CAS: 959-23-9; 1-(4-Methoxyphenyl)-3-Phenylprop-2-En-1-One

• 英文名称1-(4-Methoxyphenyl)-3-Phenylprop-2-En-1-One
• 中文名称4'-甲氧基查耳酮
• IUPAC名称(E)-1-(4-methoxyphenyl)-3-phenylprop-2-en-1-one
• 其它别名4'-甲氧基查尔酮
• CAS编号959-23-9
• MFCD编号:MFCD00008407
• EINECS号:213-495-5
• 分子式:C16H14O2分子量:238.29
• 产品CID: 2014210
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• 产品信息参考;;;
• InChIKey: KJHHAPASNNVTSN-UHFFFAOYSA-N
• InChI=1S/C16H14O2/c1-18-15-10-8-14(9-11-15)16(17)12-7-13-5-3-2-4-6-13/h2-12H,1H3/b12-7+
• 计算化学: 氢键受体数2.0氢键供体数0可旋转键数4

物理性质

• 熔点101-103 °C
• 沸点397.5±42.0 °C at 760 mmHg
• 闪点180.5 °C
• 密度1.114g/cm3
• PSA:26.3
• LogP:3.5913
• 折射率1.606
• 溶解性Soluble In Dichloromethane And Methanol. Insoluble In Water.
• 敏感性常温常压下稳定，避免氧化物接触
• 外观形态白色至淡黄色固体
• 储存条件存储温度 2-8°C
• 产品应用该化合物用于在七氯代苯作为溶剂的情况下对氨基磷进行反应,以制备3-(4-METHOXY-苯基)-3-无色醇-4-YL-1-苯基-丙烷-1-1-1-一.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• 危险品标志Xi
• 安全声明26-36
• 危险类别码36/37/38
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Ethanol,Water; Overnight,5 - 10 °C
  标题:An Eco-Friendly Synthesis Of 2-Pyrazoline Derivatives Catalysed By Cecl3.7H2O
  作者:Bhat,Prabhat; Shridhar,Gomathi; Ladage,Savita; Ravishankar,Lakshmy
  参考文献:Journal Of Chemical Sciences (Berlin 日期:2017 卷标:129(9) 页码:1441-1448]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Catalysts: Barium Hydroxide Solvents: 1-Ethyl-3-Methylimidazolium Dicyanamide; 7 H,Rt
  标题:Large Acceleration Under Highly Concentrated Conditions: Synthesis Of Chalcones Using A Small Amount Of Dmf Or [emim]N(Cn)2
  作者:Tanemura,Kiyoshi
  参考文献:Results In Chemistry 日期:2022 卷标:4]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Ethanol,Water; Cooled; 3 H,Rt
  标题:Recyclable Copper Nanoparticles-Catalyzed Hydroboration Of Alkenes And β-Borylation Of α,β-Unsaturated Carbonyl Compounds With Bis(Pinacolato)Diboron
  作者:Shegavi,Mahadev L.; Saini,Suresh; Bhawar,Ramesh; Vishwantha,Meghana Desai; Bose,Shubhankar Kumar
  参考文献:Advanced Synthesis & Catalysis 日期:2021 卷标:363(9) 页码:2408-2416]
  
  123-11-5 + 98-86-2 = 959-23-9
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Ethanol,Water; 3 H,Rt; Overnight,Rt
  标题:A Simple And Practical Method For The Synthesis Of 2-Amino-5,6-Dihydro-5,7-Diarylquinazolin-4-Ols
  作者:Senguttuvan,S.; Nagarajan,Samuthira
  参考文献:Journal Of Heterocyclic Chemistry 日期:2009 卷标:46(6) 页码:1346-1348]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Catalysts: Sodium Hydroxide,Water,Agar Solvents: Ethanol; 90 Min,28 - 30 °C
  标题:Novel Gel-Entrapped Base Catalysts For The Claisen-Schmidt Reaction
  作者:Chaphekar,Sachin S.; Samant,Shriniwas D.
  参考文献:Journal Of Chemical Technology And Biotechnology 日期:2004 卷标:79(7) 页码:769-773]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Catalysts: Sodium Nitrate Solvents: Water; 30 Min,Rt1.2 Reagents: Oxygen; 2 H,900 °C1.3 Reagents: 1-Ethyl-3-(3′-Dimethylaminopropyl)Carbodiimide Hydrochloride Solvents: Methanol; 24 H,Rt
  标题:Application Of Natural Phosphate Modified With Sodium Nitrate In The Synthesis Of Chalcones: A Soft And Clean Method
  作者:Sebti,Said; Solhy,Abderrahim; Tahir,Rachid; Abdelatif,Smahi; Boulaajaj,Said; Et Al
  参考文献:Journal Of Catalysis 日期:2003 卷标:213(1) 页码:1-6]
  
  123-11-5 + 98-86-2 = 959-23-9
  反应条件:1.1 Catalysts: (Sp-4-1)-Bis[ethyl (2E)-2-(Phenylmethylene)Hydrazinecarbodithioato-Kn2,Ks′1]Nick... Solvents: Water; 60 Min,55 °C
  标题:Effect Of Phosphorus Amount On The Particle Size And Catalytic Performance Of Heterogeneous Nickel(Ii) Schiff-Base Complex In Aldol Condensation Reaction
  作者:Eshtiagh-Hosseini,Hossein; Tabari,Taymaz
  参考文献:Phosphorus 日期:2013 卷标:188(12) 页码:1778-1791]
  
  621-82-9 + 100-66-3 = 959-23-9
  反应条件:1.1 Catalysts: Aluminum Triflate (Crosslinked-Polystyrene-Supported Aluminum Triflate); 3.1 H,80 °C
  标题:Friedel-Crafts Acylation Of Arenes With Carboxylic Acids Using Polystyrene-Supported Aluminum Triflate
  作者:Boroujeni,Kaveh Parvanak; Parvanak,Kamran
  参考文献:Journal Of The Serbian Chemical Society 日期:2011 卷标:76(2) 页码:155-163]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Catalysts: Potassium Hydroxide; 5 Min,Rt
  标题:Advanced Mechanochemistry Device For Sustainable Synthetic Processes
  作者:Gomes,Carla; Vinagreiro,Carolina S.; Damas,Liliana; Aquino,Gilberto; Quaresma,Joana; Et Al
  参考文献:Acs Omega 日期:2020 卷标:5(19) 页码:10868-10877]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 1 H,Rt
  标题:Aldol Condensation In Water Using Polyethylene Glycol 400
  作者:Tanemura,Kiyoshi; Suzuki,Tsuneo; Nishida,Yoko; Horaguchi,Takaaki
  参考文献:Chemistry Letters 日期:2005 卷标:34(4) 页码:576-577]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Ethanol,Water; 5 S,Cooled; Overnight,Rt
  标题:3-Oxopropane-1-Sulfonic Acids And -Sulfonates
  参考文献:World Intellectual Property Organization]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Catalysts: Sodium Hydroxide Solvents: Ethanol; 3 - 4 H,Rt
  标题:Preparation Of 1,5-Diketones By Addition Of Cyclohexanone To Chalcones Under Solvent-Free Phase Transfer Catalyst Condition
  作者:Ceylan,Mustafa; Gezegen,Hayreddin
  参考文献:Turkish Journal Of Chemistry 日期:2008 卷标:32(1) 页码:55-61]
  
  123-11-5 + 98-86-2 = 959-23-9
  反应条件:1.1 Catalysts: Alumina,Potassium Fluoride Solvents: Ethanol; 25 Min
  标题:Application Of Ultrasound Irradiation In Synthesis Of Chalcones
  作者:Huang,Dan; Jiang,Guo-Qing
  参考文献:Youji Huaxue 日期:2002 卷标:22(12) 页码:1057-1059]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Catalysts: Copper Perchlorate Hexahydrate; 60 Min,Rt1.2 Reagents: Sodium Chloride Solvents: Water; Cooled
  标题:Sonochemical Aldol Condensation Using Copper Perchlorate Hexahydrate As Catalyst In Solventless Media
  作者:Puri,Saurabh; Kaur,Balbir; Kumar,Harish
  参考文献:International Journal Of Chemistry (Mumbai 日期:2013 卷标:2(2) 页码:254-258]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Methanol,Water; Overnight,Rt
  标题:Synthesis,Characterization And Antimicrobial Activity Of Thiazole,Benzothiazole And Pyrimidine Derivatives Bearing Sydnone Moieties
  作者:Asundaria,S. T.; Patel,K. C.
  参考文献:Pharmaceutical Chemistry Journal 日期:2012 卷标:45(12) 页码:725-731]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Ethanol,Water; 0 °C; 3 H,Rt
  标题:Imidazotriazine Compounds And Their Preparation,Pharmaceutical Compositions And Use In The Treatment Of Bacterial Infection
  参考文献:China]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Methanol,Water
  标题:Novel Phosphorous (V)-Based Reagents,Processes For The Preparation Tony Thereof,And Their Use In Making Stereo-Defined Organophoshorous (V) Compounds
  参考文献:World Intellectual Property Organization]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Catalysts: Sodium Hydroxide Solvents: Ethanol,Water; 3 H,15 °C; 24 H,15 °C
  标题:Synthesis And Cytotoxic Activity Of Chalcone Derivatives On Human Breast Cancer Cell Lines
  作者:Harmastuti,Nuraini; Herowati,Rina; Susilowati,Dyah; Pranowo,Harno Dwi; Mubarika,Sofia
  参考文献:Indonesian Journal Of Chemistry 日期:2012 卷标:12(3) 页码:261-267]
  
  102-92-1 + 5720-07-0 = 959-23-9
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: 4-Aza-1-Azoniabicyclo[2.2.2]Octane,1-(Phenylmethyl)-,Di-μ-Chlorotetrachlorodip... Solvents: Toluene; 40 Min,Rt
  标题:A Versatile Method For The Synthesis Of Diaryl And Alkyl Aryl Ketones Via Palladium-Catalysed Cross-Coupling Reaction Of Arylboronic Acids With Acyl Chlorides
  作者:Rafiee,Fatemeh; Hajipour,Abdol R.
  参考文献:Applied Organometallic Chemistry 日期:2015 卷标:29(3) 页码:181-184]
  
  100-52-7 + 100-06-1 = 959-23-9
  反应条件:1.1 Catalysts: 4-Methoxybenzaldehyde Solvents: Toluene; 2 H,Reflux
  标题:Efficient Synthesis Of Chalcones By A Solid Base Catalyst
  作者:Kantam,M. Lakshmi; Prakash,B. Veda; Reddy,Ch. Venkat
  参考文献:Synthetic Communications 日期:2005 卷标:35(14) 页码:1971-1978

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
  2902500000-苯乙烯
  2902600000-乙苯
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管