CAS: 17454-47-6; 2,3,5,6,8,9,11,12-Octahydronaphtho[2,3-B][1,4,7,10,13]Pentaoxacyclopentadecine
该化合物是一种氯化萘替代物,15-crown-5醚,一种以其选择性地与碱性和碱性地球金属离子结合而闻名的大型环环化合物.环球替代物增加了其芳香特性,有可能改善其复合性,并增强有机溶剂的稳定性.该化合物在离子运输研究,逐步转移催化和作为分析化学中选择性的发热剂方面特别有用.该化合物的硬性环烷基骨与非代性冠醚相比,可以为特定凝固提供更好的选择性.该化合物的结构允许在传感器开发和分子识别系统中的潜在应用,需要精确的离子选择.
- 英文名称2,3,5,6,8,9,11,12-Octahydronaphtho[2,3-B][1,4,7,10,13]Pentaoxacyclopentadecine
- 中文名称2,3-萘并-15-冠醚-5
- IUPAC名称2,3,5,6,8,9,11,12-octahydronaphtho[2,3-b][1,4,7,10,13]pentaoxacyclopentadecine
- 其它别名2,3-Naphtho-15-Crown-5; 2,3-Naphtho-15-Crown-5 ; 2,3,5,6,8,9,11,12-Octahydronaphtho[2,3-B][1,4,7,10,13]Pentaoxacyclopentadecine; Naphtho[2,3-B]-1,4,7,10,13-Pentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-Octahydro-
- CAS编号17454-47-6
- MFCD编号:MFCD00068674
- EINECS号:805-679-4
- 分子式:C18H22O5分子量:318.37
- 产品CID: 891124
- 产品分类化学试剂 → 有机试剂 → 冠醚
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
2-(2-{3-[2-(2-hydroxyethoxy)ethoxy]naphthalen-2-yloxy}ethoxy)ethanol 2,3-naphthalenediol tetraethylene glycol di(p-toluenesulfonate) naphthalene β-naphthol 2,3-naphthalenediol 3,3-diphenyl-9,10,12,13,15,16,18,19-°Ctahydro-3H-[1,4,7,10,13]pentaoxacyclopentadeca[2′,3′:4,5]benzo[f]chromene合成工艺路线路线简述
📜2,3-二羟基萘置于盐酸,Sodium Hydroxide,对甲苯磺酰氯体系中,用 1,4-二氧六环,甲醇,二氯甲烷,正丁醇 用作溶剂,化学反应 31.0H,反应生成2,3-萘并-15-冠醚-5
参考文献:Czech,B.; Czech,A.; Bartsch,R. A.,Journal Of Heterocyclic Chemistry,1984,Vol. 21,P. 341-343
标题:Czech,B.; Czech,A.; Bartsch,R. A.,Journal Of Heterocyclic Chemistry,1984,Vol. 21,P. 341-343
海关参考信息
- 2902902000-精萘
2905310000-1,2-乙二醇
2907210001-间苯二酚
2909110000-乙醚 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:The Synthesis Of Some Aromatic Crown Ether Derivatives And Their Ion-Selective Electrode Properties作者:Elżbleta Luboch,Andrzej Cygan,Jan F. Lernat |发布日期:1990.1
摘要:The Synthesis Of Alkyl, Nitro And Halogeno Derivatives Of Benzo-15-Crown-5, Benzo- 18-Crown-6 And Naphtho-15-Crown-5 Has Been Reported. Also Some Novel Ester Type Bis(Crown Ether)S Have Been Prepared. Some Of The Compounds Have Been Characterized As Electroactive Substances In Pvc Membrane Ion-Selective Electrodes.
合成参考文献
参考文献:10.1055/s-2007-990822
摘要:Kotha S, Kashinath D, Khedkar P. Synthesis of Crown-Based Sulfones via Rongalite: Diversity-Oriented Approach to Annulated Benzocrowns by Diels-Alder Reactions. Synthesis. 2007 Nov;2007(21):3357–60. doi: 10.1055/s-2007-990822.
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