CAS: 97-41-6; Ethyl 2,2-Dimethyl-3-(2-Methylprop-1-En-1-yl)Cyclopropanecarboxylate

• 英文名称Ethyl 2,2-Dimethyl-3-(2-Methylprop-1-En-1-yl)Cyclopropanecarboxylate
• 中文名称菊酸乙酯
• IUPAC名称ethyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate
• 其它别名Ethyl 2,2-dimethyl-3-(1-isobutenyl)cyclopropane-1-carboxylate
• CAS编号97-41-6
• MFCD编号:MFCD00001304
• EINECS号:202-579-7
• 分子式:C12H20O2
• 分子量:196.29
• 产品CID: 2021434
• 产品分类有机原料→分子砌块→脂肪环类化合物→环丙烷类化合物

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: VIMXTGUGWLAOFZ-UHFFFAOYNA-N
• InChI=1/C12H20O2/c1-6-14-11(13)10-9(7-8(2)3)12(10,4)5/h7,9-10H,6H2,1-5H3…
• 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数3.0

相似化合物

物理性质

• 熔点0 °C
• 沸点240.8±0.0 °C at 760 mmHg
• 闪点84°C
• 密度1.0±0.1 g/cm3
• PSA:26.3
• LogP:2.7879
• 折射率1.507
• 蒸汽压0.0±0.4 mmHg at 25°C
• 溶解性Chloroform (Slightly), Methanol (Slightly)
• 外观形态黄色液体
• 储存条件2-8°C
• 产品应用该化合物用于制备具有杀虫活动的跨硝基硝基苯基和跨北转苯丙胺.

MSDS等安全信息

• GHS象形图
• GHS符号GHS09;
  注释: Environment
• 危险类别水生慢性毒性 类别2
• 警示词Warning
• 危险描述H411 |对水生生物有毒并具有长期持续影响.
• 防范说明P261-P280-P302+P352
• 危险等级3
• UN编号UN1993
• 危险品标志Xn
• 安全声明24/25
• 危险类别码S24/25:Prevent skin and eye contact.
• WGK Germany2

欧盟法规

上下游产品

合成工艺路线路线简述

• 764-13-6 + 98684-92-5 = 97-41-6
  反应条件:1.1 Reagents: Acetic Acid Solvents: Water; Ph 3.5 - 4.51.2 Reagents: Sodium Nitrite Solvents: 1,2-Dichloroethane; 4.5 H,10 - 15 °C; 45 Min,10 - 15 °C1.3 Catalysts: Cuprous Chloride,Copper(Ii) Tetrafluoroborate; 11 H,90 - 95 °C; 45 Min,90 - 95 °C
  标题:Preparation Method Of Ethyl Chrysanthemate Using Glacial Acetic Acid
  参考文献:China]
  
  764-13-6 + 623-33-6 = 97-41-6
  反应条件:1.1 Reagents: Sodium Nitrite Solvents: Acetic Acid,Dimethyl Carbonate,Water; 4 - 5 H,Ph 3.5 - 4.5,20 - 25 °C; 60 Min,20 - 25 °C1.2 Reagents: Cuprous Chloride; Rt -> 95 °C; 10 - 12 H,90 - 95 °C; 90 Min,90 - 95 °C
  标题:Method For Preparation Of Ethyl Chrysanthemate
  参考文献:China]
  
  764-13-6 = 97-41-6
  反应条件:1.1 Catalysts: Aqua[n-[[2-(Hydroxy-Ko)Phenyl]Methylene]Glycinato(2-)-Kn,Ko]Copper
  标题:Catalytic Role Of Copper Compounds In The Synthesis Of Chrysanthemate
  作者:Li,Zhengning; Chen,Huilin; Yu,Zhenyuan; Guo,Hefu
  参考文献:Fenzi Cuihua 日期:1992 卷标:6(4) 页码:286-90]
  
  2158-64-7 = 97-41-6
  反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethylformamide
  标题:Synthesis Of Trans-Chrysanthemic Acid From Levulinic Acid
  作者:Julia,Marc; Julia,Sylvestre; Langlois,Michel
  参考文献:Bulletin De La Societe Chimique De France 日期:1965 卷标:(4) 页码:1014-19]
  
  764-13-6 = 97-41-6
  反应条件:1.1 Catalysts: Copper(Ii) Triflate,Oxazole,2,2′-Methylenebis[4,5-Dihydro-4,5,5-Triphenyl-,(4R,4′r)- Solvents: Butyl Chloride
  标题:Copper Complexes Of Optically Active Bisoxazolines As Enantioselective Catalysts In Cyclopropanation Reactions
  参考文献:European Patent Organization]
  
  53434-70-1 = 97-41-6
  反应条件:1.1 Reagents: Caronic Acid Solvents: Benzene
  标题:Synthesis Of Trans-Chrysanthemic Acid From Dimethylacrolein And Of Trans-Norchrysanthemic Acid From Crotonaldehyde
  作者:Julia,Marc; Julia,Sylvestre; Langlois,Michel
  参考文献:Bulletin De La Societe Chimique De France 日期:1965 卷标:(4) 页码:1007-14]
  
  77600-82-9 + 638-10-8 = 97-41-6
  反应条件:1.1 Reagents: Tetramethylammonium Iodide,Sodium Hydroxide Solvents: Dimethylformamide
  标题:Reaction Of Allyl Nonafluorobutyl Sulfones With Michael Acceptors. Synthesis Of Chrysanthemic Acid Derivatives
  作者:Hanack,Michael; Auchter,Anneliese; Wunde,Christian; Stoll,Theodor
  参考文献:Liebigs Annalen Der Chemie 日期:1989 卷标:(9) 页码:853-8]
  
  84524-95-8 = 97-41-6
  反应条件:1.1 Catalysts: Tetrabutylammonium Chloride
  标题:Phase-Transfer Catalyzed Synthesis Of Cyclopropanecarboxylic Acid Esters
  作者:Lantzsch,Reinhard
  参考文献:Synthesis 日期:1982 卷标:(11) 页码:955-6]
  
  = 97-41-6 [标题:Reaction Conditions
  标题:Cyclopropanecarboxylic Acid Salts And Their Application
  参考文献:Hungary]
  
  764-13-6 = 97-41-6
  反应条件:1.1 Catalysts: Hydrazine,Phenyl-,Cupric Acetate,α-[(1R)-1-[[(2-Hydroxyphenyl)Methylene]Amino]Ethyl]-2-Methoxy-α-(2-Methoxyphenyl...; 2 H,80 °C; 1 H,25 °C
  标题:Method For Producing Optically Active Chrysanthemic Acid
  参考文献:European Patent Organization]
  
  764-13-6 = 97-41-6
  反应条件:1.1 Catalysts: Zirconium,Dodecakis(Benzoato)Dodecahydroxyoctakis(Iodocopper)Octakis[[1,1′,1′′-... (Demetallated; Post-Treated With [cu(Ch3Cn)]Bf4) Solvents: Dichloromethane; 5 H,Rt; 9 H,Rt
  标题:Reversible Metalation And Catalysis With A Scorpionate-Like Metallo-Ligand In A Metal-Organic Framework
  作者:Sun,Chenyue; Skorupskii,Grigorii; Dou,Jin-Hu; Wright,Ashley M.; Dinca,Mircea
  参考文献:Journal Of The American Chemical Society 日期:2018 卷标:140(50) 页码:17394-17398]
  
  764-13-6 + 623-33-6 = 97-41-6
  反应条件:1.1 Reagents: Sodium Acetate,Sodium Nitrite Solvents: Acetic Acid,Dichloromethane,Water; 2 Min,15 °C1.2 Reagents: Hydrazine,Phenyl-,2,6-Di-Tert-Butyl-4-Methylphenol,Sodium Stearate; 2 Min,97 °C
  标题:Method For Synthesis Of Ethyl Chrysanthemate Via Diazotization And Cyclization In Microreactor
  参考文献:China]
  
  764-13-6 = 97-41-6
  反应条件:1.1 Catalysts: Dirhodium Tetraacetate Solvents: Dichloromethane; 30 Min,Rt1.2 Solvents: Dichloromethane; Rt; 24 H,Rt
  标题:Bottom-Up Synthesis Of Acrylic And Styrylic Rhii Carboxylate Polymer Beads: Solid-Supported Analogs Of Rh2(Oac)4
  作者:Levchenko,Vladimir; Sundsli,Bard; Oien-Odegaard,Sigurd; Tilset,Mats; Hansen,Finn K.; Et Al
  参考文献:European Journal Of Organic Chemistry 日期:2018 卷标:2018(44) 页码:6150-6157]
  
  764-13-6 + 623-33-6 = 97-41-6
  反应条件:1.1 Catalysts: (Sp-5-12)-Iodo[5,10,15,20-Tetraphenyl-21H,23H-Porphinato(2-)-Kn21,Kn22,Kn23,Kn24... Solvents: Dichloromethane,Water1.2 Reagents: Sodium Nitrite,Sulfuric Acid Solvents: Water
  标题:5,10,15,20-Tetraphenylporphyrinatorhodium(Iii) Iodide Catalyzed Cyclopropanation Reactions Of Alkenes Using Glycine Ester Hydrochloride
  作者:Barrett,Anthony G. M.; Braddock,D. Christopher; Lenoir,Isabelle; Tone,Hitoshi
  参考文献:Journal Of Organic Chemistry 日期:2001 卷标:66(24) 页码:8260-8263]
  
  764-13-6 = 97-41-6
  反应条件:1.1 Reagents: 2,3-Dimethyl-2-Butene Solvents: 1,2-Dichloroethane
  标题:Method For Preparation Of Rel-(1R,3R)-3-(2-Chloro-3,3,3-Trifluoro-1-Propen-1-Yl)-2,2-Dimethylcyclopropanecarboxylic Acid
  参考文献:China]
  
  764-13-6 = 97-41-6
  反应条件:1.1 Reagents: Glucose Catalysts: Cytochrome P 450Bm-3 Precursor [268-Alanine,400-Serine] (Bacillus Megaterium St... Solvents: Methanol,Water; Ph 8,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water
  标题:In Vivo And In Vitro Olefin Cyclopropanation Catalyzed By Engineered And Chimeric Heme Enzymes
  参考文献:World Intellectual Property Organization]
  
  764-13-6 = 97-41-6
  反应条件:1.1 Catalysts: Copper,[hydrotris[3-(2,4,6-Trimethylphenyl)-1H-Pyrazolato-Kn1]Borato(1-)-Kn2,Kn...
  标题:{hydrotris(3-(2,4,6-Trimethylphenyl))Pyrazolylborate}Copper,Tpmscu
  作者:Perez,Pedro J.; Diaz-Requejo,M. Mar
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]
  
  = 97-41-6 [标题:Reaction Conditions
  标题:Preparation Of Alkyl Chrysanthemate
  参考文献:China]
  
  = 97-41-6 [标题:Reaction Conditions
  标题:Alkyl Cyclopropanecarboxylates
  参考文献:Hungary]
  
  = 97-41-6 [标题:Reaction Conditions
  标题:3-Alkene-1-Yl-2,2-Dimethylcyclopropanecarboxylic Acid 4-Fluoro-3-Phenoxybenzylesters And Their Use In Pesticides
  参考文献:European Patent Organization

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
  2905121000-正丙醇
  2909110000-乙醚
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