CAS: 7704-98-5; Titanium(Ii) Hydride

该化合物是无机化合物,具有金属特性和氢化物形成形态,一般是灰或黑固体,以高熔点和密度著称;当钛在特定条件下与氢发生反应时,形成这种化合物,产生钛与氢的蒸气比; 钛(II) 氢化物具有有趣的特性,例如是一个很好的电导体,具有较高的热稳定性; 经常用于各种用途,包括减少化学反应和生产钛金属的制剂; 此外,它可以作为其他钛化合物的前体; 然而,处理钛(II) 氢化物需要谨慎,因为它能与湿度和空气发生反应,可能导致氢气释放,而氢气是易燃的. 总的来说,钛(II) 氢化物因其独特的特性和再活性,是材料科学和工业化学中的重要化合物.

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

titanium hydrogen oxygen oxygen-18lanthanum trihydride

合成工艺路线路线简述

    📜四氢化物钛,氢气 反应生成 二氢化钛
    参考文献:Malov,Yu. I.; Fokin,V. N.; Troitskaya,S. L.,Russian Journal Of Inorganic Chemistry,1994,Vol. 39,P. 1712-1714
    标题:Malov,Yu. I.; Fokin,V. N.; Troitskaya,S. L.,Russian Journal Of Inorganic Chemistry,1994,Vol. 39,P. 1712-1714

    专利信息


    专利号:EP-0035328-A1
    优先权日:1980-02-14
    标题:Method of synthesizing hydrocarbons and alcohols
    发明人:OZYAGCILAR MEHMET N
    权利人:UNIV SOUTH CAROLINA
    摘要:Improved economies are achieved in the synthesis of hydrocarbons and alcohols from hydrogen/carbon monoxide mixtures by adding steam to a hydrogen-lean synthesis gas derived, e.g., from the gasification of a liquid or solid fossil fuel and carrying out the synthesis in the presence of a catalyst comprising hydrided titanium supported on a metal or inter-metallic compound capable of forming an unstable hydride.

    专利号:EP-0042309-A1
    优先权日:1980-06-18
    标 题 :Method for the coproduction of hydrocarbons and alcohols
    发明人:OZYAGCILAR MEHMET N
    权利人:UNIV SOUTH CAROLINA
    摘要:Methods for the synthesis of hydrocarbons and alcohols by contacting carbon monoxide and hydrogen over novel catalyst compositions are disclosed. The catalyst compostions are intermetallic compounds having a first and second phase, said first phase being selected from:n (1) a single metal selected from V and Nb, (2) a single phase binary alloy selected from TiCo, TiCr, TiCu and TiMn and the binary Laves phase compounds TiCr 2 , ZrNi 2 , ZrMo 2 , ZrFe 2 , ZrCo 2 , ZrMn 2 , TiCo 2 , ZrCu 2 and ZrCr 2 , and (3) single phase ternary or quaternary alloys selected fromn (a) TiFexMyNz where M and N are any metal that can substitute for Fe such that the resulting alloy is a single phase alloy, but not Ni or Ru, and where X is a number less than 1.0, y and z are each numbers less than 1.0 or either, but not both, may be 0, and x and y and z is approximately 1.0; (b) TiA x M y N z where A is Co, Cr, Mn or Cu, M and N are any metal that can substitute for Co, Cr, Mn or Cu such that the resulting alloy is a single phase alloy, and where x is a number less than 1.0, y and z are each numbers less than 1.0 or either, but not both, may be 0, and x and y and z is approximately 1.0; and (c) ternary or higher Laves phase compounds based on Ti and/or Zr, and said second phase is free titanium hydride or zirconium hydride.

    专利号:EP-0034403-A1
    优先权日:1980-01-17
    标题 :Method of making ammonia
    发明人:OZYAGCILAR MEHMET N
    权利人:UNIV SOUTH CAROLINA
    摘要:A method of making ammonia by contacting nitrogen and hydrogen in synthesis proportions at synthesis conditions with a catalyst comprising hydrided titanium supported on a metal or inter-metallic compound capable of forming an unstable hydride. The catalyst may be prepared by alloying titanium or zirconium with a second metal capable of forming an inter-metallic compound with titanium under alloying conditions such as to produce said inter-metallic compound and free titanium in an amount effective when hydrided to catalyze the conversion of nitrogen and hydrogen to ammonia. The second metal may be selected from iron, nickel, cobalt, chromium, molybdenum, manganese and mixtures thereof. A stoichiometric excess of hydrogen is desirably used.

    专利号:CA-1133680-A
    优先权日:1977-05-20
    标题 :Catalytic process for synthesis of ammonia

    专利号:GB-1604265-A
    优先权日:1978-05-31
    标 题:Method for synthesis of ammonia

    专利号:GB-1604264-A
    优先权日:1978-05-19
    标 题:Method for the synthesis of ammonia

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    合成参考文献


    参考文献:10.1007/978-1-4899-0545-1_68
    摘要:Nagy Z. Ti—Titanium. 1985. In: Electrochemical Synthesis of Inorganic Compounds.
    参考文献:10.1007/978-981-16-3033-0_9
    摘要:Dinbandhu, Thakur A, Venugopal Goud E, Abhishek K, Vora JJ. An Overview of Proteus: The world’s First Man-Made Non-cuttable Material. 2021. In: Lecture Notes in Mechanical Engineering.
    参考文献:10.1007/s12034-014-0660-7
    摘要:Subject Index. Bull Mater Sci. 2013 Dec;36(7):1349–69. doi: 10.1007/s12034-014-0660-7.
    参考文献:10.1007/978-3-642-66107-5_7
    摘要:Tsuji J. Cyclization Reactions and Related Reactions. 1975. In: Reactivity and Structure Concepts in Organic Chemistry.
    参考文献:10.1007/978-3-030-68462-4_13
    摘要:Pujari RB, Lee D. Oxygen-Deficient Metal Oxide Nanostructures for Photocatalytic Activities. 2021. In: Chemically Deposited Nanocrystalline Metal Oxide Thin Films.
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