CAS: 52093-30-8; Yttrium(Iii) Trifluoromethanesulfonate

该化合物是有机合成中广泛使用的多用途刘易斯酸催化剂,其强的电光性能和高热稳定性使得它能够有效促进Friedel-Crafts 烷基化,相互交融和循环等反应.三氟甲烷硫酸盐(Otf) 氮化能提高极地有机溶剂的溶解性,同时保持低核素,尽量减少副作用.这种化合物在不对称的催化和精细化学生产中特别有用,因为它与对水敏感的子质相容.在温度条件下的可循环性和持续性进一步有助于其在学术和工业应用中的用途.

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161337-67-3 139177-62-1 62086-04-8

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    专利信息


    专利号:US-11926589-B2
    优先权日:2019-07-09
    标 题 :Process for the synthesis of non-racemic cyclohexenes
    发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
    权利人:BASF CORP; CALIFORNIA INST OF TECHN
    摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

    专利号:WO-2023247609-A1
    优先权日:2022-06-22
    标题 :Process for the preparation of cyclohomogeranates
    发明人:SCHELWIES MATHIAS; BRUNNER BERNHARD; PELZER RALF; LIST BENJAMIN; TURBERG MATHIAS; MITSCHKE BENJAMIN; DAS SAYANTANI; DE CHANDRA KANTA
    权利人:BASF SE; STUDIENGESELLSCHAFT KOHLE GGMBH
    摘要:The present invention relates to a process for the preparation of cyclohomogeranates. The invention relates to the synthesis of cyclohomogeranates from well available esters of homogeranic acid in only one step. The cyclohomogeranates prepared according to the process of the present invention can be used in the fragrance industry as intermediates or the compounds can be used as such as aroma compound.

    专利号:US-8129560-B2
    优先权日:2005-08-15
    标 题 :Process for the synthesis of mandipropamid and derivatives thereof
    发明人:BOWDEN MARTIN CHARLES; CLARK THOMAS AITCHESON; GIORDANO FANNY; JAU BEAT; SCHNEIDER HANS-DIETER; SEIFERT GOTTFRIED; ZELLER MARTIN; FABER DOMINIK; WISS JUERG
    权利人:BOWDEN MARTIN CHARLES; CLARK THOMAS AITCHESON; GIORDANO FANNY; JAU BEAT; SCHNEIDER HANS-DIETER; SEIFERT GOTTFRIED; ZELLER MARTIN; FABER DOMINIK; WISS JUERG; SYNGENTA CROP PROT INC
    摘要:A process for the preparation of a compound of formula (I), the process comprising: (i) the reaction of a compound of formula (III), with a compound of formula (IV) to give a compound of formula (II), and (ii) the reaction of the compound of formula (II) with a leaving group, to give the compound of formula (I).

    专利号:US-2007100184-A1
    优先权日:2005-10-27
    标题 :Alkylation of aromatic compounds
    发明人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA
    权利人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA
    摘要:The present invention relates to the synthesis of alkylated aromatic compounds using ionic liquids as the solvent. Alkylated aromatic compounds are synthesized by reacting an aromatic compound with a monoolefin in the presence of an acid catalyst.

    专利号:US-2017121258-A1
    优先权日:2014-04-10
    标题 :Synthesis of r-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols
    发明人:SANBORN ALEXANDRA; BINDER THOMAS P
    权利人:ARCHER DANIELS MIDLAND CO
    摘要:Disclosed herein are methods for synthesizing 1,2,5,6-hexanetetrol (HTO), 1,6 hexanediol (HDO) and other reduced polyols from C5 and C6 sugar alcohols or R glycosides. The methods include contacting the sugar alcohol or R-glycoside with a copper catalyst, most desirably a Raney copper catalyst with hydrogen for a time, temperature and pressure sufficient to form reduced polyols having 2 to 3 fewer hydoxy groups than the starting material. When the starting compound is a C6 sugar alcohol such as sorbitol or R-glycoside of a C6 sugar such as methyl glucoside, the predominant product is HTO. The same catalyst can be used to further reduce the HTO to HDO.

    专利号:US-10519124-B2
    优先权日:2014-04-10
    标题 :Synthesis of R-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols
    发明人:STENSRUD KENNETH; Ma chi-cheng; MARTIN KEVIN
    权利人:ARCHER DANIELS MIDLAND CO
    摘要:Disclosed herein are methods for synthesizing 1,2,5,6-hexanetetrol (HTO), 1,6 hexanediol (HDO) and other reduced polyols from C5 and C6 sugar alcohols or R glycosides. The methods include contacting the sugar alcohol or R-glycoside with a copper catalyst, most desirably a Raney copper catalyst with hydrogen for a time, temperature and pressure sufficient to form reduced polyols having 2 to 3 fewer hydoxy groups than the starting material. When the starting compound is a C6 sugar alcohol such as sorbitol or R-glycoside of a C6 sugar such as methyl glucoside, the predominant product is HTO. The same catalyst can be used to further reduce the HTO to HDO.
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    合成参考文献


    参考文献:10.2478/s11532-010-0092-1
    摘要:Janus E, Syguda A, Materna K. Ionic liquids - deanol derivatives as the Diels-Alder reaction solvents. 2010 Sep 05;8(5):1140–6. doi: 10.2478/s11532-010-0092-1.
    参考文献:10.1007/978-4-431-56933-6_2
    摘要:Tashiro K. Synthetic Strategies of Molecular Sequences Linked with Static Bonds. 2023. In: NIMS Monographs.
    参考文献:10.1007/978-3-658-41568-6_13
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