📜三甲基硅醇,3-氨基丙基三乙氧基硅烷 以88%的收率获得丙氨基三(三甲基硅氧基)硅烷 参考文献:Kovyazin,V. A.; Kopylov,V. M.,Journal Of General Chemistry Of The Ussr,1992,Vol. 62,# 4.2.,P. 694-696 标题:Kovyazin,V. A.; Kopylov,V. M.,Journal Of General Chemistry Of The Ussr,1992,Vol. 62,# 4.2.,P. 694-696
专利信息
专利号:US-9937556-B2 优先权日:2011-11-15 标题 :Templated synthesis of metal nanorods in silica nanotubes 发明人:YIN YADONG; GAO CHUANBO 权利人:UNIV CALIFORNIA 摘要:A method of preparing a metal nanorod. The method includes seeding a metal nanoparticle within the lumen of a nanotube, and growing a metal nanorod from the seeded metal nanoparticle to form a metal nanorod-nanotube composite. In some cases, the nanotube includes metal binding ligands attached to the inner surface. Growing of the metal nanorod includes incubating the seeded nanotube in a solution that includes: a metal source for the metal in the metal nanorod, the metal source including an ion of the metal; a coordinating ligand that forms a stable complex with the metal ion; a reducing agent for reducing the metal ion, and a capping agent that stabilizes atomic monomers of the metal. Compositions derived from the method are also provided.
专利号:US-2012238661-A1 优先权日:2011-01-14 标 题 :Processes for the Synthesis of Compounds from Cyclic Carbonates 发明人:IYER RAMESH; MCKENNA PETER; SMALLRIDGE MARK; MATTHEWS MELISSA; NATESH ANBAZHAGAN 权利人:IYER RAMESH; MCKENNA PETER; SMALLRIDGE MARK; MATTHEWS MELISSA; NATESH ANBAZHAGAN; COGNIS IP MAN GMBH 摘要:The invention provides compounds containing the ring-opening products of ethylenically unsaturated cyclic carbonates for use in preparing hydrogel polymers, as well as methods for their preparation. A preferred method of the invention includes the reaction of nucleophilic compounds containing Si, F, N or O atoms, or combinations thereof, or latent moieties in the form of unsaturated or hydroxylated functional groups, with ethylenically unsaturated glycerol carbonate derivatives. The compounds and hydrogel polymers are useful for the preparation of contact lenses.
专利号:US-6423862-B1 优先权日:1999-06-29 标 题 :Synthesis of vinyl carbonates for use in producing vinyl carbamates 发明人:ALLEN DAVID LEWIS; HENRY HEATHER FORT; CAHILL BECKY LYNN; PONTON JR JOHN; CHURCH KATHRYN MARIE 权利人:WRIGHT CHEM CORP 摘要:A method for making a vinyl carbonate represented by the formula (I):wherein X1 is oxygen or sulfur and R1 is a substituted or an unsubstituted aliphatic alkyl, aryl, aryl alkyl, olefinic, vinyl, or cycloaliphatic group comprises:(a) reacting a compound represented by the formula (II): wherein X2 is a halogen other than fluorine, with a compound represented by the formula (III): wherein M1 is selected from a Group IA metal, in the presence of a first phase transfer catalyst and a first organic solvent, to form a compound represented by the formula (IV): and(b) reacting a compound represented by the formula (IV) with a compound represented by the formula (V): wherein R2 is a substituted or an unsubstituted aliphatic alkyl, aryl, aryl alkyl, olefinic, vinyl, or cycloaliphatic group, or any combination thereof, in the presence of a metal salt represented by the formula M2-F wherein M2 is a Group IA metal, a second phase transfer catalyst, and a second organic solvent, to form the compound represented by formula (I).
专利号:US-7745564-B2 优先权日:2005-06-28 标 题 :System for synthesis of device forming monomers 发明人:NANDU MAHENDRA; FRIENDS GARY D; SEELYE DAVID E; KANSAL VINOD KUMAR; SHAH C C; MISTRY DHARMESH BALVANTRAI 权利人:BAUSCH & LOMB 摘要:Disclosed in embodiments herein is a method of synthesizing device forming monomers using N-(Vinyloxycarbonyloxy)succinimide.
专利号:US-2002151740-A1 优先权日:1999-06-29 标题 :Synthesis of vinyl carbonates for use in producing vinyl carbamates
专利号:US-2006293476-A1 优先权日:2005-06-28 标 题:Novel system for synthesis of device forming monomers
参考标题:Synthesis Of Vinyl Carbonates For Use In Producing Vinyl Carbamates 摘要:A Method For Making A Vinyl Carbonate Represented By The Formula (I): Ch2═choc(O)X1R1 (I) Wherein X1 Is Oxygen Or Sulfur And R1 Is A Substituted Or An Unsubstituted Aliphatic Alkyl, Aryl, Aryl Alkyl, Olefinic, Vinyl, Or Cycloaliphatic Group Comprises: (A) Reacting A Compound Represented By The Formula (II): X2C(O)X1R1 (II) Wherein X2 Is A Halogen Other Than Fluorine, With A Compound Represented By The Formula (III): M1-F (III) Wherein M1 Is Selected From A Group Ia Metal, In The Presence Of A First Phase Transfer Catalyst And A First Organic Solvent, To Form A Compound Represented By The Formula (Iv): Fc(O)X1R1 (Iv) And (B) Reacting A Compound Represented By The Formula (Iv) With A Compound Represented By The Formula (V): Ch2═chosi(R2)3 (V) Wherein R2 Is A Substituted Or An Unsubstituted Aliphatic Alkyl, Aryl, Aryl Alkyl Olefinic, Vinyl, Or Cycloaliphatic Group, Or Any Combination Thereof, In The Presence Of A Metal Salt Represented By The Formula M2-F Wherein M2 Is A Group Ia Metal, A Second Phase Transfer Catalyst, And A Second Organic Solvent, To Form The Compound Represented By Formula (I).
合成参考文献
参考文献:10.1364/boe.2.001828 摘要:Bayer CL, Chen YS, Kim S, Mallidi S, Sokolov K, Emelianov S. Multiplex photoacoustic molecular imaging using targeted silica-coated gold nanorods. Biomed Opt Express. 2011 Jul 01;2(7):1828–35.