专利号:WO-2020130862-A1 优先权日:2018-12-17 标题:Lyophilized fertilizer composition comprising iron siderophore chelates, lyophilized composition comprising siderophores, their processes of obtention and uses to treat plants 发明人:MONTEIRO SOARES HELENA MARIA VIEIRA; HENRIQUES FERREIRA CARLOS MIGUEL; VALENTE SOARES EDUARDO JORGE; LUCENA MAROTTA JUAN JOSÉ; LOPÉZ RAYO SANDRA 权利人:UNIV DO PORTO; INST SUPERIOR DE ENGENHARIA DO PORTO; UNIV MADRID AUTONOMA 摘要:Lyophilized fertilizer composition comprising iron siderophore chelates and a stabilizing agent and a lyophilized composition comprising siderophores and a stabilizing agent, wherein the stabilizing agent is starch. The invention further relates to processes of obtaining a lyophilized fertilizer composition and a lyophilized composition comprising a step of synthesis of at least one siderophore compound by means of biochemical transformation performed by at least one microorganism, and to the use of the compositions for treating cultivated plants, for example in conditions of low iron availability, wherein the compositions are capable of correcting chlorosis in plants and do not present environmental risks. The lyophilized fertilizer composition and the lyophilized composition have high storage stability.
专利号:WO-2025056767-A1 优先权日:2023-09-15 标题 :Process for the preparation of enantiomerically enriched aliphatic amines 发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS 权利人:SYNGENTA CROP PROTECTION AG 摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.
专利号:US-2016073631-A1 优先权日:2013-03-04 标 题 :Process for the preparation of dihydropyrrole derivatives 发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS 权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD 摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).
专利号:US-9233920-B2 优先权日:2010-06-11 标题 :Process for the preparation of dihydropyrrole derivatives 发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS 权利人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS; SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD 摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) wherein P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; R 1 is chlorodifluoromethyl or trifluoromethyl; R 2 is optionally substituted aryl or optionally substituted heteroaryl; n is 0 or 1; including the process comprising (a-i) reacting a compound of formula II wherein P, R 1 and R 2 are as defined for the compound of formula I; with nitromethane in the presence a chiral catalyst to give a compound of formula III Wherein P, R 1 and R 2 are as defined for the compound of formula I; and (a-ii) reductively cyclizing the compound of formula III to give the compound of formula I. The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).
专利号:US-10906880-B2 优先权日:2016-01-26 标题:Kind of isothiazole oxime ether-containing strobilurin derivatives and its preparation methods and application 发明人:FAN ZHIJIN; CHEN LAI; GUO XIAOFENG; ZHU YUJIE; QIAN XIAOLIN; MA LIUYONG; ZHANG NAILOU; WANG HAIXIA; ZHANG ZHIMING; XU JINGHUA; SONG YINQI 权利人:UNIV NANKAI 摘要:The present invention is that provided a synthesis method of a series of isothiazole oxime ether containing strobilurin derivatives IV. The present invention relates to 3,4-dichloroisothiazolyl oxime ether strobilurin derivatives, and their chemical structural formula is as shown by IV. n n n n n n n n n n The invention discloses the structural formula of the above compound, the synthesis method and the use as an insecticide, a fungicide, an anti-plant virus agent, and an agriculturally acceptable auxiliary or synergist and a commercial insecticide. The use of a fungicide, an anti-plant virus agent and an acaricide in combination for controlling agricultural, forestry, horticultural plant pests, diseases, virus diseases and preparation methods.
专利号:US-2015368556-A1 优先权日:2014-06-18 标题:Method of synthesizing composite phosphor by phase transition 发明人:LIN YIN-CHIH; WU SHIN-MOU; HUNG HAO-EN; TSAI YI-TING; LIN CHUN-CHE; LIU RU-SHI; WANG LI-CHUN; HSIEH CHI-HSING 权利人:NAT INST CHUNG SHAN SCIENCE & TECHNOLOGY 摘要:A method of synthesizing a composite phosphor by phase transition, characterized by controlling the sintering temperature and duration, changing M 2−y Si 5 N 8 :R y phase to M 1−x Si 6 N 8 : R x phase, thereby forming a two-phase composite phosphor, wherein proportions of the two phases of the composite phosphor are variable. As indicated by its varying CIE color coordinates, Sr 1.98 Si 5 N 8 :Eu 2+ 0.02 changes from red to pink, and then to blue. The CIE color coordinates are collinear. If there is no color deviation at the two ends of the straight line, the coordinates of any color resulting from a mixture of two colors will lie on the straight line. The aforesaid synthesis method dispenses with the hassles of sintering two colored phosphors separately, thus attaining uniformity of resultant light color and cutting the costs of phosphor synthesis.
摘要:World Review of Pest Control., 9(119), 1970 摘要:Tsitologiya i Genetika. Cytology and Genetics. For English translation, see CYGEDX., 16(1)(45), 1982 摘要: 摘要:USEPA/Office of Pesticide Programs; Reregistration Eligibility Decision Document - Propargite. p.23. Case No. 0243 Effective: September 28, 2001 Amended: December 15, 2005. Available from, as of June 5, 2007: 摘要:USEPA/Office of Pesticide Programs; Reregistration Eligibility Decision Document - Propargite. p.87. Case No. 0243 Effective: September 28, 2001 Amended: December 15, 2005. Available from, as of June 5, 2007: https://www.epa.gov/pesticides/reregistration/status.htm