CAS: 844-51-9; [1,1:4,1-Terphenyl]-2,5-Dione

该化合物是一种替代苯丙酮衍生物,其特征是其2和5个位置的苯基组,该化合物由于其电子接受特性,在有机合成和材料科学中被广泛使用,使其作为红氧化物活性材料和电荷转移复合体的构件具有宝贵价值,其同系结构和五类系统有助于其在各种化学变异中的稳定性和反应性,包括 Diels-Alder反应和聚合工艺.该化合物还用于光化研究,并用作功能化芳香系统的前体.其明确界定的晶体结构有利于净化和定性,确保研究和工业应用的一贯性能.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号363-03-1 2-苯基-1,4-苯醌 | CAS号98-80-6 苯硼酸 | CAS号100151-17-5 2,5-dimethoxy-(... | CAS号106-51-4 苯醌 | CAS号71-43-2 苯 | CAS号2684-02-8 benzenediazonium | CAS号2674-34-2 1,4-二溴-2,5-二甲氧基苯 | CAS号150-78-7 对苯二甲醚 | CAS号369-57-3 四氟硼酸重氮苯盐 | CAS号123-31-9 对苯二酚 | CAS号28293-39-2 2,5-Cyclohexadi... | CAS号28293-27-8 2,5-Cyclohexadi... | CAS号65087-11-8 (4-acetyloxy-2,... | CAS号7204-23-1 4,7-diphenyl-1,... | CAS号4423-47-6 3,6-diphenylben... | CAS号5422-91-3 2,5-二苯基对苯二酚 | CAS号1187741-78-1 2,5-diphenyl-4-... | CAS号791-28-6 三苯基氧化膦

合成工艺路线路线简述

  • 100151-17-5 = 844-51-9
    反应条件:1.1 Reagents: Ceric Ammonium Nitrate Solvents: Acetonitrile,Water; 60 °C
    标题:Chemical Reactions With Upright Monolayers Of Cruciform π-Systems
    作者:Klare,Jennifer E.; Et Al
    参考文献:Langmuir 日期:2004 卷标:20(23) 页码:10068-10072]

    100151-17-5 = 844-51-9
    反应条件:1.1 Reagents: Diammonium Cerium Hexanitrate Solvents: Acetonitrile,Water; Rt; 15 Min,60 °C
    标题:Planar Chiral Rhodium Complexes Of 1,4-Benzoquinones
    作者:Ankudinov,Nikita M.; Et Al
    参考文献:Chemistry - A European Journal 日期:2022 卷标:28(18)]

    100151-17-5 = 844-51-9
    反应条件:1.1 Reagents: Ceric Ammonium Nitrate Solvents: Acetonitrile,Water1.2 Reagents: Water
    标题:Efficient Synthesis Of Symmetrical 2,5-Disubstituted Benzoquinones Via Palladium-Catalyzed Double Negishi Coupling
    作者:Palmgren,Andreas; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1998 卷标:63(11) 页码:3764-3768]

    591-51-5 + 20765-04-2 = 844-51-9 [标题:Reaction Conditions
    标题:Synthesis Of Substituted Quinones. 2,5-Disubstituted 1,4-Benzoquinones
    作者:Moore,Harold W.; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1980 卷标:45(25) 页码:5057-64]

    155725-10-3 = 844-51-9 [标题:Reaction Conditions
    标题:Studies On The Meerwein Arylation-Based Preparation Of 2,3-Diarylbenzene-1,4-Diones And Its Theoretical Interpretation
    作者:Takahashi,Ichiro; Et Al
    参考文献:Chemistry Letters 日期:1994 卷标:(3) 页码:465-8]

    98-80-6 + 2674-34-2 = 844-51-9
    反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Toluene; 3 H,90 °C2.1 Reagents: Diammonium Cerium Hexanitrate Solvents: Acetonitrile,Water; Rt; 15 Min,60 °C
    标题:Planar Chiral Rhodium Complexes Of 1,4-Benzoquinones
    作者:Ankudinov,Nikita M.; Et Al
    参考文献:Chemistry - A European Journal 日期:2022 卷标:28(18)]

    98-80-6 = 844-51-9 + 2887-97-0
    反应条件:1.1 Reagents: 2,6-Dichloro-1,4-Benzoquinone Catalysts: Palladium Trifluoroacetate Solvents: Acetone; 48 H,Rt
    标题:Palladium-Catalyzed Direct C-H Functionalization Of Benzoquinone
    作者:Walker,Sarah E.; Et Al
    参考文献:Angewandte Chemie 日期:2014 卷标:53(50) 页码:13876-13879]

    = 844-51-9 + 363-03-1 + 2887-97-0
    反应条件:1.1 Reagents: Palladium Diacetate Solvents: Acetic Acid,Benzene
    标题:Oxidative Coupling Of Quinones And Aromatic Compounds By Palladium(Ii) Acetate
    作者:Itahara,Toshio
    参考文献:Journal Of Organic Chemistry 日期:1985 卷标:50(26) 页码:5546-50]

    591-51-5 + 20765-04-2 = 844-51-9
    反应条件:1.1 Reagents: Sulfuric Acid
    标题:A Simple Synthetic Route To 2,5-Disubstituted 1,4-Benzoquinones
    作者:Moore,Harold W.; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1977 卷标:42(20) 页码:3320-1]

    = 844-51-9
    反应条件:1.1 Reagents: Aluminum Chloride
    标题:Alkylaluminums. Xix. Behavior Of 1,4-Quinones,Mono- And Polycyclic,With Triphenylaluminum And Related Compounds
    作者:Alberola,A.; Et Al
    参考文献:Anales De Quimica 日期:1980 卷标:76(3) 页码:199-206]

    = 844-51-9
    反应条件:1.1 Reagents: Aluminum Chloride
    标题:Alkylaluminums. Xvii. Behavior Of P-Benzoquinones With Trialkylaluminum
    作者:Alberola,A.; Et Al
    参考文献:Anales De Quimica 日期:1980 卷标:76(2) 页码:118-22]

    2674-34-2 = 844-51-9
    反应条件:1.1 Reagents: Tert-Butyllithium Solvents: Tetrahydrofuran,Hexane; 2 H,-78 °C -> 0 °C1.2 Reagents: Zinc Chloride Solvents: Tetrahydrofuran1.3 Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran; Overnight,Reflux2.1 Reagents: Ceric Ammonium Nitrate Solvents: Acetonitrile,Water; 60 °C
    标题:Chemical Reactions With Upright Monolayers Of Cruciform π-Systems
    作者:Klare,Jennifer E.; Et Al
    参考文献:Langmuir 日期:2004 卷标:20(23) 页码:10068-10072]

    2674-34-2 + 591-51-5 = 844-51-9
    反应条件:1.1 Reagents: Zinc Chloride Solvents: Tetrahydrofuran1.2 Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran1.3 Reagents: Ammonium Chloride Solvents: Water2.1 Reagents: Ceric Ammonium Nitrate Solvents: Acetonitrile,Water2.2 Reagents: Water
    标题:Efficient Synthesis Of Symmetrical 2,5-Disubstituted Benzoquinones Via Palladium-Catalyzed Double Negishi Coupling
    作者:Palmgren,Andreas; Et Al
    参考文献:Journal Of Organic Chemistry 日期:1998 卷标:63(11) 页码:3764-3768]

    98-80-6 + 363-03-1 = 844-51-9 + 2887-97-0
    反应条件:1.1 Reagents: Tetrafluoroboric Acid Catalysts: 1,2-Bis(Diphenylphosphino)Benzene,Palladium Trifluoroacetate Solvents: Tetrahydrofuran,Water; 24 H,Rt1.2 Reagents: Iron Chloride (Fecl3) Solvents: Dichloromethane; 1 H,Rt
    标题:Synthesis And Evaluation Of Arylquinones As Bace1 Inhibitors,β-Amyloid Peptide Aggregation Inhibitors,And Destabilizers Of Preformed β-Amyloid Fibrils
    作者:Ortega,Andrea; Et Al
    参考文献:Bioorganic & Medicinal Chemistry Letters 日期:2011 卷标:21(8) 页码:2183-2187]

    1079-21-6 = 844-51-9 + 2887-97-0
    反应条件:1.1 Reagents: Dimethyl Sulfoxide,Pivalic Acid,Silver Carbonate,Oxygen Catalysts: Palladium Diacetate Solvents: Benzene; 24 H,140 °C
    标题:Tandem Oxidation-Oxidative C-H/c-H Cross-Coupling: Synthesis Of Arylquinones From Hydroquinones
    作者:Zhang,Shuai; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2013 卷标:49(40) 页码:4558-4560]

    53558-55-7 = 844-51-9 + 2887-97-0 [标题:Reaction Conditions
    标题:Product Subclass 8: Alkynyl-,Aryl-,And Alkenyl-Substituted Benzo-1,4-Quinones
    作者:Balci,M.; Et Al
    参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:131-156]

    = 844-51-9 + 2887-97-0 [标题:Reaction Conditions
    标题:Product Subclass 8: Alkynyl-,Aryl-,And Alkenyl-Substituted Benzo-1,4-Quinones
    作者:Balci,M.; Et Al
    参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:131-156
📜N-亞硝乙醯胺苯置于乙醇体系中,化学反应生成 2,5-联苯对苯醌
参考文献:Akagi; Hirose,Yakugaku Zasshi/journal Of The Pharmaceutical Society Of Japan,1942,Vol. 62,P. 191,193
标题:Akagi; Hirose,Yakugaku Zasshi/journal Of The Pharmaceutical Society Of Japan,1942,Vol. 62,P. 191,193

海关参考信息

专利信息


专利号:US-7745564-B2
优先权日:2005-06-28
标 题 :System for synthesis of device forming monomers
发明人：NANDU MAHENDRA; FRIENDS GARY D; SEELYE DAVID E; KANSAL VINOD KUMAR; SHAH C C; MISTRY DHARMESH BALVANTRAI
权利人:BAUSCH & LOMB
摘要:Disclosed in embodiments herein is a method of synthesizing device forming monomers using N-(Vinyloxycarbonyloxy)succinimide.

专利号:US-7368624-B2
优先权日:2004-03-30
标 题 :Synthesis for polycyclic aromatic hydrocarbon compounds
发明人：BROWN CHRISTOPHER T; SHUKLA DEEPAK; DOCKERY KEVIN P; LENHARD JEROME R; MATZ JAMES R
权利人:EASTMAN KODAK CO
摘要:A process for forming an aryl-aryl bond comprises the step of reacting an arene hydrocarbon compound with either (1) an organic oxidant selected from the group consisting of a quinone, a quinone imine, a quinone diimine, and a nitroarene, or (2) an oxidizing salt selected from the group consisting of a triarylaminium salt, an oxonium salt, and a nitrosium salt, or (3) a hypervalent iodine compound, each in the presence of a Brönsted or Lewis acid.

专利号:US-2006293476-A1
优先权日:2005-06-28
标 题:Novel system for synthesis of device forming monomers

专利号:JP-2004168830-A
优先权日:2002-11-18
标题:Novel unsaturated polyester resin composition, molding material, reinforced plastic molded article, which is made of modified PET and PEN which are recycled materials and has improved water resistance, and a method for short-time synthesis of this composition

专利号:US-2015105534-A1
优先权日:2011-10-21
标题 :Synthesis of conjugated polymers via oxidative polymerization and related compositions

专利号:US-12173210-B2
优先权日:2021-09-28
标题:Solventless quantum dot composition, method for producing same, and cured film, color filter, and display device comprising same
发明人：KIM GILRAN; BAE YUNJU; JO AHYOUNG; PARK SHULGI; NAM EUNHEE; HA SUNGMIN; NAM CHUNRAE; KWON SUNYOUNG; KIM BUYONG; KIM JINWON; PAEK HYE-JIN; SONG TAEYOUNG
权利人:HANSOL CHEMICAL CO LTD; SAMSUNG DISPLAY CO LTD
摘要:A solventlesss quantum dot composition, a method for preparing the same, and a cured film, a color filter, and a display device including the same are disclosed. The solventless quantum dot composition comprises quantum dots surface-modified with at least two ligands, has low viscosity and good optical properties, and can be prepared by synthesis of quantum dots (QDs), followed by direct ligand substitution in the solution, thereby securing a simplified preparation process.

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合成参考文献


摘要:Balci, M.; Gültekin, M. S.; Çelik, M., Science of Synthesis, (2006) 28, 144.
摘要:Balci, M.; Gültekin, M. S.; Çelik, M., Science of Synthesis, (2006) 28, 143.
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