专利号:US-10011567-B1 优先权日:2017-03-09 标题 :Method for the synthesis of acrylate derivatives 发明人:WANG MINGWEN; ZHANG YUE 权利人:INNOSCI LLC 摘要:The present invention provides an improved synthesis of a salt of acrylate derivatives. The synthesis generally includes the preparation of an ester or an amide containing a leaving group followed by the formation of a salt.
专利号:US-11970449-B2 优先权日:2021-10-04 标 题:Mechanochemical based synthesis of perfluoropyridine monomers for polymerization 发明人:IACONO SCOTT T; FRIESEN CHADRON M 权利人:US GOV AIR FORCE; US AIR FORCE 摘要:The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.
专利号:WO-2025122636-A1 优先权日:2023-12-04 标题:Method for the synthesis of acrylate derivatives 发明人:CAICEDO-CARVAJAL CARLOS; KATZ JORDAN; CHOI SEAN 权利人:ORTHOBOND CORP 摘要:The disclosure relates to the synthesis of quaternary salts of various acrylates in high yield and high purity.
专利号:US-10676423-B2 优先权日:2017-02-21 标题 :Structure and synthesis of highly fluorinated amino acid derivatives 发明人:WEAVER JIMMIE DEAN; TEEGARDIN KIP ALLEN; ARORA AMANDEEP 权利人:UNIV OKLAHOMA STATE 摘要:Methods of synthesizing polyfluorinated amino acid derivatives are disclosed, along with polyfluorinated amino acid derivatives produced from said methods, as well as compositions containing same. The synthesis methods utilize an oxazolone and a perfluoroarene to produce the polyfluorinated amino acid derivatives.
专利号:US-2024067621-A1 优先权日:2021-02-23 标 题:Polyfluorinated cannabinoid and cannabinoid-like compounds and methods of synthesis and use thereof 发明人:WEAVER JIMMIE D; DAY JON; GROTJAHN SASCHA; SENAWEERA SAMEERA; KOENIG BURKHARD 权利人:WEAVER JIMMIE D; DAY JON; GROTJAHN SASCHA; SENAWEERA SAMEERA; KOENIG BURKHARD; THE BOARD OF REGENTS FOR THE OKLAHOMA AGRICULTURAL AND MECH COLLEGES 摘要:Polyfluorinated compounds are disclosed, including polyfluorinated cannabinoid and cannabinoid-like compounds. Also disclosed are methods of producing the polyfluorinated compounds.
专利号:US-2024309128-A1 优先权日:2023-03-13 标 题 :Perfluoropyridine based polymers obtained via radical initiated methods 发明人:JENNINGS ABBY R; IACONO SCOTT T; AULECIEMS ZACHARY J; LOCHMAIER EMELINE C 权利人:US GOV AIR FORCE 摘要:The synthesis of the fluorinated monomer, 2-((perfluoropyridin-4-yl)amino)ethyl methacrylate, and the use of the same in the preparation of fluorinated homo- and copolymers is provided. Such monomer was designed to contain a terminal methacrylate group, allowing for polymerization through free-radical techniques, both chain-growth and reversible addition-fragmentation chain-transfer methods. The monomer was designed to be compatible with other commercially available monomers and solvents to facilitate ease of copolymerization through free-radical polymerization techniques. The polymerization does not require perfluorinated alkyl substances or perfluorooctanoic acids or related compounds in the synthesis of the fluoropolymers.
[参考文献]: Barbara Procacci, Et Al. Photochemical Reactions Of Fluorinated Pyridines At Half-Sandwich Rhodium Complexes: Competing Pathways Of Reaction. Organometallics. 2014 Jan 13;33(1):45-52. [参考文献]: Masato Ohashi, Et Al. Palladium-Catalyzed Coupling Reaction Of Perfluoroarenes With Diarylzinc Compounds. Chemistry. 2014 Feb 10;20(7):2040-8. [参考文献]: Sanka N Atapattu, Et Al. Solid Phase Analytical Derivatization Of Anthropogenic And Natural Phenolic Estrogen Mimics With Pentafluoropyridine For Gas Chromatography-Mass Spectrometry. J Chromatogr A. 2011 Dec 23;1218(51):9135-41.
合成参考文献
摘要:Beweries, T.; Rosenthal, U., Science of Synthesis Knowledge Updates, (2011) 4, 33. 摘要:Inoue, S.; Driess, M., Science of Synthesis Knowledge Updates, (2012) 4, 234. 摘要:Ghosh, B.; Maleczka, R. E., Jr., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 1, 362. 摘要:Shu, X.-Z.; Pang, X., Science of Synthesis: Special Topics, (2022) 1, 430. 摘要:Ouellet-Du Berger, M.-R.; Paquin, J.-F., Science of Synthesis: Knowledge Updates, (2023) 2, 287.