaceae)的新的鸢尾糖苷,并阐明了mussaenoside的c(8)处的绝对构型†
摘要:从veronica Officinalis L中分离出了一种新的鸢尾糖苷,名为ladroside,与mussaenoside (1) [2]分离.通过光谱分析已确定了ladroside (4)的结构和mussaenoside的身份.此外,通过化学证据已经确定了在c(8)上带有叔羟基的绝对构型.
DOI:10.1002/hlca.19810640104
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905143000-叔丁醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
1: Gomes AF, Almeida MP, Leite MF, Schwaiger S, Stuppner H, Halabalaki M, Amaral JG, David JM. Seasonal variation in the chemical composition of two chemotypes of Lippia alba. Food Chem. 2019 Feb 1;273:186-193. doi: 10.1016/j.foodchem.2017.11.089. Epub 2017 Nov 23. 18(10):12109-18. doi: 10.3390/molecules181012109.
3: Amin A, Tuenter E, Foubert K, Iqbal J, Cos P, Maes L, Exarchou V, Apers S, Pieters L. In Vitro and In Silico Antidiabetic and Antimicrobial Evaluation of Constituents from Kickxia ramosissima (Nanorrhinum ramosissimum). Front Pharmacol. 2017 May 1;8:232. doi: 10.3389/fphar.2017.00232.
4: Vogl S, Atanasov AG, Binder M, Bulusu M, Zehl M, Fakhrudin N, Heiss EH, Picker P, Wawrosch C, Saukel J, Reznicek G, Urban E, Bochkov V, Dirsch VM, Kopp B. The Herbal Drug Melampyrum pratense L. (Koch): Isolation and Identification of Its Bioactive Compounds Targeting Mediators of Inflammation. Evid Based Complement Alternat Med. 2013;2013:395316. doi: 10.1155/2013/395316. Epub 2013 Feb 26.
合成参考文献
参考文献:10.1016/0031-9422(91)83759-e
摘要:He ZD, Yang CR. Brandioside, a phenylpropanoid glycoside from Brandisia hancei. Phytochemistry. 1991;30(2):701–2. doi: 10.1016/0031-9422(91)83759-e.
参考文献:10.1016/s0031-9422(00)95221-x|10.1016/s0031-9422(00)95234-8
摘要:Liu ZM, Jia ZJ. Phenylpropanoid and iridoid glycosides from Pedicularis striata. Phytochemistry. 1991;30(4):1341–4. doi: 10.1016/s0031-9422(00)95221-x.
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