CAS: 627-40-7; 3-Methoxyprop-1-Ene

相似化合物

3970-20-5 18913-31-0 1471-03-0

上下游产品

1,2-epithio-3-methoxypropane triethyl phosphite methanol 3-ethoxyprop-1-ene 1,2-dibromo-3-methoxypropane cyclopropylmethyl methyl ether methyl 2-methoxy-4-pentenoate (2-(methoxymethyl)cyclopropyl)benzene

📜(甲氧基甲基)环氧乙烷置于一氧化碳,C29H32Irn5O,Bis(Trifluoromethane)Sulfonimide Lithium体系中,用 氘代苯 作为反应溶剂,80.0 °C,1.0 Mpa 条件下,反应 24.0H,以52%的收率获得产物烯丙基甲基醚
参考文献:用一氧化碳对环氧化物进行脱氧.
标题:用一氧化碳对环氧化物进行脱氧.
摘要:提出了使用一氧化碳作为直接还原剂将末端环氧化物和内部环氧化物脱氧成相应的烯烃.该反应由羰基钳-铱(I)络合物与路易斯酸助催化剂结合均匀催化,实现环氧化物底物的预活化,以及从γ-2-铱丁内酯中消除co 2中间的.特别是末端烷基环氧化物在co气氛下,苯或甲苯中,80-120oc下反应顺利,并且不会明显异构化为内烯烃.详细的研究揭示了环氧化物c−o键活化机制中底物依赖性变化,该变化发生在保留构型的氧化加成和导致构型反转的s N 2 反应之间.
DOI:10.1002/chem.202002651

专利信息

专利号:US-11220513-B2
优先权日:2015-04-30
标题:Chromium-mediated coupling and application to the synthesis of halichondrins
发明人：KISHI YOSHITO; YAN WUMING; LI JINGWEI; LI ZHANJIE; YAHATA KENZO
权利人:HARVARD COLLEGE
摘要:The present invention provides unified synthesis of the C1-C19 building blocks of halichondrins and analogs thereof using selective coupling of poly-halogenated nucleophiles in chromium-mediated coupling reactions. The present invention also provides a practical and efficient synthesis of C20-C38 building blocks of halichondrins and analogs thereof. Also provided herein are general methods of selective activation and coupling of poly-halogenated analogs with an aldehyde. The provided coupling reactions are selective for halo-enone and halo-acetylenic ketal over vinyl halide and halide attached to a sp hybridized carbon. The provided efficient selective coupling reactions can allow easy access to the C1-C19 building blocks and C20-C38 building blocks of halichondrins and analogs thereof with limited or no purification or separation of the intermediates.

专利号:US-4476252-A
优先权日:1982-11-06
标题 :Process for the synthesis of polymers with laterally linked polyoxyalkylene chains and their use for the production of polyurethanes
发明人：ESSELBORN EBERHARD; FOCK JUERGEN
权利人:GOLDSCHMIDT AG TH
摘要:Process for the synthesis of polymers with laterally linked polyoxyalkylene chains by the free radical polymerization of polyoxyalkylene ethers with olefinic double bonds with other vinyl compounds, capable of copolymerizing wherein the polyoxyalkylene ethers of allyl and/or methallyl alcohol are copolymerized in a known manner with vinyl esters of lower carboxylic acids or mixtures of vinyl esters of lower carboxylic acids with up to 50 mole percent of esters of acrylic or methacrylic acid. The compounds can be used to advantage as reaction components having hydroxyl groups in the production of polyurethanes. In particular, they improve the mechanical properties of polyurethane foams, such as, for example, their compression hardness.

专利号:US-2005240037-A1
优先权日:2002-07-23
标 题 :Method for the continuous intermediate separation of the solvent used in the oxirane synthesis with no coupling product
发明人：BASSLER PETER; GOBBEL HANS-GEORG; TELES JOAQUIN H; RUDOLF PETER
权利人:BASF AG
摘要:Process for the continuously operated distillation of the solvent used in the synthesis of an oxirane by reaction of a hydroperoxide with an organic compound, wherein the mixture comprising the solvent which is obtained in the synthesis and subsequent work-up is separated in a dividing wall column into a low-boiling fraction, an intermediate-boiling fraction and a high-boiling fraction and the solvent is taken off as intermediate-boiling fraction from the side offtake of the column.

专利号:US-12006540-B2
优先权日:2015-09-28
标题:Synthesis of novel disulfide linker based nucleotides as reversible terminators for DNA sequencing by synthesis
发明人：JU JINGYUE; LI XIAOXU; CHEN XIN; LI ZENGMIN; KUMAR SHIV; SHI SHUNDI; GUO CHENG; REN JIANYI; HSIEH MIN-KANG; CHIEN MINCHEN; TAO CHUANJUAN; ERTURK ECE; KALACHIKOV SERGEY; RUSSO JAMES J
权利人:UNIV COLUMBIA
摘要:Disclosed herein, inter alia, are compounds, compositions, and methods of use thereof in the sequencing of a nucleic acid.

专利号:US-5260402-A
优先权日:1990-06-21
标 题 :Curable organopolysiloxanes with oxyalkylene ether groups linked through SiOC groups, their synthesis and use
发明人：WEITEMEYER CHRISTIAN; DOEHLER HARDI
权利人:GOLDSCHMIDT AG TH
摘要:Curable organopolysiloxanes are disclosed which contain oxyalkylene ether groups linked through SiOC groups; the oxyalkylene ether groups have the formula ##STR1## A method for the synthesis of these compounds, as well as their use as casting compositions, adhesive coating agents and modifying additives for compounds which can be cured cationically, by free radicals, or by high-energy radiation are also disclosed.

专利号:US-6087512-A
优先权日:1996-09-18
标题:Process for preparation of glycidyl ether
发明人：FURUKAWA YOSHIRO; KITAORI KAZUHIRO; YANAGIMOTO TETSUYA; MIKAMI MASAFUMI; YOSHIMOTO HIROSHI; OTERA JUNZO
权利人:DAISO CO LTD
摘要:A process for preparation of a glycidyl ether which is characrelized in reacting an epoxy compound of the formula ##STR1## wherein X is halogen or sulfonyloxy in the presence of a fluoride salt, with an alcohol. According to the above method, glycigyl ethers or their optically active compounds important as intermediates for synthesis of medicines are easily obtained in good yield and especially the optically active compounds are obtained with highly optical purity.