CAS: 16605-03-1; 3-(Diphenylphosphino)Propan-1-Amine

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3-chloropropan-1-amine potassium diphenylphosphine 1-chloro-3-azidopropane lithium diphenylphosphide γ aminopropyl phenyl phosphine 3-benzaldiminopropyldiphenylphosphine 2(CH2)3NCH)C6H4OH2-(PPh2(CH2)3NCH)C6H4OH 3-diphenylphosphinopropylamin°Carbonylmethane

2-氰基乙基二苯基膦置于lithium Aluminium Tetrahydride体系中,用 乙醚 用作溶剂,化学反应 60.0H,反应生成3-(二苯基膦基)丙胺
参考文献:将二苯基膦加到michael型烯烃上:膦腈和膦酸酯配体的制备
标题:将二苯基膦加到michael型烯烃上:膦腈和膦酸酯配体的制备
摘要:已经进行了五种迈克尔型烯烃与二苯基膦的反应.1-氰基环戊烯,1-氰基环己烯和4-叔丁基-1-氰基环己烯均提供相应的2-二苯基膦基-1-氰基环烷烃,丙烯酸甲酯和甲基丙烯酸乙酯均产生相应的2-二苯基膦酸丙酸酯.对于1-氰基环戊烯和1-氰基环己烯的产物,13 C和31 P NMR数据与反式(ph 2 P赤道和cn轴)和顺式(ph 2都)的形成一致.P和cn赤道)异构体.通过用吗啉的二甲基铝加合物处理-3-二苯基膦酸丙酸甲酯,可以得到3-二苯基膦酸丙酸的吗啉酰胺.该膦ph 2 Pmorph已分离为其钯(II)配合物(ph 2 Pmorph)2 Pdcl 2.通过使php(ch 2)2还原,使ph 2 P(ch 2)3 Nh 2反应,得到膦-苯甲二胺ph 2 P(ch 2)3 Nc(h)c 6 H 5.Cn,在分子筛存在下与苯甲醛一起使用.
Doi:10.1016/0022-328X(90)87207-T

专利信息

专利号:US-7977269-B2
优先权日:2005-07-21
标 题:Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
发明人：SMALL BROOKE L; CARNEY MICHAEL
权利人:CHEVRON PHILLIPS CHEMICAL CO
摘要:Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.

专利号:US-7728161-B2
优先权日:2005-07-21
标题:Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
发明人：SMALL BROOKE L; CARNEY MICHAEL
权利人:CHEVRON PHILLIPS CHEMICAL CO
摘要:Methods for making α-diimine metal complexes are described. The methods comprise forming an α-diimine metal complex imine bond in the presence of a metal salt or an α-acylimine metal complex. The method is particularly using for the production of α-diimine metal complexes having two different α-diimine nitrogen groups. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins.

专利号:US-7728160-B2
优先权日:2005-07-21
标 题 :Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
发明人：SMALL BROOKE L; CARNEY MICHAEL
权利人:CHEVRON PHILLIPS CHEMICAL CO
摘要:Novel α-diimine metal complexes, particularly iron complexes are disclosed. The α-diimine metal complexes are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. α-diimine metal complexes having two different α-diimine nitrogen groups may be produced. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins.

专利号:EP-1904509-B1
优先权日:2005-07-21
标题:Diimine metal complexes, synthesis, and use in oligomerization and polymerization
发明人：SMALL BROOKE L; CARNEY MICHAEL
权利人:CHEVRON PHILLIPS CHEMICAL CO
摘要:Methods for making α-diimine metal complexes are disclosed. The methods comprise forming an α-diimine metal complex imine bond in the presence of a metal salt or an ce-acylimine metal complex. The method is particularly using for the production of α-diimine metal complexes having two different α-diimine nitrogen groups. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins. Novel α-diimine metal complexes, particularly iron complexes are disclosed. The α-diimine metal complexes are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex, α-diimine metal complexes having two different α-diimine nitrogen groups may be produced. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins. Processes to polymerize or oligomerize olefins by contacting olefins with α-diimine metal complexes are disclosed. In particular, alpha olefins can be produced in high selectivity by contacting ethylene with selected α-diimine metal complexes.

专利号:US-2007112150-A1
优先权日:2005-07-21
标题 :Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization

专利号:US-2008004441-A1
优先权日:2005-07-21
标 题:Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization