CAS: 15925-47-0; S-(Tert-Butyl) 3-Oxobutanethioate

上下游产品

CAS号999-90-6 S-叔丁基硫代乙酸酯 | CAS号674-82-8 双乙烯酮 | CAS号75-66-1 叔丁基硫醇 | CAS号5394-63-8 2,2,6-三甲基-4H-1,... | CAS号29364-29-2 2-甲基-2-丙硫醇钠盐 | CAS号60-29-7 乙醚 | CAS号920-39-8 异丙基溴化镁 | CAS号541-50-4 3-氧丁酸 | CAS号75-66-1 叔丁基硫醇 | CAS号6375-27-5 乙酰乙酰-2,5-二甲氧基苯胺 | CAS号1657-28-9 3-氧代-N-(吡啶-2-基)丁酰胺 | CAS号88939-01-9 S-tert-butyl 2-... | CAS号88939-02-0 S-tert-butyl 2-... | CAS号88939-05-3 S-tert-butyl 3-... | CAS号88939-10-0 S-tert-butyl 3-... | CAS号88939-15-5 S-tert-butyl 3-... | CAS号6947-02-0 乙酰乙酸环己酯

S-叔丁基硫代乙酸酯置于乙醚,异丙基溴化镁体系中,化学反应生成乙酰硫代乙酸s-叔丁酯
参考文献:Evidence For Low-Temperature Growth Of Fayalite And Hedenbergite In Macalpine Hills 88107,An Ungrouped Carbonaceous Chondrite Related To The Cm-Co Clan
标题:Evidence For Low-Temperature Growth Of Fayalite And Hedenbergite In Macalpine Hills 88107,An Ungrouped Carbonaceous Chondrite Related To The Cm-Co Clan
摘要:Abstract-The Carbonaceous Chondrite Macalpine Hills (Mac) 88107 Has Bulk Composition And Mineralogy That Are Intermediate Between Those Of Co And Cm Chondrites. This Meteorite Experienced Minor Alteration And A Low Degree Of Thermal Metamorphism (Petrologic Type 3.1) And Escaped Post‐accretional Brecciation. The Alteration Resulted In The Formation Of Fayalite (Fa90-100). Al‐free Hedenbergite (∼fs50Wo50),Phyllosilicates (Saponite‐serpentine Intergrowths),Magnetite,And Ni‐bearing Sulfides (Pyrrhotite And Pentlandite). Fayalite And Hedenbergite Typically occur As Veins,Which Start At The Opaque Nodules In The Chondrule Peripheries,Crosscut Fine‐grained Rims And Either Terminate At The Boundaries With The Neighboring Fine‐grained Rims Or Continue As Layers Between These Rims. These Observations Suggest That Fayalite And Hedenbergite Crystallized After Accretion And Compaction Of The Fine‐grained Rims. Fayalite Also Overgrows Isolated Forsteritic (Fa1-5) And Fayalitic (Fa20-40) Olivine Grains Without Any Evidence For Fe‐mg Interdiffusion; It Also Replaces Massive Magnetite‐sulfide Grains. The Initial 53Mn/55Mn Ratio Of (1.58 +/-0.26) x 10−6 In The Mac 88107 Fayalite Corresponds To An Age Difference Between The Formation Of Fayalite And Refractory Inclusions In Allende Of Either ∼9 Or 18 Ma,Depending Upon The Value Of The Solar System Initial Abundance Of 53Mn Used In Age Calculations.Formation Of Secondary Fayalite And Hedenbergite Requires Mobilization And Transport Of Ca,Si,And Fe Either Through A High‐temperature Gaseous Phase (Hua And Buseck,1995) Or Low‐temperature Aqueous Solution (Krot Et Al.,1998A,B). The High‐temperature Nebular Model For The Origin Of Fayalite (Hua And Buseck,1995) Fails To Explain (A) Formation Of Fayalite‐hedenbergite Assemblages After Accretion Of Fine‐grained Rims That Lack Any Evidence For High‐temperature Processing; (B) Extreme Fractionation Of Refractory Lithophile Elements Of Similar Volatility,Ca And Al,In Hedenbergite; And (C) Absence Of Fe‐mg Interdiffusion Along Fayalite‐forsterite Boundaries. We Conclude That Fayalite And Hedenbergite In Mac 88107 Formed During Late‐stage,Low‐temperature (Approximately 150-200 oc) Aqueous Alteration. The Data For Mac 88107 Extend The Evidence For An Early Onset Of Aqueous Activity On Chondrite Parent Bodies And Reinforce The Conclusion That Liquid Water Played An Important Role In The Chemical And Mineralogical Evolution Of The First Chondritic Planetesimals.
Doi:10.1111/j.1945-5100.2000.Tb01522.X