1,2-二甲基环氧乙烷 反应生成 2,3-丁二硫醇 参考文献:Overberger,C.G.; Ferraro,J.J.,Journal Of Organic Chemistry,1962,Vol. 27,P. 3539-3545 标题:Overberger,C.G.; Ferraro,J.J.,Journal Of Organic Chemistry,1962,Vol. 27,P. 3539-3545
专利信息
专利号:US-8231848-B1 优先权日:2012-04-10 标题:One-pot synthesis of chalcopyrite-based semi-conductor nanoparticles 发明人:REN YUHANG; SUN CHIVIN; SHUM KAI 权利人:REN YUHANG; SUN CHIVIN; SHUM KAI; SUN HARMONICS LTD 摘要:Ternary and quaternary Chalcopyrite CuInxGa1-xSySe2-y (CIGS, where 0≰x and y≰1) nanoparticles were synthesized from molecular single source precursors (SSPs) by a one-pot reaction in a high boiling solvent using salt(s) (i.e. NaCl as by-product) as heat transfer agent via conventional convective heating method. The nanoparticles sizes were 1.8 nm to 5.2 nm as reaction temperatures were varied from 150° C. to 190° C. with very high-yield. Tunable nanoparticle size is achieved through manipulation of reaction temperature, reaction time, and precursor concentrations. In addition, the method developed in this study was scalable to achieve ultra-large quantities production of tetragonal and quaternary Chalcopyrite CIGS nanoparticles.
专利号:US-9896776-B2 优先权日:2011-09-21 标 题 :Chemical and electrochemical synthesis and deposition of chalcogenides from room temperature ionic liquids 发明人:STEVENSON KEITH J; MURUGESAN SANKARAN; KEARNS PATRICK; AKKINENI ARUNKUMAR 权利人:UNIV TEXAS 摘要:Room temperature electrochemical methods to deposit thin films of chalcogenide glasses.
专利号:US-9382462-B2 优先权日:2013-03-15 标 题:Metal ligand-containing prepolymers, methods of synthesis, and compositions thereof 发明人:RAO CHANDRA; DENG JUN; LIN RENHE 权利人:PRC DESOTO INT INC 摘要:Metal ligand-containing prepolymers, compositions containing metal ligand-containing prepolymers, methods of synthesizing metal ligand-containing prepolymers and the use of metal ligand-containing prepolymers in aerospace sealant applications are disclosed. The metal ligand-containing prepolymers have metal ligands incorporated into the backbone of the prepolymer. Cured sealant compositions comprising the metal ligand-containing prepolymers exhibit enhanced properties suitable for aerospace sealant applications.
专利号:US-9540540-B2 优先权日:2013-03-15 标 题:Sulfone-containing polythioethers, compositions thereof, and methods of synthesis 发明人:RAO CHANDRA; CAI JUEXIAO; LIN RENHE 权利人:PRC DESOTO INT INC 摘要:Sulfone-containing polythioethers, compositions containing sulfone-containing polythioethers, methods of synthesizing sulfone-containing polythioethers and the use of sulfone-containing polythioethers in aerospace sealant applications are disclosed. The sulfone-containing polythioethers have sulfone groups incorporated into the backbone of the polythioether. Cured sealant compositions comprising the sulfone-containing polythioethers exhibit enhanced thermal resistance.
专利号:US-8952124-B2 优先权日:2013-06-21 标 题 :Bis(sulfonyl)alkanol-containing polythioethers, methods of synthesis, and compositions thereof 发明人:RAO CHANDRA; CAI JUEXIAO; LIN RENHE 权利人:PRC DESOTO INT INC 摘要:Bis(sulfonyl)alkanol-containing polythioethers, compositions containing bis(sulfonyl)alkanol-containing polythioethers, methods of synthesizing bis(sulfonyl)alkanol-containing polythioethers and the use of bis(sulfonyl)alkanol-containing polythioethers in aerospace sealant applications are disclosed. The bis(sulfonyl)alkanol-containing polythioethers have bis(sulfonyl)alkanol groups incorporated into the backbone of the polythioether. Cured sealant compositions comprising the bis(sulfonyl)alkanol-containing polythioethers exhibit enhanced properties suitable for aerospace sealant applications.
专利号:US-10689333-B1 优先权日:2019-02-22 标 题 :2-mercaptoethanol synthesis 发明人:KREIDER JASON L; HASENBERG DANIEL M; PAUWELS ALEX 权利人:CHEVRON PHILLIPS CHEMICAL CO LP 摘要:A process comprising reacting, in a reactor having a fixed bed containing a solid catalyst which contains a zeolite, hydrogen sulfide and an oxirane in the presence of the solid catalyst to yield a reaction product with contains a mercapto-alcohol. A reactor system includes the reactor, an oxirane feed stream, a hydrogen sulfide feed stream, a fixed bed containing the solid catalyst placed inside the reactor, and an effluent stream containing the reaction product. The hydrogen sulfide and the oxirane are present in a mole ratio in a range of about 5:1 to 50:1.