专利号:EP-0035328-A1 优先权日:1980-02-14 标题:Method of synthesizing hydrocarbons and alcohols 发明人:OZYAGCILAR MEHMET N 权利人:UNIV SOUTH CAROLINA 摘要:Improved economies are achieved in the synthesis of hydrocarbons and alcohols from hydrogen/carbon monoxide mixtures by adding steam to a hydrogen-lean synthesis gas derived, e.g., from the gasification of a liquid or solid fossil fuel and carrying out the synthesis in the presence of a catalyst comprising hydrided titanium supported on a metal or inter-metallic compound capable of forming an unstable hydride.
专利号:EP-0042309-A1 优先权日:1980-06-18 标 题 :Method for the coproduction of hydrocarbons and alcohols 发明人:OZYAGCILAR MEHMET N 权利人:UNIV SOUTH CAROLINA 摘要:Methods for the synthesis of hydrocarbons and alcohols by contacting carbon monoxide and hydrogen over novel catalyst compositions are disclosed. The catalyst compostions are intermetallic compounds having a first and second phase, said first phase being selected from:n (1) a single metal selected from V and Nb, (2) a single phase binary alloy selected from TiCo, TiCr, TiCu and TiMn and the binary Laves phase compounds TiCr 2 , ZrNi 2 , ZrMo 2 , ZrFe 2 , ZrCo 2 , ZrMn 2 , TiCo 2 , ZrCu 2 and ZrCr 2 , and (3) single phase ternary or quaternary alloys selected fromn (a) TiFexMyNz where M and N are any metal that can substitute for Fe such that the resulting alloy is a single phase alloy, but not Ni or Ru, and where X is a number less than 1.0, y and z are each numbers less than 1.0 or either, but not both, may be 0, and x and y and z is approximately 1.0; (b) TiA x M y N z where A is Co, Cr, Mn or Cu, M and N are any metal that can substitute for Co, Cr, Mn or Cu such that the resulting alloy is a single phase alloy, and where x is a number less than 1.0, y and z are each numbers less than 1.0 or either, but not both, may be 0, and x and y and z is approximately 1.0; and (c) ternary or higher Laves phase compounds based on Ti and/or Zr, and said second phase is free titanium hydride or zirconium hydride.
专利号:EP-0034403-A1 优先权日:1980-01-17 标题 :Method of making ammonia 发明人:OZYAGCILAR MEHMET N 权利人:UNIV SOUTH CAROLINA 摘要:A method of making ammonia by contacting nitrogen and hydrogen in synthesis proportions at synthesis conditions with a catalyst comprising hydrided titanium supported on a metal or inter-metallic compound capable of forming an unstable hydride. The catalyst may be prepared by alloying titanium or zirconium with a second metal capable of forming an inter-metallic compound with titanium under alloying conditions such as to produce said inter-metallic compound and free titanium in an amount effective when hydrided to catalyze the conversion of nitrogen and hydrogen to ammonia. The second metal may be selected from iron, nickel, cobalt, chromium, molybdenum, manganese and mixtures thereof. A stoichiometric excess of hydrogen is desirably used.
专利号:CA-1133680-A 优先权日:1977-05-20 标题 :Catalytic process for synthesis of ammonia
专利号:GB-1604265-A 优先权日:1978-05-31 标 题:Method for synthesis of ammonia
专利号:GB-1604264-A 优先权日:1978-05-19 标 题:Method for the synthesis of ammonia
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