CAS: 17955-81-6; 1,3-Diallyltetramethyldisiloxane

该化合物是一种硅氧烷化合物,其独特结构包括两个环基组和一个硅氧烷主干管,其特性一般为粘度低,热稳定性高,对水的抗药性强,适合化学和材料工业的各种应用,分子结构允许在反应性方面有灵活性,特别是在聚合过程中,可用作交叉连接剂或反应稀释剂.此外,存在各种环基组增加了其进一步化学改造的潜力,能够合成更为复杂的硅氧烷基材料,该化合物经常用于硅酮弹性体,涂层和密封剂的配制,其特性有助于改进性能特征.应参考安全数据表,以便处理和储存准则,如任何化学物质,确保在工业或实验室环境中安全使用.

结构式图片

相似化合物

994-49-0 67875-55-2 7418-20-4

上下游产品

chloro-trimethyl-silane Allylchlorodimethylsilane methyl magnesium iodide diallyldichlorosilane 1,1,3,3-Tetramethyl-1,3-bis-(3-mercapto-propyl)-disiloxan propene

合成工艺路线路线简述

    二烯丙基二甲基硅烷置于水体系中,化学反应生成1,3-二烯丙基四甲基二硅烷
    参考文献:Brook,Michael A.; Crowe,Grant D.; Hiemstra,Henk,Canadian Journal Of Chemistry,1994,Vol. 72,# 1,P. 264-268
    标题:Brook,Michael A.; Crowe,Grant D.; Hiemstra,Henk,Canadian Journal Of Chemistry,1994,Vol. 72,# 1,P. 264-268

    海关参考信息

    专利信息


    专利号:US-11767388-B1
    优先权日:2019-09-18
    标 题 :Silicon-functionalized rubber
    发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
    权利人:GOODYEAR TIRE & RUBBER
    摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

    专利号:US-6384172-B1
    优先权日:2001-01-02
    标题:Hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof
    发明人:DVORNIC PETAR R; HU JIN; MEIER DALE J; NOWAK ROBERT M
    权利人:MICHIGAN MOLECULAR INST
    摘要:Hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof are prepared by reacting a difunctional or polyfunctional monomer having functional groups of one type (A) without any other functional groups capable of reacting significantly during polymerization, and a difunctional or polyfunctional monomer having functional groups of another type (B) without any other functional groups capable of reacting significantly during polymerization, wherein each A-functional group is reacted with a B-functional group, and wherein at least one of the monomers has a functionality of at least three. The process enables hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof to be prepared at a lower cost than with conventional synthesis processes, and provides greater flexibility in the preparation of a larger variety of different types of hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof.
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    合成参考文献


    参考文献:10.1007/bf00915929
    摘要:Petrov AD, Vdovin VM. Reaction of symmetrical tetraalkyldisiloxanes with dialkenyldialkylsilanes and with symmetrical dialkenyltetraalkyldisiloxanes. Russian Chemical Bulletin. 1959 May;8(5):905–7. doi: 10.1007/bf00915929.
    参考文献:10.1007/bf00914219
    摘要:Mironov VF, Pogonkina NA. Addition of thioacetic acid to trialkylalkenylsilanes and the synthesis of silicon-containing thiols. Russian Chemical Bulletin. 1959 Jan;8(1):76–80. doi: 10.1007/bf00914219.
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