CAS: 111-25-1; 1-Bromohexane

上下游产品

CAS号17774-09-3 chloro(hexyl)mercury | CAS号2695-47-8 6-溴-1-己烯 | CAS号111-27-3 正己醇 | CAS号3377-87-5 3-溴己烷 | CAS号544-10-5 氯(代)正己烷 | CAS号3377-86-4 2-溴己烷 | CAS号6675-64-5 1,6-hexanediylm... | CAS号4798-44-1 1-己烯-3-醇 | CAS号5756-43-4 1-ETHOXYHEXANE | CAS号10307-26-3 methyl n-hexyls... | CAS号111651-85-5 1-(3-hexoxyphen... | CAS号107451-16-1 N-己基-N-甲基丙烯酰氧基-... | CAS号109292-69-5 3-(hexylamino)phenol | CAS号110316-87-5 3-methylidenede... | CAS号3172-56-3 3,3'-双噻吩 | CAS号740804-46-0 3-(1-methylpent... | CAS号1693-86-3 3-己基噻吩 | CAS号4721-24-8 正己基磷酸 | CAS号33228-45-4 4-己基苯胺

1-乙氧基己烷置于三甲基溴硅烷体系中,化学反应 168.0H,反应生成溴己烷
参考文献:Syntheses Of Alkyl Bromides From Ethers And Bromotrimethylsilane
标题:Syntheses Of Alkyl Bromides From Ethers And Bromotrimethylsilane
摘要:
Doi:10.1055/s-1981-29460

专利信息

专利号:US-2024294462-A1
优先权日:2023-02-15
标题:Method for the Synthesis of Ionizable Lipids Using a Doubly Alkylated Intermediate
发明人：SAADATI FARIBA; TRAN HUY; CIUFOLINI MARCO; ATMURI N D PRASAD
权利人:NANOVATION THERAPEUTICS INC
摘要:Provided herein is a method for the preparation of ionizable, cationic amino lipids using a doubly alkylated nucleophilic intermediate to produce a ketone. The ketone, or a corresponding alcohol, is subjected to one or more synthesis steps to add an ionizable moiety thereto. The method can be advantageously employed for the synthesis of unsymmetrical analogues of the above lipids that would be considerably more difficult to make by alternative strategies. The method can also be used to prepare symmetrical ionizable, cationic amino lipids with fewer steps and/or with the use of fewer hazardous chemicals than known synthesis methods.

专利号:US-8084007-B2
优先权日:2004-01-30
标题 :Methods of synthesis of isotropically enriched borohydride and methods of synthesis of isotropically enriched boranes
发明人：SPIELVOGEL BERNARD; COOK KEVIN S
权利人:SPIELVOGEL BERNARD; COOK KEVIN S; SEMEQUIP INC
摘要:The invention provides new methods for the synthesis of isotopically enriched metal borohydrides, metal tetrahydroundecaborate salts, and decaborane from isotopically enriched 10 B-boric acid or 11 B-boric acid. The invention is particularly useful for synthesis of isotopically enriched sodium or lithium borohydride, MB 11 H 14 (where M is Li, Na, K, or alkylammonium), and decaborane.

专利号:US-4936966-A
优先权日:1987-12-18
标题:Process for the electrochemical synthesis of alpha-saturated ketones
发明人：GARNIER LAURENCE; ROLLIN YOLANDE; PERICHON JACQUES
权利人:POUDRES & EXPLOSIFS STE NALE
摘要:The present invention relates to a process for the electrochemical synthesis of alpha-saturated ketones by electrochemical reduction, in an organic solvent medium, of alpha-saturated organic halides in the presence of CO2 and of a catalyst based on nickel complexed with a bidentate organic ligand containing two nitrogen atoms, such as 2,2'-bipyridine and, optionally, with an ethylenic coligand. The anode, made of a metal chosen from the group consisting of the reducing metals and their alloys, is consumed during the electrochemical reaction whose site it is. It is preferably made of magnesium. This process is simple to use and allows a single-compartment cell to be employed. Alpha-saturated ketones are compounds commonly employed in the chemical industry, particularly as solvents or synthesis intermediates.

专利号:WO-9429243-A1
优先权日:1993-06-11
标 题 :Synthesis of substituted triphenylenes, useful as discotic liquid crystals
发明人：BUSHBY RICHARD JAMES; CAMMINDGE ANDREW NEIL; HEADDOCK GARETH; BORNER RUTH CAROL; BODEN NEVILLE
权利人:BRITISH TECH GROUP; BUSHBY RICHARD JAMES; CAMMINDGE ANDREW NEIL; HEADDOCK GARETH; BORNER RUTH CAROL; BODEN NEVILLE
摘要:Unsymmetrically substituted triphenylenes required in the synthesis of polymeric discotic liquid crystals are made using iron (III) chloride in organic solvent at room temperature to effect the oxidative coupling of 1,2-dialkoxybenzenes to 3,3',4,4'-tetraalkoxybiphenyls. This is followed by a reductive workup. The same oxidation-reduction protocol also proves effective in the trimerisation of 1,2-dialkoxybenzenes.

专利号:US-7767826-B2
优先权日:2007-10-05
标题 :Process for the synthesis of L-(+)-ergothioneine
发明人：TRAMPOTA MIROSLAV
权利人:PHARMATECH INTERNATIONAL INC
摘要:This invention relates to a novel process for the preparation of optically pure L-(+)-ergothioneine. The process for the chemical synthesis of L-ergothioneine comprises steps which consist of reacting L-histidine alkyl ester with an acid halide, chloroformate or pyrocarbonate in the presence of a base, hydrolysis of the alkyl-(S,Z)-2,4,5-triamidopent-4-enoate to obtain a (S)-alkyl 2,5-diamido-4-oxopentanoate, acid catalyzed hydrolysis of the (S)-alkyl 2,5-diamido-4-oxopentanoate followed by reaction with a metal thiocyanate to obtain the thiohistidine, protection of the sulfur of thiohistidine as the tert-butyl thioether, dialkylation of the primary amine to obtain a tertiary amine, quaternization of the tertiary amine, and removal of the protecting group to obtain the desired (S)-3-(2-mercapto-1H-imidazol-5-yl)-2-(trialkylammonio)propanoate (I). This process affords a better yield and is capable of practical application at large scale.

专利号:WO-2025132776-A1
优先权日:2023-12-20
标题 :Use of iron-based compounds for the synthesis of borated compounds, and corresponding methods
发明人：HANNEDOUCHE JÉRÔME; BEZZENINE SOPHIE; GIL RICHARD; CHEN DONGHUANG; WOWK VINCENT
权利人:UNIV PARIS SACLAY; CENTRE NAT RECH SCIENT
摘要:The present invention relates to the use of iron-based compounds for the synthesis of borated compounds, and the corresponding methods.