CAS: 1937-62-8; (E)-Methyl Octadec-9-Enoate

相似化合物

112-62-9 112-79-8 1120-25-8

上下游产品

油酸甲酯 Methyl Oleate 112-62-9
反油酸甲酯 Octadec-9-Enoic Acid Methyl Ester 2462-84-2
亚油酸甲酯 Methyl Linoleate 112-63-0
甲基反亚油酸酯 Methyl Linolelaidate 2566-97-4
油酸 Cis-Octadecenoic Acid 112-80-1
反油酸 Elaidic Acid 112-79-8
(Z)-7-十二碳烯-1-醇乙酸酯 (Z)-7-Dodecenyl Acetate 14959-86-5
甲基9,10-二溴硬脂酸酯 Erythro-9,10-Dibromooctadecanoic Acid 25456-04-6 (+/-)-Threo-9,10-Dibromo-Octadecanoic Acid Methyl Ester (E)-9,10-Epoxyoctadecanoic Acid Methyl Ester

📜油酸甲酯置于zinc Sulfide体系中,用 甲醇 用作溶剂,化学反应生成反-9-十八碳烯酸甲酯
参考文献:半导体光催化.第 6 部分. 表面态俘获空穴诱导的简单烯烃的顺反光异构化
标题:半导体光催化.第 6 部分. 表面态俘获空穴诱导的简单烯烃的顺反光异构化
摘要:使用 Zns 或 Cds 作为光催化剂诱导简单烯烃(例如 2-辛烯,3-己烯-1-醇和 9-十八碳烯酸甲酯)的有效顺反光异构化,其光稳态顺反比几乎与热力学相同苯硫基达到的平衡比率.顺反光异构化的量子产率 Phi Ct/ 大大超过了 1.涉及 Stern-Volmer 分析,氧的淬灭效应和在 Zns 在甲醇中的带隙照射下的 Esr 分析的机理研究表明,光异构化发生在活性位点处的高周转数,其中在表面状态捕获空穴,即产生硫自由基来自硫化物半导体上的锌空位和/或间隙硫,起着决定性的作用.由含多硫化物的 Na 2/s 溶液制备的 Zns 溶胶发生了高效的催化作用.水作为非常好电子受体的增强作用以及二乙胺作为电子供体的猝灭作用进一步支持了陷阱空穴机制.
Doi:10.1021/ja00264A014

专利信息

专利号:WO-2018191373-A1
优先权日:2017-04-12
标 题:Synthesis and characterization of metathesis catalysts
发明人：JOHNS ADAM
权利人:MATERIA INC
摘要:This invention relates generally to olefin metathesis catalysts, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, and the use of such compounds in the metathesis of olefins and in the synthesis of related olefin metathesis catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and in industrial applications such as oil and gas, fine chemicals and pharmaceuticals.

专利号:WO-2023248205-A1
优先权日:2022-06-23
标 题 :Novel ruthenium complexes, method of their synthesis, intermediate compounds used in this method, method of their synthesis and the use of novel ruthenium complexes in olefin metathesis reactions
发明人：GRELA KAROL; KAJETANOWICZ ANNA; SYTNICZUK ADRIAN; MILEWSKI MARIUSZ; PUROHIT VISHAL; STRUZIK FILIP
权利人:UNIV WARSZAWSKI
摘要:The subject of the invention is a novel ruthenium complex with the general formula Ru-1, in which all the variables have the meaning defined in the disclosure. The subject of the invention is also a synthesis method of the ruthenium complex, an intermediate which is a precursor of the ligand used in the synthesis reactions of the ruthenium complex CAAC-1 and application of this ruthenium complex as a (pre)catalyst in olefin metathesis reactions.

专利号:US-2023095259-A1
优先权日:2020-06-01
标 题:Synthesis of pheromone derivatives via z-selective olefin metathesis

专利号:US-2015065682-A1
优先权日:2013-08-30
标 题 :Aliphatic polyesters and copolyesters derived from natural oils and their related physical properties
发明人：NARINE SURESH; BOUZIDI LAZIZ; LI SHAOJUN; JOSE JESMY; POURFALLAH GHAZALEH
权利人:ELEVANCE RENEWABLE SCIENCES
摘要:The synthesis of certain medium and long chain ω-hydroxy esters and certain ω-hydroxy fatty acids is disclosed. Such ω-hydroxy esters and ω-hydroxy fatty acids are derived from natural oils, and their corresponding polymers were obtained by melt polycondensation. Additionally, the present effort investigates the effects of structural and molecular parameters on the thermal and mechanical properties of ω-hydroxy ester based polymers. Additionally, the present effort investigates the co-polymerization of ω-hydroxy ester based polymers.

专利号:US-5798434-A
优先权日:1994-03-16
标 题 :Monomer mixture and method for the preparation thereof
发明人：KIGAWA HITOSHI; YAMAGISHI HIROSHI; SUZUKI NORIKO; ASAO YOSHIKAZU
权利人:LION CORP
摘要:PCT No. PCT/JP95/00423 Sec. 371 Date Aug. 30, 1996 Sec. 102(e) Date Aug. 30, 1996 PCT Filed Mar. 15, 1995 PCT Pub. No. WO95/25133 PCT Pub. Date Sep. 21, 1995A monomer mixture having a hydroxyl value ranging from 0 to 134 KOH mg/g, obtainable by polymerizing a mixed raw material of an unsaturated compound selected from the group consisting of fatty acids each having one carboxyl group and one double bond in the molecule and having 11 to 22 carbon atoms and lower alkyl esters thereof with an unsaturated compound selected from the group consisting of fatty acids each having one carboxyl group and 2 to 4 double bonds in the molecule and having 11 to 22 carbon atoms and whose iodine value ranges from 30 to 130 g (iodine)/100 g to give dimers and trimers, then converting the carboxyl groups (or the lower alkyl ester group in case of the lower alkyl esters) present in the resulting dimers and trimers into hydroxyl groups through reduction to give a mixture substantially consisting of dimer diols and trimer triols, and then subjecting the mixture having a dimer diol/trimer triol weight ratio ranging from 30/70 to 99/1 to an esterification reaction with an alpha , beta -unsaturated carboxylic acid or a transesterification reaction with a lower alkyl ester of an alpha , beta -unsaturated carboxylic acid. The monomer mixture is useful in the synthesis of polymers such as various kinds of resin materials for optical applications.

专利号:US-10857530-B2
优先权日:2015-12-10
标题 :Olefin metathesis catalysts
发明人：JOHNS ADAM M; MONTGOMERY T PATRICK; AHMED TONIA S; GRUBBS ROBERT H; PEDERSON RICHARD L
权利人:UMICORE AG & CO KG; CALIFORNIA INST OF TECHN
摘要:This invention relates generally to metathesis catalysts and the use of such catalysts in the metathesis of olefins and olefin compounds, more particularly, in the use of such catalysts in Z and E selective olefin metathesis reactions. The invention has utility in the fields of organometallics and organic synthesis.